(1,8-bis[(trimethylsilyl)amino]naphthalene)(dimethylaminobismuth) | 1176300-39-2

• 分子结构分类: 有机化合物 - 苯类化合物 - 萘
• 英文名称: (1,8-bis[(trimethylsilyl)amino]naphthalene)(dimethylaminobismuth)
• 英文别名: 1,8-C10H6(NSiMe3)2BiNMe2；Bismuth;dimethylazanide;trimethylsilyl-(8-trimethylsilylazanidylnaphthalen-1-yl)azanide；bismuth;dimethylazanide;trimethylsilyl-(8-trimethylsilylazanidylnaphthalen-1-yl)azanide
• CAS: 1176300-39-2
• 化学式: Bi*C₂H₆N*C₁₆H₂₄N₂Si₂
• 分子量: 553.608
• InChiKey: WYCKTKQKJMULBL-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6.76
• 重原子数：
  24
• 可旋转键数：
  4
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.44
• 拓扑面积：
  3
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  (1,8-bis[(trimethylsilyl)amino]naphthalene)(dimethylaminobismuth) 在 苯硅烷 作用下， 以 正己烷 为溶剂， 以60%的产率得到{[1,8-(NSiMe₃)₂C₁₀H₆]Bi}₂
  参考文献：
  名称：

  Organobismuth(III) and Dibismuthine Complexes Bearing N,N′-Disubstituted 1,8-Diaminonaphthalene Ligand: Synthesis, Structure, and Reactivity

  摘要：

  The organobismuth(III) and dibismuthine complexes bearing N,N'-disubstituted 1,8-diaminonaphthalene ligand were prepared. The reaction of LBiNMe2 (1) [L = 1,8-(NSiMe3)(2)C10H6] with ClSiMe3 results in the elimination of Me3SiNMe2, while PhCCH, Cp*H, and PhOH proceed via HNMe2 elimination and provide the complexes of LBiCl (2), LBiCCPh (3), LBiCp*(4), and LBiOPh (5), respectively. Reaction of 1 with AlMe3 in n-hexane yields LBiMe (6). Compound 1 reacts with diisopropylcarbodiimide and phenyl isocyanate under insertion at the Bi-NMe2 bond to give the addition products LBi(NiPr)(2)CNMe2 (7) and LBiN(Ph)C(O)NMe2 (8). The reactions of 1 with sulfur and PhSiH3 result in the formation of LBi-S-BiL (9) and LBi-BiL (10), respectively. Compounds 2-10 were characterized by elemental analysis, H-1, C-13, and Si-29 NMR spectroscopy, and X-ray crystallographic studies.

  DOI：

  10.1021/om300758s
• 作为产物：
  描述：

  1,8-bis(trimethylsilylamino)naphthalene 、 Bi(NMe₂)₃ 以 not given 为溶剂， 生成 (1,8-bis[(trimethylsilyl)amino]naphthalene)(dimethylaminobismuth)
  参考文献：
  名称：

  Nekoueishahraki, Bijan; Sarish, Sankaranarayana Pillai; Roesky, Herbert W., Angewandte Chemie - International Edition, 2009, vol. 48, p. 4517 - 4520

  摘要：

  DOI：

文献信息

• Synthesis and Structural Characterization of Heterobimetallic Bismuth Complexes with Main Group and Transition Metals
  作者：Bijan Nekoueishahraki、Anukul Jana、Herbert W. Roesky、Lallan Mishra、Daniel Stern、Dietmar Stalke

  DOI：10.1021/om900623w

  日期：2009.10.12

  corresponding complexes L1Bi(μ-O)ZrMeCp*2 (5) and L1Bi(μ-O)HfClCp*2 (6). Compounds 3, 4, and 6 represent the first examples of structurally characterized heterobimetallic complexes featuring the Bi−O−Ga, Bi−O−Ge, and Bi−O−Hf moiety, respectively. The crystal structural data show that the complexes 3 and 4 crystallize in the monoclinic space group P21/c and P21/n, while the complexes 5 and 6 are present

