trineopentylindium | 106136-98-5

• 分子结构分类: 有机化合物 - 有机金属化合物 - 有机过渡后金属化合物
• 英文名称: trineopentylindium
• 英文别名: Trisneopentylindium
• CAS: 106136-98-5
• 化学式: C₁₅H₃₃In
• 分子量: 328.247
• InChiKey: WAKXDUIFFXWYTN-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.62
• 重原子数：
  16
• 可旋转键数：
  6
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  trineopentylindium 以 氘代苯 、 正戊烷 为溶剂， 生成 Chlorobis(2,2-dimethylpropyl)indigane
  参考文献：
  名称：

  Reactions of Neopentylindium(III) Derivatives with Isopropylphosphorus Compounds

  摘要：

  A 1:1 mixture of In(CH2CMe3)(3) and HP(i-Pr)(2) at room temperature undergoes a very slow hydrocarbon elimination reaction to form [(Me3CCH2)(2)InP(i-Pr)(2)](2) and neopentane. The indium phosphide [(Me3CCH2)(2)InP(i-Pr)(2)](2) has also been prepared by reacting KIn(CH2CMe3)(3)H with CIP(i-Pr)(2) in pentane. When pentane solutions of these reagents were combined at -78 degreesC and then maintained at similar to 20 degreesC for 2 days, [(Me3CCH2)(2)InP(i-Pr)(2)](2), (Me3CCH2)(3)In .P(H)(i-Pr)(2), (Me3CCH2)(3)In .P-2(i-Pr)(4), (Me3CCH2)(3)In .P(CH2CMe3)(i-Pr)(2), H-2, indium metal, and KCl were observed. The formation of all products is explained by a set of experimentally verified reactions. An X-ray structural study of [(Me3CCH2)(2)InP(i-Pr)(2)](2) shows each molecule to have an unusual puckered four-membered In2P2 core.

  DOI：

  10.1021/om0101902
• 作为产物：
  描述：

  以 苯 为溶剂， 生成 trineopentylindium
  参考文献：
  名称：

  Reactions of Neopentylindium(III) Derivatives with Isopropylphosphorus Compounds

  摘要：

  A 1:1 mixture of In(CH2CMe3)(3) and HP(i-Pr)(2) at room temperature undergoes a very slow hydrocarbon elimination reaction to form [(Me3CCH2)(2)InP(i-Pr)(2)](2) and neopentane. The indium phosphide [(Me3CCH2)(2)InP(i-Pr)(2)](2) has also been prepared by reacting KIn(CH2CMe3)(3)H with CIP(i-Pr)(2) in pentane. When pentane solutions of these reagents were combined at -78 degreesC and then maintained at similar to 20 degreesC for 2 days, [(Me3CCH2)(2)InP(i-Pr)(2)](2), (Me3CCH2)(3)In .P(H)(i-Pr)(2), (Me3CCH2)(3)In .P-2(i-Pr)(4), (Me3CCH2)(3)In .P(CH2CMe3)(i-Pr)(2), H-2, indium metal, and KCl were observed. The formation of all products is explained by a set of experimentally verified reactions. An X-ray structural study of [(Me3CCH2)(2)InP(i-Pr)(2)](2) shows each molecule to have an unusual puckered four-membered In2P2 core.

  DOI：

  10.1021/om0101902

文献信息

• The mixed alkyl gallium or indium N,N,N-trimethylpropylenediaminedithiocarbamates. Crystal structure of diethyl(N,N′,N′-trimethylpropylenediamine) dithiocarbamatoindium(III)
  作者：S.W. Haggata、M. Azad Malik、M. Motevalli、Paul O'Brien

  DOI：10.1016/0022-328x(95)05934-h

  日期：1996.4

  A series of compounds with the general formula (R2MS2CNMe(CH2)3NMe2, RMe, Et, Np, C5H11; MGa, In) have been synthesized and characterized. Their low melting points and reasonable volatility makes them potentially suitable as single-source precursors for III/VI materials. The crystal structure of Et2InS2CNMe(CH2)3NMe2 has been determined.

