1,1'-Sulphonylbis(2-methoxyethane) | 7209-44-1

• 分子结构分类: 有机化合物 - 有机硫化合物 - 磺酰类
• 英文名称: 1,1'-Sulphonylbis(2-methoxyethane)
• 英文别名: Bis-2-methoxyethylsulfon；bis-(2-methoxy-ethyl) sulfone；Bis-(2-methoxy-aethyl)-sulfon；2.2'-Dimethoxy-diaethylsulfon；β.β'-Dimethoxy-diaethylsulfon；2,2'-dimethoxy-diethyl sulfone；1-Methoxy-2-(2-methoxyethanesulfonyl)ethane；1-methoxy-2-(2-methoxyethylsulfonyl)ethane
• CAS: 7209-44-1
• 化学式: C₆H₁₄O₄S
• 分子量: 182.241
• InChiKey: BXRHGJXTOFSMNX-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  -0.7
• 重原子数：
  11
• 可旋转键数：
  6
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  61
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为产物：
  描述：

  二乙烯基砜 、 sodium methylate 生成 1,1'-Sulphonylbis(2-methoxyethane)
  参考文献：
  名称：

  Alexander; McCombie, Journal of the Chemical Society, 1931, p. 1916

  摘要：

  DOI：

文献信息

• Nucleophile-mediated oxa-Michael addition reactions of divinyl sulfone – a thiol-free option for step-growth polymerisations
  作者：Simone Strasser、Christian Slugovc

  DOI：10.1039/c5cy01527h

  日期：——

  Triphenylphosphine and 4-dimethylaminopyridine promote the oxa-Michael addition reaction of alcohols and divinyl sulfone. Under solvent-free conditions, the reaction is particularly fast and allows for the preparation of polymers.

  三苯基膦和4-二甲基氨基吡啶促进了醇与二乙烯基砜的氧杂-迈克尔加成反应。在无溶剂条件下，反应特别快，可以制备聚合物。
• Ring–Chain Tautomerism of the 1,4-Oxathiane S,S-Dioxide Anion
  作者：Nashwa Hammad、Alan G. Sutherland

  DOI：10.1039/a901601e

  日期：——

  The ring-chain tautomer of the α-sulfonyl anion of 1,4-oxathiane S,S-dioxide can be trapped by addition of alkoxides to the vinyl sulfone; the scope of this reaction is explored.

  通过在乙烯基砜上添加烷氧基化合物，可以捕获 1,4-氧硫烷 S,S-二氧化物的δ-砜阴离子的环链同系物；探讨了这一反应的范围。
• ELECTRIC CURRENT-PRODUCING DEVICE HAVING SULFONE-BASED ELECTROLYTE
  申请人：Angell Charles Austen

  公开号：US20110020712A1

  公开（公告）日：2011-01-27

  Electrolytic solvents and applications of such solvents including electric current-producing devices. For example, a solvent can include a sulfone compound of R 1 —SO 2 —R 2 , with R 1 being an alkyl group and R 2 a partially oxygenated alkyl group, to exhibit high chemical and thermal stability and high oxidation resistance. For another example, a battery can include, between an anode and a cathode, an electrolyte which includes ionic electrolyte salts and a non-aqueous electrolyte solvent which includes a non-symmetrical, non-cyclic sulfone. The sulfone has a formula of R 1 —SO 2 —R 2 , wherein R 1 is a linear or branched alkyl or partially or fully fluorinated linear or branched alkyl group having 1 to 7 carbon atoms, and R 2 is a linear or branched or partially or fully fluorinated linear or branched oxygen containing alkyl group having 1 to 7 carbon atoms. The electrolyte can include an electrolyte co-solvent and an electrolyte additive for protective layer formation.

  电解质溶剂及其应用，包括电流产生装置。例如，溶剂可以包括R1—SO2—R2的磺酰化合物，其中R1是烷基，R2是部分氧化的烷基，以展现高化学和热稳定性以及高氧化抗性。另一个例子是，电池可以在阳极和阴极之间包括电解质，其中包括离子电解质盐和非水电解质溶剂，其中包括非对称、非环状的磺酰。磺酰的公式为R1—SO2—R2，其中R1是具有1至7个碳原子的线性或支链烷基或部分或完全氟化的线性或支链烷基，R2是具有1至7个碳原子的线性或支链或部分或完全氟化的含氧烷基。电解质可以包括电解质共溶剂和电解质添加剂以形成保护层。
• Porous film, separator including the same, electrochemical device including separator, and method of preparing porous film
  申请人：Samsung Electronics Co., Ltd.

  公开号：US11211671B2

  公开（公告）日：2021-12-28

  Provided herein are a porous film, a separator including the same, an electrochemical device including the separator, and a method of preparing the porous film. The porous film includes first cellulose nanofibers which is impregnated with a carbonate-based solvent-containing electrolyte solution and has a reaction heat of 150 J/g or less at a temperature ranging from about 30° C. to about 300° C., as measured by differential scanning calorimetry (DSC).

  本文提供了一种多孔薄膜、一种包括多孔薄膜的分离器、一种包括分离器的电化学装置以及一种制备多孔薄膜的方法。多孔薄膜包括第一纤维素纳米纤维，该纤维素纳米纤维浸渍在含碳酸盐溶剂的电解质溶液中，通过差示扫描量热仪（DSC）测量，在约 30°C 至约 300°C 的温度范围内，反应热为 150 焦耳/克或更低。
• Black, R. M.; Brewster, K.; Harrison, J. M., Phosphorus, Sulfur and Silicon and the Related Elements, 1992, vol. 71, # 1-4, p. 31 - 48
  作者：Black, R. M.、Brewster, K.、Harrison, J. M.、Stansfield, N.

  DOI：——

  日期：——