Triethoxy-<3-(heptafluorbutyryloxy)-propyl>-silan | 36957-50-3

• 分子结构分类: 有机化合物 - 有机卤素化合物 - 卤代烷
• 英文名称: Triethoxy-<3-(heptafluorbutyryloxy)-propyl>-silan
• 英文别名: Triethoxy-[3-(heptafluorbutyryloxy)-propyl]-silan；3-(Triethoxysilyl)propyl heptafluorobutanoate；3-triethoxysilylpropyl 2,2,3,3,4,4,4-heptafluorobutanoate
• CAS: 36957-50-3
• 化学式: C₁₃H₂₁F₇O₅Si
• 分子量: 418.381
• InChiKey: JPUSRVGXESIVLZ-UHFFFAOYSA-N

物化性质

• 沸点：
  295.0±40.0 °C(Predicted)
• 密度：
  1.231±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  3.8
• 重原子数：
  26
• 可旋转键数：
  13
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.92
• 拓扑面积：
  54
• 氢给体数：
  0
• 氢受体数：
  12

反应信息

• 作为产物：
  描述：

  三乙氧基硅烷 、 七氟丁酸烯丙酯 在 dihydrogen hexachloroplatinate 作用下， 以 异丙醇 为溶剂， 生成 Triethoxy-<3-(heptafluorbutyryloxy)-propyl>-silan
  参考文献：
  名称：

  Pomerantseva,M.G. et al., Journal of general chemistry of the USSR, 1972, vol. 42, # 4, p. 852 - 855

  摘要：

  DOI：

文献信息

• Effect of catalysts on the reaction of allyl esters with hydrosilanes
  作者：Z. V. Belyakova、M. G. Pomerantseva、L. A. Efimova、E. A. Chernyshev、P. A. Storozhenko

  DOI：10.1134/s1070363210040079

  日期：2010.4

  The reaction of hydrosilylation of allyl esters XOCH(2)CH=CH(2) (X = MeCO, CF(3)CO, C(3)F(7)CO) and PhOCH(2)CH=CH(2) with hydrosilanes HSiY(3) (Y = Cl, OEt) in the presence of the Speier catalyst, the Speier catalyst with additives, and of various nickel complexes was studied. The catalytic hydrosilylation reaction in the presence of the Speier catalyst is accompanied by the reduction. Additives to the Speier catalyst (vinyltriethoxysilane and some ethers) allow to suppress considerably the reduction reaction. In the presence of the studied nickel complexes mainly reduction and isomerization reactions occurred. The best nickel catalysts of hydrosilylation were the mixtures of NiCl(2) or Ni(acac)(2) with phosphine oxides. In contrast to allyl esters, the hydrosilylation of simple olefins proceeds easier, the content of the product of hydrosilylation in the reaction mixture reaches 94.3%.
• Pomerantseva,M.G. et al., Journal of general chemistry of the USSR, 1972, vol. 42, # 4, p. 852 - 855
  作者：Pomerantseva,M.G. et al.

  DOI：——

  日期：——