  合成并表征了一系列具有通式（R 2 MS 2 CNMe（CH 2）3 NMe 2，RMe，Et，Np，C 5 H 11；MGa，In）的化合物。它们的低熔点和合理的挥发性使它们有可能适合作为III / VI材料的单源前体。已经确定了Et 2 InS 2 CNMe（CH 2）3 NMe 2的晶体结构。
• Synthesis and molecular structures of R(Me3CCH2)2In · E(SiMe3)3 (R=Me3CCH2, E = P or As; R = Me, E = P).
  作者：Mark F. Self、Andrew T. McPhail、Leonidas J. Jones、Richard L. Wells

  DOI：10.1016/s0277-5387(00)84739-7

  日期：1994.1

  Combining P(SiMe 3 ) 3 or As(SiMe 3 ) 3 with (Me 3 CCH 2 ) 3 In in a 1:1 mole ratio yields simple adducts (Me 3 CCH 2 ) 3 In·P(SiMe 3 ) 3 ( I ) and (Me 3 CCH 2 ) 3 In·As(SiMe 3 ) 3 ( II ), respectively. Addition of (Me 3 CCH 2 ) 2 InCl to a diethyl ether solution of LiP(SiMe 3 ) 2 produces Me(Me 3 CCH 2 ) 2 In·P(SiMe 3 ) 3 ( III ). X-ray crystal structures have been determined for compounds ( I ), (

  摘要以1：1的摩尔比将P（SiMe 3）3或As（SiMe 3）3与（Me 3 CCH 2）3 In结合，可得到简单的加合物（Me 3 CCH 2）3 In·P（SiMe 3）3（ I）和（Me 3 CCH 2）3 In·As（SiMe 3）3（II）。将（Me 3 CCH 2）2 InCl加到LiP（SiMe 3）2的乙醚溶液中可制得Me（Me 3 CCH 2）2 In·P（SiMe 3）3（III）。已经确定了化合物（I），（II）和（III）的X射线晶体结构。
• Synthesis and characterization of amphoteric ligands including the crystal and molecular structure of [(Me3SiCH2)2InPPh2]2
  作者：O.T. Beachley、John P. Kopasz、Hongming Zhang、William E. Hunter、Jerry L. Atwood

  DOI：10.1016/0022-328x(87)80389-3

  日期：1987.5

  analyses, cryoscopic molecular weight measurements and 1H NMR, 31P NMR and IR spectroscopic data. An X-ray structural study was carried out to define the nature of [(Me3SiCH2)2InPPh2]2 in the solid state. The compounds were prepared either by a thermolysis reaction between the group 13 metal trialkyl and PPh2H or by a metathetical reaction between the dialkylmetal halide and KPPh2. Cryoscopic molecular

  制备了新的两性配体（Me 3 SiCH 2）2 GaPPh 2，（Me 3 SiCH 2）2 InPPh 2和（Me 3 CCH 2）2 InPPh 2并通过元素分析，低温分子量测量和1 H表征NMR，31 P NMR和IR光谱数据。进行了X射线结构研究，以确定[（Me 3 SiCH 2）2 InPPh 2 ] 2的性质在固态。通过第13族金属三烷基与PPh 2 H之间的热解反应或通过二烷基金属卤化物与KPPh 2之间的易位反应来制备化合物。低温分子量测量和31 P NMR光谱数据表明，新化合物以单体-二聚体平衡混合物的形式存在于苯溶液中。[（Me 3 SiCH 2）2 InPPh 2 ] 2的无色晶体在每个晶胞中包含两个离散的二聚体分子。所述化合物以三斜晶系空间群P，具有下列晶胞参数：一个10.323（4），b 11.113（5），c 21.509（8）Å，α83.85 （5），β86.66（6），γ83
• Chemistry of In(C₅H₅)₃ and Some Heteroleptic Organoindium(III) Derivatives. Crystal and Molecular Structures of In(C₅H₅)₃, (C₅H₅)₃In·PPh₃, and (Me₃CCH₂)₂In(C₅H₅)
  作者：O. T. Beachley,、David J. MacRae、Andrey Yu. Kovalevsky,、Yuegang Zhang、Xue Li

