(1,5-cylooctadiene)di-iodoplatinum(II) | 12266-72-7

• 物质功能分类: 化学试剂 - 有机试剂 - 烯烃（环状与无环状）
• 分子结构分类: 有机化合物 - 有机盐 - 有机金属盐
• 英文名称: (1,5-cylooctadiene)di-iodoplatinum(II)
• 英文别名: [(cod)PtI2]；diiodo(1,5-cyclooctadiene)platinum(II)；[Pt(cyclo-octa-1,5-diene)I2]；diiodo(cycloocta-1,5-diene)platinum(II)；cis-PtI2(cyclo-octa-1,5-diene)；[PtI2(cycloocta-1,5-diene)]；[PtI2(1,5-cyclooctadiene)]；(1,5-cyclooctadiene)PtI2；Pt(1,5-cyclooctadiene)I2；[Pt(COD)I2]；(1Z,5Z)-cycloocta-1,5-diene;platinum(2+);diiodide
• CAS: 12266-72-7
• 化学式: C₈H₁₂I₂Pt
• 分子量: 557.072
• InChiKey: SGSFNZOKVYTGRR-PHFPKPIQSA-L

物化性质

• 熔点：
  260°C (dec.)
• 暴露限值：
  ACGIH: TWA 0.002 mg/m3NIOSH: IDLH 4 mg/m3; TWA 0.002 mg/m3
• 稳定性/保质期：
  在常温常压下稳定，应避免与氧化物接触。

计算性质

• 辛醇/水分配系数(LogP)：
  -3.32
• 重原子数：
  11
• 可旋转键数：
  0
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.5
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  2

安全信息

• 危险品标志：
  Xi
• 危险类别码：
  R36/37/38
• 安全说明：
  S26,S36/37/39,S37/39
• 危险性防范说明：
  P261,P305+P351+P338
• 危险性描述：
  H302,H315,H319,H335
• 储存条件：
  常温下应存于密闭容器中，避免光照，并置于通风、干燥处。

SDS

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Section 1: Product Identification
Chemical Name: Diiodo(1,5-cyclooctadiene)platinum (II), 99%
CAS Registry Number: 12266-72-7
Formula: PtI2(1,5-C8H12)
EINECS Number: 235-538-7
Chemical Family: organometallic complexes
Synonym: 1,5-cyclooctadieneplatinum diiodide

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Section 2: Composition and Information on Ingredients
Ingredient CAS Number Percent ACGIH (TWA) OSHA (PEL)
Title Compound 12266-72-7 100% 1mg/m3(as-Pt) no data

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Section 3: Hazards Identification
Emergency Overview: Irritating to the respiratory tract, skin and eyes. May be harmful if swallowed.
Primary Routes of Exposure: Ingestion, inhalation, skin
Eye Contact: Causes mild to moderate irritation of the eyes.
Skin Contact: Causes slight to mild irritation of the skin.
Inhalation: Irritating to the nose, mucous membranes and respiratory tract.
Ingestion: Ingestion may lead to dizziness, abdominal cramps, vomiting, bloody diarrhea, weakness, and convulsions.
Irritating to skin, eyes and respiratory tract. Exposure to platinum compounds may lead to wheezing, coughing,
Acute Health Affects:
and running of the nose. Skin exposure may lead to dermatitis.
Chronic Health Affects: No information available on long-term chronic effects.
NTP: No
IARC: No
OSHA: No

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SECTION 4: First Aid Measures
Immediately flush the eyes with copious amounts of water for at least 10-15 minutes. A victim may need
Eye Exposure:
assistance in keeping their eye lids open. Get immediate medical attention.
Wash the affected area with water. Remove contaminated clothes if necessary. Seek medical assistance if
Skin Exposure:
irritation persists.
Remove the victim to fresh air. Closely monitor the victim for signs of respiratory problems, such as difficulty
Inhalation:
in breathing, coughing, wheezing, or pain. In such cases seek immediate medical assistance.
Seek medical attention immediately. Keep the victim calm. Give the victim water (only if conscious). Induce
Ingestion:
vomiting only if directed by medical personnel.

