2,3-diamino-5-hydrophenazinium chloride | 76190-35-7

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 二氮杂萘
• 英文名称: 2,3-diamino-5-hydrophenazinium chloride
• 英文别名: phenazine-2,3-diamine;hydrochloride
• CAS: 76190-35-7
• 化学式: C₁₂H₁₀N₄*ClH
• 分子量: 246.699
• InChiKey: QUTVCPKWEFTMQY-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.37
• 重原子数：
  17
• 可旋转键数：
  0
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  77.8
• 氢给体数：
  3
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  2,3-diamino-5-hydrophenazinium chloride 在 盐酸 、 sodium nitrite 作用下， 以 水 为溶剂， 以94.6 %的产率得到1H-1,2,3-triazole[4,5-d]phenazine
  参考文献：
  名称：

  A simple phenazine derivative fluorescence sensor for detecting formaldehyde

  摘要：

  我们开发了用于检测 HCHO 的荧光传感器。这种分子传感器具有很大的应用潜力。我们希望这种简单的荧光探针能在分子传感和食品化学领域引起广泛关注。

  DOI：

  10.1039/d2nj02586h
• 作为产物：
  描述：

  2,3-二氨基吩嗪 在 盐酸 作用下， 以 乙醇 、 水 为溶剂， 生成 2,3-diamino-5-hydrophenazinium chloride
  参考文献：
  名称：

  Highly selective and sensitive chemosensor based on 2,3-diaminophenazine hydrochloride for the detection of cyanide in pure water and its application in plant seed samples

  摘要：

  一种2,3-二氨基苯并吡嗪盐酸盐（Q1）在纯水中通过氢键形成对氰化物显示出超灵敏的可见光和荧光响应。

  DOI：

  10.1039/c8nj02316f

文献信息

• 一种吩嗪三唑类化合物的合成及其识别汞离子和钴离子的应用
  申请人：西北师范大学

  公开号：CN110563734B

  公开（公告）日：2022-05-13

  本发明公开了一种吩嗪三唑1H‑[1,2,3]三唑[4,5‑b]吩嗪，是以二氨基吩嗪盐酸盐和NaNO2为原料，在酸性环境中反应而得。该吩嗪三唑可以作为荧光传感器同时在含水30%的体系中对Hg2+、Co2+进行双功能检测：即在吩嗪三唑的DMSO/H2O体系中加入12种常见的重金属阳离子，只有Hg2+的加入可使主体溶液的荧光变为亮黄色，且只有Co2+的加入可使主体溶液的荧光变为蓝绿色。滴定实验表明，该吩嗪三唑对Hg2+荧光响应的最低检测限为4.96×10‑7M，对Co2+荧光响应的最低检测限为3.33×10‑8M，因而对Hg2+、Co2+的检测具有很高的灵敏度。
• A novel synthesis of 2,3-diaminophenazine
  作者：Luo Mei、Liu Shuang Tai、Feng Hai Tao、Sun Jie、Li Qian Rong

  DOI：10.1007/s11164-011-0366-z

  日期：2012.2

  The title heterocyclic 2,3-diaminophenazine (DAP) hydrochloride with the crystallization solvent were obtained from three different routes and their structures were determined by X-ray diffraction, elemental analysis, and IR.

  通过三种不同的途径获得了标题杂环 2,3-二氨基吩嗪（DAP）盐酸盐和结晶溶剂，并通过 X 射线衍射、元素分析和红外光谱测定了它们的结构。
• Rates of formation of some phenazines by cyclization of di- and monoimines of N-(2-aminophenyl)-p-benzoquinone
  作者：Norman P. Loveless、Keith C. Brown、Robert H. Horrocks

  DOI：10.1021/jo00319a027

  日期：1981.3
• Mn(II) and Zn(II) ions catalytic oxidation of o-phenylenediamine and characterization, X-ray crystal structure and solution study of the final products DAPH+Cl−·3H2O and [DAPH][Zn(dipicH)(dipic)]·4H2O
  作者：Khaled Ghasemi、Fatemeh Ghasemi、Ali Reza Rezvani、Ardeshir Shokrollahi、Masoud Refahi、Santiago García-Granda、Rafael Mendoza-Meroño

  DOI：10.1016/j.poly.2016.02.005

  日期：2016.5

  Compound DAPH(+)Cl(-)center dot 3H(2)O (1), and complexes Mn(dipic)(H2O)(3) (2) and [DAPH][Zn(dipicH)(dipic)center dot 4H(2)O (3), (dipicH(2) = 2,6-pyridinedicarboxylic acid and DAP = 2,3-diaminophenazine) were prepared from the reaction of MgCl2 center dot 4H(2)O and ZnCl2 with mixture of o-phenylenediamine (OPD) and 2,6-pyridinedicarboxylic acid in water. These compounds were characterized by elemental analysis, FTIR, H-1 NMR and UV-Vis spectroscopy. The solid-state structure of [DAPH][Zn(dipicH)(dipic)]center dot 4H(2)O (monoclinic, P2(1)/c) was determined by the single crystal X-ray diffraction method. The protonation constants of dipic and DAP, in all of probability protonated forms, the equilibrium constants for the dipic-DAP proton transfer system and the stoichiometry and stability constants of binary and ternary complexes of this system with Zn2+ and Mn2+ ions in aqueous solution were investigated by the potentiometric pH titration method. The stoichiometries of the most complex species in solution were compared with corresponding crystalline complexes in the solid state. (C) 2016 Elsevier Ltd. All rights reserved.
• 2,3-Diamino-5-hydrophenazinium Chloride Trihydrate
  作者：S. K. Brownstein、G. D. Enright

  DOI：10.1107/s010827019500103x

  日期：1995.8.15

  The three rings of the phenazinium molecule of the title compound, C12H11N4+.Cl-.3H(2)O, are all coplanar, and protonation occurs preferentially on an aromatic N atom rather than the amino N atoms. The C-C and C-N bond lengths of the unsubstituted side of the molecule agree closely with those of phenazine, but those on the substituted side differ from those of phenazine and 1,2-benzenediamine.