  制备了含有Bi-OM（M = Al，Ga，Ge，Zr，Hf）核的异双金属铋-氧桥联配合物。L 1 BiNMe 2（1）[L 1 = 1,8-C 10 H 6（NSiMe 3）2 ]与LM（Me）（OH）和LGe（OH）的反应（M = Al，Ga，L = CH（（CMe）NAr）2，Ar = 2,6- i Pr 2 C 6 H 3）通过消除HNMe 2进行并提供了配合物L 1 Bi（μ-O）MMeL（M = Al 2 ; Ga，3）和L 1 Bi（μ-O）GeL（4）。的过渡金属氢氧化物的Cp * 2 ZrMe（OH）1和Cp * 2的HfCl（OH）与反应1中Ñ分别-己烷和甲苯，下消除1个当量HNME的2，以产生相应的络合物大号1毕（μ- O）ZrMeCp * 2（5）和L 1 Bi（μ-O）HfClCp * 2（6）。化合物3，4和6表示了结构表征双核配合物配碧-O -镓，铋-O-Ge，
• Bismuthanylstibanes
  作者：Katherine M. Marczenko、Saurabh S. Chitnis

  DOI：10.1039/d0cc00254b

  日期：——

  are prepared in a one-step, high yield reaction, providing the first examples of neutral Bi–Sb σ-bonds in the solid state. DFT calculations indicate that the bis(silylamino)naphthalene scaffold is well-suited for supporting otherwise labile bonds. The reaction chemistry of the Bi–Sb bond is debuted by showing fission using NH3BH3 and insertion of a sulfur atom, the latter providing the first example

  一步法，高产率的反应制备了耐热性强的双变戊基苯乙烯，提供了固态中性Bi-Sbσ键的第一个实例。DFT计算表明，双（甲硅烷基氨基）萘支架非常适合支撑不稳定的键。通过显示使用NH 3 BH 3的裂变和插入一个硫原子，Bi-Sb键的反应化学开始出现，后者提供了Bi-S-Sb基序的第一个例子。
• C–H Bond Activation in a Molybdenumoxo-Bismuth Compound
  作者：Christina Knispel、Christian Limberg

  DOI：10.1021/om2004223

  日期：2011.7.25

  at the Bi center, which in turn triggers C–H activation at the methylcyclopentadienyl ligand through complex-induced proximity effects. This leads to a heterobimetallic molybdenum/bismuth compound, wherein the two metal centers are linked by an oxide bridge as well as by a σ,π-binding [μ-η5:η1-CH2(C5H4)]2– ligand.

  的反应〔LBiNMe 2 ]，我（L = [1,8-C 10 H ^ 6（NSiMe 3）2 ] 2- ），用[我的Cp 2 Mo═O]导致Mo═O组的协调在Bi中心，这又通过复合物诱导的邻近效应触发了甲基环戊二烯基配体上的C–H活化。这就导致了一个异核钼/铋化合物，其中所述两个金属中心由氧化物桥以及由σ相连，π结合[μ-η 5：η 1 -CH 2（C 5 H ^ 4）] 2 – 配体。
• Nekoueishahraki, Bijan; Sarish, Sankaranarayana Pillai; Roesky, Herbert W., Angewandte Chemie - International Edition, 2009, vol. 48, p. 4517 - 4520
  作者：Nekoueishahraki, Bijan、Sarish, Sankaranarayana Pillai、Roesky, Herbert W.、Stern, Daniel、Schulzke, Carola、Stalke, Dietmar

  DOI：——

  日期：——
• Organobismuth(III) and Dibismuthine Complexes Bearing N,N′-Disubstituted 1,8-Diaminonaphthalene Ligand: Synthesis, Structure, and Reactivity
  作者：Bijan Nekoueishahraki、Prinson P. Samuel、Herbert W. Roesky、Daniel Stern、Julia Matussek、Dietmar Stalke

  DOI：10.1021/om300758s

  日期：2012.9.24

  The organobismuth(III) and dibismuthine complexes bearing N,N'-disubstituted 1,8-diaminonaphthalene ligand were prepared. The reaction of LBiNMe2 (1) [L = 1,8-(NSiMe3)(2)C10H6] with ClSiMe3 results in the elimination of Me3SiNMe2, while PhCCH, Cp*H, and PhOH proceed via HNMe2 elimination and provide the complexes of LBiCl (2), LBiCCPh (3), LBiCp*(4), and LBiOPh (5), respectively. Reaction of 1 with AlMe3 in n-hexane yields LBiMe (6). Compound 1 reacts with diisopropylcarbodiimide and phenyl isocyanate under insertion at the Bi-NMe2 bond to give the addition products LBi(NiPr)(2)CNMe2 (7) and LBiN(Ph)C(O)NMe2 (8). The reactions of 1 with sulfur and PhSiH3 result in the formation of LBi-S-BiL (9) and LBi-BiL (10), respectively. Compounds 2-10 were characterized by elemental analysis, H-1, C-13, and Si-29 NMR spectroscopy, and X-ray crystallographic studies.