  DOI：10.1021/om0202322

  日期：2002.10.1

  CH2CMe3) in THF solution provided R2In(C5H5) and RIn(C5H5)2. These heteroleptic organoindium(III) compounds have been isolated as analytically pure crystalline solids, but in THF solution they form equilibrium mixtures of the adducts of InR3, R2In(C5H5), RIn(C5H5)2, and In(C5H5)3, as appropriate. Crystals of [In(C5H5)3]n, (C5H5)3In·PPh3, and [(Me3CCH2)2In(C5H5)]n were characterized by single-crystal

  在没有外部加热的情况下，由InCl 3和Li（C 5 H 5）在THF溶液中高产率地制备了纯In（C 5 H 5）3。整齐在（C 5 H ^ 5）3容易分解，在150℃，以形成在（C 5 H ^ 5）（S）和环戊二烯作为主要产品，而苯的悬浮液在回流条件下分解。In（C 5 H 5）3与PPh 3形成可分离的1：1加合物，但NMe 3，THF和Et 2O不形成稳定的加合物。与InR 3（R = Me和CH 2 CMe 3）在THF溶液中进行配体再分布反应，得到R 2 In（C 5 H 5）和RIn（C 5 H 5）2。这些杂化的有机铟（III）化合物已分离为分析纯的结晶固体，但在THF溶液中，它们形成InR 3，R 2 In（C 5 H 5），RIn（C 5 H 5）2，和In（C 5 H 5）3， 作为适当的。用单晶表征[In（C 5 H 5）3 ] n，（C 5 H 5）3 In·PPh
• Selenium Insertion into the M−C Bond (M = Ga, In):  Syntheses and X-ray Crystal Structures of [Np₂In(μ-SeNp)]₂, [(Me₃SiCH₂)₂Ga(μ-SeCH₂SiMe₃)]₂, [(Mes)C₆H₇N·Ga-μ-Se]₂, and (Mes)₂C₆H₇N·GaSeMes (Np = CH₂C(CH₃)₃, Mes = 2,4,6-Me₃C₆H₂, C₆H₇N = 4-Picoline)
  作者：Hamid Rahbarnoohi、Richard L. Wells、Louise M. Liable-Sands、Glenn P. A. Yap、Arnold L. Rheingold

  DOI：10.1021/om970402o

  日期：1997.9.1

  selenium resulted in the formation of novel dimeric compounds with the general formula [R2M(μ-SeR)]2 (M = In, R = Np (1); M = Ga, R = CH2SiMe3 (2)) in a nearly quantitative yield. Reaction of GaMes3 (Mes = 2,4,6-Me3C6H2) with 2 mol of elemental Se, and subsequent addition of 4-picoline (C6H7N), resulted in the isolation of three compounds, [(Mes)C6H7N·Ga-μ-Se]2 (3), (Mes)2C6H7N·GaSeMes (4), and Se2Mes2

  InNp 3（Np = CH 2 CMe 3）和Ga（CH 2 SiMe 3）3与元素硒的独立1：1反应导致形成通式[R 2 M（μ-SeR）的新型二聚化合物] 2（M ＝ In，R ＝ Np（1）； M ＝ Ga，R ＝ CH 2 SiMe 3（2））以接近定量的产率。GaMes 3（Mes = 2,4,6-Me 3 C 6 H 2）与2 mol元素硒的反应，然后添加4-picoline（C 6 H 7N），导致分离出[[Mes）C 6 H 7 N·Ga-μ-Se] 2（3），（Mes）2 C 6 H 7 N·GaSeMes（4）和Se 2这三种化合物混乱2。化合物3是硒桥联的二聚体，在二聚体单元中具有两个二配位的Se原子和两个4-甲基吡啶（C 6 H 7 N）分子。在相关工作中，InNp 3与S 2 Ph 2反应得到二聚体化合物[Np 2 In（μ-SPh）] 2（5），消除了NpSPh。的合成和表征1