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SECTION 5: Fire Fighting Measures
Flash Point: not applicable
Autoignition Temperature: none
Explosion Limits: none
Extinguishing Medium: carbon dioxide, foam or dry powder
If this product is involved in a fire, fire fighters should be equipped with a NIOSH approved positive pressure
Special Fire Fighting Procedures:
self- contained breathing apparatus and full protective clothing.
Hazardous Combustion and If involved in a fire this material may emit toxic and corrosive fumes.
Decomposion Products:
Unusual Fire or Explosion Hazards: No unusual fire or explosion hazards.

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SECTION 6: Accidental Release Measures
Small spills can be mixed with vermiculite, sodium carbonate or other suitable non combustible adsorbent and
Spill and Leak Procedures:
swept up.

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SECTION 7: Handling and Storage
Handling and Storage: Store in a cool, dry place in a tightly sealed container.

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SECTION 8: Exposure Controls and Personal Protection
Eye Protection: Always wear approved safety glasses when handling a chemical substance in the laboratory.
Skin Protection: Wear protective clothing and gloves.
Ventilation: To minimize exposure, handle the material in an efficient fume hood.
If ventilation is not available a respirator should be worn. The use of respirators requires a Respirator
Respirator:
Protection Program to be in compliance with 29 CFR 1910.134.
Ventilation: To minimize exposure, handle the material in an efficient fume hood.
Additional Protection: No additional protection required.

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SECTION 9: Physical and Chemical Properties
Color and Form: yellow pwdr.
Molecular Weight: 557.08
Melting Point: no data
Boiling Point: no data
Vapor Pressure: not applicable
Specific Gravity: no data
Odor: none
Solubility in Water: insoluble

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SECTION 10: Stability and Reactivity
Stability: air and moisture stable
Hazardous Polymerization: no hazardous polymerization
Conditions to Avoid: none
Incompatibility: oxidizing agents, halogens, and active metals
Decomposition Products: carbon dioxide, carbon monoxide, iodine, organic fumes and platinum salts.

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SECTION 11: Toxicological Information
RTECS Data: No information available in the RTECS files.
Carcinogenic Effects: No data
Mutagenic Effects: No data
Tetratogenic Effects: No data

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SECTION 12: Ecological Information
Ecological Information: No information available

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SECTION 13: Disposal Considerations
Disposal: Dispose of according to local, state and federal regulations.

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SECTION 14: Transportation
Shipping Name (CFR): Non-hazardous
Hazard Class (CFR): NA
Additional Hazard Class (CFR): NA
Packaging Group (CFR): NA
UN ID Number (CFR): NA
Shipping Name (IATA): Non-hazardous
Hazard Class (IATA): NA
Additional Hazard Class (IATA): NA
Packaging Group (IATA): NA
UN ID Number (IATA): NA

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SECTION 15: Regulatory Information
TSCA: Not listed in the TSCA inventory.
SARA (Title 313): Not regulated by Title 313.
Second Ingredient: None

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SECTION 16 - ADDITIONAL INFORMATION
N/A

反应信息

• 作为反应物：
  描述：

  (1,5-cylooctadiene)di-iodoplatinum(II) 在 sodium tetrahydroborate 作用下， 以 水 、 甲苯 为溶剂， 生成 platinum
  参考文献：
  名称：

  Thin film formation of platinum nanoparticles at oil–water interface, using organoplatinum(ii) complexes, suitable for electro-oxidation of methanol

