1,1'-bitetralyl | 1154-13-8

• 分子结构分类: 有机化合物 - 苯类化合物 - 四氢化萘
• 英文名称: 1,1'-bitetralyl
• 英文别名: Bitetralin；1-(1,2,3,4-tetrahydronaphthalen-1-yl)-1,2,3,4-tetrahydronaphthalene
• CAS: 1154-13-8
• 化学式: C₂₀H₂₂
• 分子量: 262.395
• InChiKey: ZKCXIIVGQKLRLW-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6
• 重原子数：
  20
• 可旋转键数：
  1
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.4
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

安全信息

• 海关编码：
  2902199090

反应信息

• 作为反应物：
  描述：

  1,1'-bitetralyl 生成 Naphthalene, decahydro-, 1,1'-bis
  参考文献：
  名称：

  摘要：

  DOI：
• 作为产物：
  描述：

  1,2,3,4-四氢-1-萘酚 生成 1,1'-bitetralyl
  参考文献：
  名称：

  Radical pathways of coal dissolution in hydrogen donor media. 2. .beta. Scission and 1,2 aryl migration reactions of radicals derived from methylindans and tetralin at 327-627.degree.C

  摘要：

  DOI：

  10.1021/jo01314a005

文献信息

• The Thermal Decomposition of<i>N</i>,<i>O</i>-Diacyl-<i>N</i>-<i>t</i>-butylhydroxylamines
  作者：Yuzuru Uchida、Yukinobu Hashimoto、Seizi Kozuka

  DOI：10.1246/bcsj.53.2309

  日期：1980.8

  Several N,O-diacyl-N-t-butylhydroxylamines and O-acyl-N-t-butylhydroxylamines were prepared, and their thermal decompositions were studied. The thermal decompositions of N,O-diacyl-N-t-butylhydroxylamines in tetralin gave substituted N-t-butylbenzamides, carboxylic acids, 1,1′-bitetralyl, and 1,2-dihydronaphthalene as the major products, together with small amounts of carbon dioxide, t-butylamine, and benzanilides. In the thermal decompositions of O-acyl-N-t-butylhydroxylamines, the products were t-butylamine, carboxylic acids, substituted N-t-butylbenzamides, 1,1′-bitetralyl, and 1,2-dihydronaphthalene.

  合成了几种N,O-二酰基-N-t-丁基羟胺和O-酰基-N-t-丁基羟胺，并研究了它们的热分解。在四氢萘中，N,O-二酰基-N-t-丁基羟胺的热分解产生了取代的N-t-丁基苯甲酰胺、羧酸、1,1'-双四氢萘和1,2-二氢萘，主要产物，同时还产生了少量的二氧化碳、t-丁胺和苯甲酰胺。在O-酰基-N-t-丁基羟胺的热分解中，产物包括t-丁胺、羧酸、取代的N-t-丁基苯甲酰胺、1,1'-双四氢萘和1,2-二氢萘。
• Intermediates in the dehydrogenation of 3,3′,4,4′-tetrahydro-1,1′-binaphthyl. Some hydrogenated 1,1′-binaphthyls and benzo[j]fluoranthenes
  作者：Malcolm Crawford、V. R. Supanekar

  DOI：10.1039/j39680002328

  日期：——

  3,3′,4,4′-Tetrahydro-1,1′-binaphthyl can undergo dehydrogenation and cyclodehydrogenation simultaneously. Possible intermediates with various degrees of hydrogenation have been prepared and characterised. Some of these have been recognised as intermediates and thus the respective courses of the two parallel reactions have been traced.

  3，3′，4，4′-四氢-1，1′-联萘可同时进行脱氢和环脱氢。已经制备并表征了具有不同氢化度的可能的中间体。这些中的一些已经被认为是中间体，因此已经追踪了两个平行反应的各自过程。
• Partially fluorinated heterocyclic compounds. Part 24. [1] A plausible mechanism for the formation of the fischer indole product from acetophenone 1,3,4,5,6,7,8-heptafluoro-2-naphthylhydrazone in which o-fluorine is lost
  作者：Gerald M. Brooke

  DOI：10.1016/s0022-1139(00)81061-1

  日期：1988.7

  Acetophenone 1,3,4,5,6,7,8-heptafluoro-2-naphthylhydrazone (1) reacts in tetralin at reflux to give 4,5,6,7,8,9-hexafluoro-2-phenylbenz[e]indole (2) as the major product, accompanied by other materials including acetophenone 3,4,5,6,7,8-hexafluoro-2-naphthylhydrazone (4) which is proposed as the true precursor to the Fisher indole product (2) since it gives (2) under the same conditions. The presence

  苯乙酮1,3,4,5,6,7,8-七氟-2-萘hydr在回流中在四氢萘中反应，得到4,5,6,7,8,9-六氟-2-苯基苯并[e]吲哚（2）为主要产品，并伴有其他材料，包括苯乙酮3,4,5,6,7,8-六氟-2-萘hydr（4），被提议为Fisher吲哚产品（2）的真正前体因为它在相同条件下给出（2）α四氢萘酮的在反应混合物中的存在提供了线索到还原消除的F -从（1）。
• Galust'yan, G. G., Journal of Organic Chemistry USSR (English Translation), 1986, vol. 22, # 4, p. 811 - 815
  作者：Galust'yan, G. G.

  DOI：——

  日期：——
• Meier, Herbert; Konnerth, Ursula; Graw, Sylvia, Chemische Berichte, 1984, vol. 117, # 1, p. 107 - 126
  作者：Meier, Herbert、Konnerth, Ursula、Graw, Sylvia、Echter, Toni

  DOI：——

  日期：——