N,N'-bis-(2-methyl-aziridine-1-carbonyl)-hexanediyldiamine | 3901-51-7

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 有机碳酸及其衍生物
• 英文名称: N,N'-bis-(2-methyl-aziridine-1-carbonyl)-hexanediyldiamine
• 英文别名: N,N'-Bis-(2-methyl-aziridin-1-carbonyl)-hexandiyldiamin；N,N'-(hexane-1,6-diyl)bis-(2-methylaziridine-1-carboxamide)；1-Aziridinecarboxamide, N,N'-hexamethylenebis(2-methyl-；2-methyl-N-[6-[(2-methylaziridine-1-carbonyl)amino]hexyl]aziridine-1-carboxamide
• CAS: 3901-51-7
• 化学式: C₁₄H₂₆N₄O₂
• 分子量: 282.386
• InChiKey: QJMVVECCBAWCLZ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  0.7
• 重原子数：
  20
• 可旋转键数：
  7
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.86
• 拓扑面积：
  64.2
• 氢给体数：
  2
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  2-甲基氮丙啶 、 1,6-己二异氰酸酯 在 ice 作用下， 以 甲苯 为溶剂， 反应 25.0h， 以to give N,N′-(hexane-1,6-diyl)bis-(2-methylaziridine-1-carboxamide)的产率得到N,N'-bis-(2-methyl-aziridine-1-carbonyl)-hexanediyldiamine
  参考文献：
  名称：

  Grafted compounds formed from aziridinyl-containing compounds

  摘要：

  嫁接化合物是由反应(1)既含有氮杂环丙基基团又含有聚合基团的第一化合物与(2)至少含有一个酸性基团的第二化合物形成的。这种反应导致第一化合物上的氮杂环丙基团被第二化合物上的酸性基团打开，并形成一种连接第一化合物聚合基团与第二化合物的附着基团。在某些实施例中，第二化合物是具有多个酸性基团的聚合材料，第一化合物与第二化合物的反应产物导致嫁接共聚物的形成。

  公开号：

  US08796390B2

文献信息

• AZIRIDINE CROSSLINKING AGENTS FOR ACRYLIC ADHESIVES
  申请人：Zhu Peiwang

  公开号：US20100227969A1

  公开（公告）日：2010-09-09

  A crosslinkable, pre-adhesive composition is described comprising an acid-functional (meth)acrylate copolymer and an aziridine crosslinking agent, which when crosslinked provides a pressure-sensitive adhesive and pressure-sensitive adhesive articles.

  描述了一种可交联的预粘合组合物，包括酸官能团的（甲基）丙烯酸酯共聚物和环氧丙烷交联剂，当交联后可以提供一种压敏粘合剂和压敏粘合剂制品。
• Aziridinyl-containing compounds
  申请人：Clapper Jason D.

  公开号：US08779068B2

  公开（公告）日：2014-07-15

  Compounds are described that have both an aziridinyl group as well as a polymeric group. Methods of making these compounds are also described. The aziridinyl group of the compound can be reacted with an acidic group on a second compound resulting in the opening of the aziridinyl ring and the attachment of the polymeric group to the second compound.

  描述了同时具有环氧丙烷基团和聚合基团的化合物。还描述了制备这些化合物的方法。该化合物的环氧丙烷基团可以与第二种化合物上的酸性基团反应，导致环氧丙烷基团开环并将聚合基团附着到第二种化合物上。
• AZIRIDINYL-CONTAINING COMPOUNDS
  申请人：Clapper Jason D.

  公开号：US20130090434A1

  公开（公告）日：2013-04-11

  Compounds are described that have both an aziridinyl group as well as a polymeric group. Methods of making these compounds are also described. The aziridinyl group of the compound can be reacted with an acidic group on a second compound resulting in the opening of the aziridinyl ring and the attachment of the polymeric group to the second compound.

  本文介绍了同时具有环氧乙烷基团和聚合物基团的化合物，并描述了制备这些化合物的方法。该化合物的环氧乙烷基团可以与第二种化合物上的酸性基团反应，导致环氧乙烷环的开放，并将聚合物基团连接到第二种化合物上。
• GRAFTED COMPOUNDS FORMED FROM AZIRIDINYL-CONTAINING COMPOUNDS
  申请人：Clapper Jason D.

  公开号：US20130102731A1

  公开（公告）日：2013-04-25

  Grafted compounds are formed by reacting (1) a first compound having both an aziridinyl group and a polymeric group with (2) a second compound having at least one acidic group. This reaction results in the opening of the aziridinyl ring on the first compound by the acidic group on the second compound and the formation of an attachment group that connects polymeric group of the first compound to the second compound. In some embodiments, the second compound is a polymeric material having multiple acidic groups and the product of the reaction of the first compound with the second compound results in the formation of a grafted copolymer.

  嵌合化合物是由以下反应形成的：(1)具有氮杂环丙基基团和聚合基团的第一化合物与(2)至少具有一个酸性基团的第二化合物反应。该反应导致第二化合物上的酸性基团打开第一化合物上的氮杂环丙基环，并形成连接第一化合物的聚合基团和第二化合物的附着基团。在某些实施例中，第二化合物是具有多个酸性基团的聚合材料，第一化合物与第二化合物的反应产物导致嵌合共聚物的形成。
• Adhesive film for polarizing plate, polarizing plate and optical display comprising the same
  申请人：SAMSUNG SDI CO., LTD.

  公开号：US10358581B2

  公开（公告）日：2019-07-23

  An adhesive film for polarizing plates, a polarizing plate including the same, and an optical display including the same are provided. An adhesive film for polarizing plates is formed of an adhesive composition including a (meth)acrylic copolymer and a cellulose ester binder. The (meth)acrylic copolymer contains an alkyl group, a hydroxyl group, an alicyclic group, and a hetero-alicyclic group. The adhesive film has a modulus at 30° C. of about 100,000 Pa or more.

  本发明提供了一种偏光板用胶膜、包括该胶膜的偏光板和包括该胶膜的光学显示器。偏光板用胶膜由包括（甲基）丙烯酸共聚物和纤维素酯粘合剂的粘合剂组合物形成。甲基丙烯酸共聚物含有烷基、羟基、脂环基和杂脂环基。胶膜在 30° C 时的模量约为 100,000 Pa 或更大。