  摘要：

  本文介绍了一种简单有效的策略，即在甲苯与水的界面上，在没有稳定剂的情况下，通过还原有机铂（II）复合物[PtCl2（cod）] 1a、[PtI2（cod）] 1b（cod = 1,5-环辛二烯）和顺式-[Pt（p-MeC6H4）2（SMe2）2] 2，将单个铂纳米粒子（NPs）整合成宏观薄膜。利用 X 射线衍射（XRD）、透射电子显微镜（TEM）和选区电子衍射（SAED）技术对铂 NPs 的结构和形态进行了表征。最后，在玻璃碳电极上沉积了铂薄膜，并研究了它们在甲醇氧化反应中的电氧化作用。与商用铂催化剂相比，铂 NPs 薄膜在甲醇氧化反应中表现出更高的电催化活性。本方法为燃料电池中应用的不同贵金属电催化剂的合成提供了一种简便、低成本的策略。

  DOI：

  10.1039/c3dt51175h
• 作为产物：
  描述：

  β-CD*Pt(COD)I2 以 乙醇 、 水 为溶剂， 生成 (1,5-cylooctadiene)di-iodoplatinum(II)
  参考文献：
  名称：

  环辛-1,5-二烯和降冰片二烯与环糊精的过渡金属配合物的包合物的制备及性能

  摘要：

  DOI：

  10.1021/om00113a007
• 作为试剂：
  描述：

  在 (1,5-cylooctadiene)di-iodoplatinum(II) 、 (S)-(+)-4,12-bis[di(3,5-xylyl)phosphino]-[2.2]paracyclophane 、 silver trifluoromethanesulfonate 作用下， 以 硝基甲烷 、 乙腈 为溶剂， 反应 16.0h， 以92%的产率得到Diethyl 1-ethenyl-1,2,4,9-tetrahydrocarbazole-3,3-dicarboxylate
  参考文献：
  名称：

  醇对映体的对映选择性金催化的吲哚烯丙基烷基化：一种功能化的四氢咔唑的有效途径

  摘要：

  打破禁忌：在手性金配合物的存在下，首次首次描述了在催化和对映选择性的Friedel-Crafts烷基化反应中直接使用烯丙醇。该分子内Friedel-Crafts反应用于制备范围广泛的官能化四氢咔唑（参见方案； X = Me，F，Br，Cl，OMe； R = Me，Et，t Bu； R'= H，Me）。

  DOI：

  10.1002/anie.200904388

文献信息

• Heteropolytopic Arsanylarylthiolato Ligands: Cis–Trans Isomerism of Nickel(II), Palladium(II), and Platinum(II) Complexes of 1-AsPh₂-2-SHC₆H₄
  作者：Alexandra Hildebrand、Imola Sárosi、Peter Lönnecke、Luminiţa Silaghi-Dumitrescu、Menyhárt B. Sárosi、Ioan Silaghi-Dumitrescu、Evamarie Hey-Hawkins

  DOI：10.1021/ic300002p

  日期：2012.7.2

  afforded the square-planar complexes trans-[Ni(AsS)-κ2S,As}2] (1), cis-[Pd(AsS)-κ2S,As}2] (2), trans-[Pd(AsS)-κ2S,As}2] (3), and cis-[Pt(AsS)-κ2S,As}2] (4). In the cases of nickel and platinum, only one isomer was isolated. With palladium, initially the cis isomer 2 is formed and undergoes slow isomerization to the trans isomer 3 in solution. Small amounts of the trinuclear complex [PtI(1-AsPh2-μ-2-S-C6H4-κ2S

  杂多芳基硫杂芳基配体1-AsPh 2 -2-SHC 6 H 4（AsSH），PhAs（2-SHC 6 H 4）2（AsS 2 H 2）和As（2-SHC 6 H 4）3（AsS 3 H 3）已经通过锂化-亲电取代程序制备。在2：1反应ASSH用的NiCl 2 ·6H 2 O，的Na 2 [的PdCl 4 ]和[PTI 2（COD）]（COD = 1,5-环辛二烯）在净的存在3得到正方形平面络合物反式- [镍（ASS）-κ 2小号，如} 2 ]（1），顺式- [钯（ASS）-κ 2小号，如} 2 ]（2），反式- [钯（ASS）-κ 2小号，如} 2 ]（3），以及顺式- [铂（ASS）-κ 2小号，正如} 2 ]（4）。在镍和铂的情况下，仅分离出一种异构体。与钯一起，最初形成顺式异构体2，并在溶液中缓慢地异构化为反式异构体3。少量三核的络合物[PTI（1- ASPH 2 -μ-2-SC
• 31P and 195Pt NMR characteristics of new binuclear complexes of [Pt2X4](PR3)2] cis/trans isomers and of mononuclear analogs
  作者：Ibrahim M. Al-Najjar

