5-amino-4-methyl-tropolone | 412324-04-0

• 分子结构分类: 有机化合物 - 碳氢化合物衍生物 - 环庚三烯酮
• 英文名称: 5-amino-4-methyl-tropolone
• 英文别名: 5-Amino-4-methyl-tropolon；2,4,6-Cycloheptatrien-1-one,5-amino-2-hydroxy-4-methyl-；5-amino-2-hydroxy-6-methylcyclohepta-2,4,6-trien-1-one
• CAS: 412324-04-0
• 化学式: C₈H₉NO₂
• 分子量: 151.165
• InChiKey: WRIFEPMYCKIQSN-UHFFFAOYSA-N

物化性质

• 沸点：
  267.2±40.0 °C(Predicted)
• 密度：
  1.269±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  0.4
• 重原子数：
  11
• 可旋转键数：
  0
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.12
• 拓扑面积：
  63.3
• 氢给体数：
  2
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  5-amino-4-methyl-tropolone 在 硫酸 、 sodium nitrite 作用下， 生成 5-hydroxy-4-methyl-tropolone
  参考文献：
  名称：

  Spectral characteristic of infrared radiations of some acupoint and non-acupoint areas in human arm surface

  摘要：

  Using infrared spectrum detective device, we experiment on Neiguan, Laogong and Hegu acupoints of seven adult volunteers as well as contrastive points beside ones. We get 63 infrared spectrums. The experiment outcome tells us that the differences of the Intensities among individuals are great, and so are the differences between acupoint and non-acupoint areas. However, the differences of spectral character are small, which indicates that infrared radiations of human body are based on the same biophysical fundament.

  DOI：

  10.1007/bf03182835
• 作为产物：
  描述：

  4-methyl-5-nitro-tropolone 在 sodium hydroxide 、 sodium dithionite 作用下， 生成 5-amino-4-methyl-tropolone
  参考文献：
  名称：

  459. Purpurogallin。第八部分 β-甲基对苯二酚的硝化和亚硝化

  摘要：

  DOI：

  10.1039/jr9510002067

文献信息

• Nozoe et al., Sci. Rep. Tohoku Univ., Ser. 1: Phys., Chem., Astron., 1951, vol. <I>35, p. 242,259
  作者：Nozoe et al.

  DOI：——

  日期：——
• Akroyd et al., Journal of the Chemical Society, 1954, p. 286,290
  作者：Akroyd et al.

  DOI：——

  日期：——
• Spectral characteristic of infrared radiations of some acupoint and non-acupoint areas in human arm surface
  作者：Guanghong Ding、Wei Yao、Junhao Chu、Xueyong Shen、Zhiming Huang、Huansheng Cheng、Hui Liu、Shenzhang Wang、Jing Yang、Hu Wei、Lun Fei

  DOI：10.1007/bf03182835

  日期：2001.4

  Using infrared spectrum detective device, we experiment on Neiguan, Laogong and Hegu acupoints of seven adult volunteers as well as contrastive points beside ones. We get 63 infrared spectrums. The experiment outcome tells us that the differences of the Intensities among individuals are great, and so are the differences between acupoint and non-acupoint areas. However, the differences of spectral character are small, which indicates that infrared radiations of human body are based on the same biophysical fundament.
• 459. Purpurogallin. Part VIII. Nitration and nitrosation of β-methyltropolone
  作者：Robert D. Haworth、Phillip R. Jefferies

  DOI：10.1039/jr9510002067

  日期：——