4-fluorocarbonyltetrathiafulvalene | 255870-35-0

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 乙烯基硫酯
• 英文名称: 4-fluorocarbonyltetrathiafulvalene
• 英文别名: 2-(1,3-Dithiol-2-ylidene)-1,3-dithiole-4-carbonyl fluoride
• CAS: 255870-35-0
• 化学式: C₇H₃FOS₄
• 分子量: 250.363
• InChiKey: YUQQXBDFWJRMDA-UHFFFAOYSA-N

物化性质

• 沸点：
  270.9±40.0 °C(Predicted)
• 密度：
  1.750±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  2.7
• 重原子数：
  13
• 可旋转键数：
  1
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  118
• 氢给体数：
  0
• 氢受体数：
  6

反应信息

• 作为反应物：
  描述：

  1-十六烷醇 、 4-fluorocarbonyltetrathiafulvalene 在 4-二甲氨基吡啶 作用下， 以 二氯甲烷 为溶剂， 反应 12.0h， 以93%的产率得到[2,2']Bi[[1,3]dithiolylidene]-4-carboxylic acid hexadecyl ester
  参考文献：
  名称：

  Fluorocarbonyltetrathiafulvalene: an effective building block for the production of tetrathiafulvalene esters and amides

  摘要：

  4-Fluorocarbonyltetrathiafulvalene has been synthesised under mild conditions, and has been reacted with alcohols and amides to furnish esters and amides in near quantitative yield. (C) 1999 Elsevier Science Ltd. All rights reserved.

  DOI：

  10.1016/s0040-4039(99)01804-3
• 作为产物：
  描述：

  tetrathiafulvalene-4-carboxylic acid 在 吡啶 、 三聚氟氰 作用下， 以 二氯甲烷 为溶剂， 反应 1.5h， 以83%的产率得到4-fluorocarbonyltetrathiafulvalene
  参考文献：
  名称：

  Fluorocarbonyltetrathiafulvalene: an effective building block for the production of tetrathiafulvalene esters and amides

  摘要：

  4-Fluorocarbonyltetrathiafulvalene has been synthesised under mild conditions, and has been reacted with alcohols and amides to furnish esters and amides in near quantitative yield. (C) 1999 Elsevier Science Ltd. All rights reserved.

  DOI：

  10.1016/s0040-4039(99)01804-3

文献信息

• Synthesis and Characterisation of Tetrathiafulvalenyl- and Ferrocenyl-Triphenylenes
  作者：Graeme Cooke、Abdulla Radhi、Neville Boden、Richard J Bushby、Zhibao Lu、Sarah Brown、Sarah L Heath

  DOI：10.1016/s0040-4020(00)00250-7

  日期：2000.5

  The synthesis, electrochemistry and mesogenic properties of novel tetrathiafulvalenyl- and ferrocenyl-triphenylenes are described. In all cases the juxtaposition of the hexa-alkyloxytriphenylene with a tetrathiafulvalene or ferrocene unit failed to give rise to derivatives displaying a discotic mesophase. Solution electrochemistry of derivatives 7 and 13 has revealed an interaction occurs between the dicationic state of the TTF moiety and the triphenylene nucleus. (C) 2000 Elsevier Science Ltd. All rights reserved.
• An electrochemically tuneable cyclodextrin-based molecular adapter
  作者：Graeme Cooke、Patrice Woisel、François Delattre、Marc Bria、James F. Garety、Shanika Gunatiliaka Hewage、Gouher Rabani

  DOI：10.1016/j.tetlet.2006.06.116

  日期：2006.9

  We report the synthesis of a cyclodextrin-based molecular adapter which has the propensity to form an electrochemically tuneable ternary complex with cyclophanes 2 or 3 and ferrocene 4 in non-aqueous and aqueous environments, respectively. (c) 2006 Elsevier Ltd. All rights reserved.
• Fluorocarbonyltetrathiafulvalene: an effective building block for the production of tetrathiafulvalene esters and amides
  作者：Graeme Cooke、Vincent M. Rotello、Abdulla Radhi

  DOI：10.1016/s0040-4039(99)01804-3

  日期：1999.12

  4-Fluorocarbonyltetrathiafulvalene has been synthesised under mild conditions, and has been reacted with alcohols and amides to furnish esters and amides in near quantitative yield. (C) 1999 Elsevier Science Ltd. All rights reserved.