  DOI：10.1016/s0020-1693(00)84701-5

  日期：1987.4

  for complexes of binuclear platinum(II) of the type [Pt2(μ-X)2(X)2(PR3)2]. These were identified as intermediate from the reaction of the [PtX2COD)] complex with different tertiary phosphines (where X may be Cl or I and PR3 may be PBz3, PCy3, PCyPh2, PCy2Ph or PPh2C6F5). In addition, cis and trans-[PtX2(PR3)2] were produced in the final step, and their 31P and 195Pt are also described (X = Cl or I;

  摘要首次报道了[Pt2（μ-X）2（X）2（PR3）2]型双核铂（II）配合物的31P和195Pt化学位移。从[PtX2COD）]配合物与不同的叔膦（其中X可以是Cl或I，PR3可以是PBz3，PCy3，PCyPh2，PCy2Ph或PPh2C6F5）的反应中鉴定出这些为中间体。此外，在最终步骤中还生成了顺式和反式[PtX2（PR3）2]，并描述了它们的31P和195Pt（X = Cl或I； PR3 = PBz3，PCy3，PPhCy2，PPh2Cy，PPh2iPr，PPh2C6F5， PPh3，P（间甲苯基）3，P（对甲苯基）3，PBu3，PPhMe2，PPh2Me，（bis-1,2-Ph2P）-C6H4，Ph2PCH2PPh2或Ph2PCH2CH2PPh2）。研究表明，铂195的化学位移对复杂几何形状的性质相对敏感。非对称（不对称）顺式异构体的吸收频率（高场）比对称（对称）异构体低。）的
• Coulombic inter-ligand repulsion effects on the Pt(ii) coordination chemistry of oligocationic, ammonium-functionalized triarylphosphines
  作者：Dennis J. M. Snelders、Maxime A. Siegler、Lars S. von Chrzanowski、Anthony L. Spek、Gerard van Koten、Robertus J. M. Klein Gebbink

  DOI：10.1039/c0dt01105c

  日期：——

  triarylphosphines (L) is described. Complexes of the type PtX2(L)2 (X = Cl, I) have been isolated and characterized. For the hexa-meta-ammoniomethyl-substituted ligands [1]6+ and [2]6+, two ligands always occupy a trans-configuration with respect to each other in complexes of the type PtX2(L)2, while for the tri-para-ammoniomethyl-substituted ligand [7]3+, the trans/cis ratio is dependent on the ionic

  描述了低阳离子铵甲基和中性氨基甲基取代的三芳基膦（L）的Pt（II）配位化学。已分离出PtX 2（L）2（X = Cl，I）类型的复合物。对于六-间-氨基甲基取代的配体[ 1 ] 6+和[ 2 ] 6+，两个配体在PtX 2（L）2类型的复合物中始终相对于彼此占据反式构型，而对于三对-氨甲基取代的配体[ 7 ] 3+，反式/顺式比取决于溶液的离子强度。对于中性氨基甲基取代的配体未观察到此行为。在反式-[PtI 2（1）2 ] I 12的晶体结构中，膦配体[ 1 ] 6+的几何参数与基准配体PPh 3的类似配合物中所发现的几何参数非常相似，即反式- PtI 2（PPh 3）2，表明该复合物中不存在明显的空间充血增加。取而代之的是，这类膦配体的配位化学是由排斥库仑间配体相互作用决定的。
• Chemical Properties of Mononuclear and Dinuclear Phenylplatinum(II) Hydroxo Complexes with Cod Ligands. Transmetalation of Arylboronic Acids, Coupling of the Phenyl Ligands, and Carbonylation
  作者：Yuji Suzaki、Kohtaro Osakada

  DOI：10.1021/om060206u

  日期：2006.6.1

  aryl group transfer from boron to platinum. The accompanying formation of B(OH)3 has been confirmed by 11B1H} NMR spectroscopy. The reaction of BF3·Et2O with 1-BF4 followed by the addition of NH4Cl(aq) produces biphenyl and PtCl2(cod), which takes place possibly via a dinuclear intermediate. The cationic dinuclear complex 1-BF4 reacts with CO (1 atm) to form benzophenone. Since the reactions of AgBF4

  bpy与[Pt（Ph）（cod）} 2（μ-OH）]（BF 4）（1-BF 4； cod = 1,5-环辛二烯）在丙酮中的反应拆分了一个Pt-O键，得到了Pt（CH 2 COMe）（Ph）（cod）（2）和[Pt（Phpy （bpy）（cod）]（BF 4）（3-BF 4）的混合物，而在甲苯中的类似反应可生成3 -BF 4和Pt（OH）（Ph）（cod）（4）。络合物4是在溶液中获得的，由于其逐渐歧化而不能分离为分析纯的晶体，得到PtPh 2（cod）（5）。双核复合物1-BF 4与ArB（OH）2（Ar = Ph，C 6 H 2 F 3 -2,4,6）反应形成5和Pt（C 6 H 2 F 3 -2,4,6）（Ph）（cod） （6）分别通过芳基从硼转移到铂。B（OH）3的伴随形成已通过11 B 1 H} NMR光谱证实。BF 3 ·Et 2 O与1-BF 4的反应，然后添加NH 4
• Bis(2-diphenylphosphinoxynaphthalen-1-yl)methane: transition metal chemistry, Suzuki cross-coupling reactions and homogeneous hydrogenation of olefins
  作者：Benudhar Punji、Joel T. Mague、Maravanji S. Balakrishna

  DOI：10.1039/b510589g

  日期：——

  Transition metal complexes of bis(2-diphenylphosphinoxynaphthalen-1-yl)methane (1) are described. Bis(phosphinite) 1 reacts with Group 6 metal carbonyls, [Rh(CO)2Cl]2, anhydrous NiCl2, [Pd(C3H5)Cl]2/AgBF4 and Pt(COD)I2 to give the corresponding 10-membered chelate complexes 2, 3 and 5–8. Reaction of 1 with [Rh(COD)Cl]2 in the presence of AgBF4 affords a cationic complex, [Rh(COD)Ph2P(–OC10H6)(µ-CH2)(C10H6O–)PPh2-κP

  描述了双（2-二苯基次膦氧基萘-1-基）甲烷（1）的过渡金属络合物。双亚膦酸酯1与第6组反应金属羰基，铑[Rh（CO）2 CL] 2，无水的NiCl 2，[钯（C 3 H ^ 5）CL] 2 /的AgBF 4和Pt（COD）我2，得到相应的10-元螯合络合物2，3和5 –8。的反应1用的[Rh（COD）CL] 2中的AgBF存在4次得到的阳离子性络合物，铑[Rh（COD）博士2 P（-OC 10 ħ 6）（μ-CH 2）（C 10 H ^ 6 O-）PPH 2 -κ P，κP }] BF 4（4）。的治疗1与AUCL（SME 2）给出单核螯合络合物，[（AUCL）博士2 P（-OC 10 ħ 6）（μ-CH 2）（C 10 H ^ 6 O-）PPH 2 -κ P，κ P }]（9），以及一个双核配合物，[金（CL）μ-PH 2 P（-OC 10 ħ 6）（μ-CH 2）（C 10 H