O,O′-(1,1′-methylenedinaphthalen-2-yl) bis(dimethylcarbamothioate) | 1357478-92-2

• 分子结构分类: 有机化合物 - 苯类化合物 - 萘
• 英文名称: O,O′-(1,1′-methylenedinaphthalen-2-yl) bis(dimethylcarbamothioate)
• 英文别名: 2,2'-bis(N,N-dimethylthiocarbamoyloxy)-1,1'-methylenedinaphthalene；O-[1-[[2-(dimethylcarbamothioyloxy)naphthalen-1-yl]methyl]naphthalen-2-yl] N,N-dimethylcarbamothioate
• CAS: 1357478-92-2
• 化学式: C₂₇H₂₆N₂O₂S₂
• 分子量: 474.648
• InChiKey: PFDSDMCTRNXLIZ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  7.1
• 重原子数：
  33
• 可旋转键数：
  6
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.19
• 拓扑面积：
  89.1
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  O,O′-(1,1′-methylenedinaphthalen-2-yl) bis(dimethylcarbamothioate) 反应 0.17h， 以60%的产率得到2,2'-thio-di(1-naphthyl)methane
  参考文献：
  名称：

  Synthesis of dinaphthylmethane derivatives containing carbamothioyloxy and carbamoylsulfanyl groups

  摘要：

  Chemical modification of 1,1'-methylenedinaphthalen-2-ol and 1,1'-methylenedinaphthalen-2,7-diol, including thiocarbamoylation, Newman-Kwart rearrangement, and hydride reduction, afforded dinaphthylmethane derivatives containing carbamothioyloxy, carbamoylsulfanyl, and sulfanyl groups.

  DOI：

  10.1134/s1070428014040083
• 作为产物：
  描述：

  1,1-亚甲基-2-萘酚 、 二甲氨基硫代甲酰氯 在 potassium carbonate 作用下， 生成 O,O′-(1,1′-methylenedinaphthalen-2-yl) bis(dimethylcarbamothioate)
  参考文献：
  名称：

  二萘甲基甲烷和间苯二酚[4]芳烃的多官能螯合物衍生物：螯合物结构及其受体能力的合成与关系

  摘要：

  摘要 亚甲基双（萘-2-醇/ -2,7-二醇）和rccc-间苯二酚杯[4]芳烃的官能化已在OH基上提供了一系列衍生物，它们分别具有1对，2对或4对螯合离子载体取代基组成给电子原子（O，S，N，P）的组合。通过液体萃取研究了配体的结构特征对其识别和结合过渡金属阳离子（Cd 2 +，Ag +，Hg 2+）的能力的影响。

  DOI：

  10.1134/s1070363220080137

文献信息

• Transformation of mononuclear aryl thiocarbamates to cyclic disulfides
  作者：O. S. Serkova、D. V. Tarasenko、L. K. Vasyanina、A. I. Stash、V. I. Maslennikova

  DOI：10.1007/s11172-016-1510-0

  日期：2016.7

  Thermolysis of the melt of octakis(O-thiocarbamoyl)tetra(C-phenethyl)resorcinarene in a microwave reactor afforded a cavitand, the upper rim of which was formed due to the formation of disulfide bridges between the neighboring benzene rings of the resorcinarene framework. The reaction of 2,2’-bis(carbamoylthio)-1,1’-methylenedinaphthalene with LiAlH4 gave a tricyclic derivative, in which the naphthalene

  八（O-硫代氨基甲酰基）四（C-苯乙基）间苯二酚在微波反应器中熔体的热解提供了一个空洞，其上缘是由于间苯二酚骨架的相邻苯环之间形成二硫桥而形成的。2,2'-双(氨基甲酰硫基)-1,1'-亚甲基萘与LiAlH4反应生成三环衍生物，其中萘环由亚甲基和二硫键结合。通过该化合物的单晶 X 射线衍射分析证实了 2,2'-二硫茚的结构。
• Complex formation between sulfur-containing dinaphthylmethanes and Pd and Nd salts
  作者：D. V. Tarasenko、O. S. Serkova、I. I. Levina、O. A. Begmyradova、V. I. Maslennikova

  DOI：10.1134/s1070363215100357

  日期：2015.10
• Polyvariant modification of di- and tetrahydroxydinaphthylmethanes
  作者：Vera I. Maslennikova、Olga S. Serkova、Lyudmila V. Shelenkova、Larisa K. Vasyanina、Dmitrii V. Tarasenko、Edward E. Nifantiev

  DOI：10.1016/j.tetlet.2011.12.034

  日期：2012.2

  Modification of di- and tetrahydroxydinaphthylmethanes yielded a new family of aromatic systems differing by the nature, the number, and positions of functional groups and by the mode of fusion of the naphthalene nuclei. The effect of the starting dinaphthylmethane structure on the modification route was demonstrated. (C) 2011 Elsevier Ltd. All rights reserved.
• Polyfunctional Chelate Derivatives of Dinaphthylmethane and Resorcincalix[4]arene: Synthesis and Relationship between Chelate Structure and Its Acceptor Ability
  作者：O. S. Serkova、A. V. Kamkina、I. Yu. Toropygin、V. I. Maslennikova

  DOI：10.1134/s1070363220080137

  日期：2020.8

  methylenebis(naphthalene-2-ol/-2,7-diol) and rccc-resorcincalix[4]arene has given a series of their derivatives at the OH groups with 1, 2, or 4 pairs of chelate ionophore substituents differing in the combination of the constituting electron-donating atoms (O, S , N, P). The effect of the structural features of the ligand on its ability to recognize and bind transition metals cations (Cd2+, Ag+, Hg2+) has been studied

  摘要 亚甲基双（萘-2-醇/ -2,7-二醇）和rccc-间苯二酚杯[4]芳烃的官能化已在OH基上提供了一系列衍生物，它们分别具有1对，2对或4对螯合离子载体取代基组成给电子原子（O，S，N，P）的组合。通过液体萃取研究了配体的结构特征对其识别和结合过渡金属阳离子（Cd 2 +，Ag +，Hg 2+）的能力的影响。
• Synthesis of dinaphthylmethane derivatives containing carbamothioyloxy and carbamoylsulfanyl groups
  作者：O. S. Serkova、D. V. Tarasenko、L. K. Vasyanina、O. A. Begmyradova、V. I. Maslennikova、E. E. Nifant’ev

  DOI：10.1134/s1070428014040083

  日期：2014.4

  Chemical modification of 1,1'-methylenedinaphthalen-2-ol and 1,1'-methylenedinaphthalen-2,7-diol, including thiocarbamoylation, Newman-Kwart rearrangement, and hydride reduction, afforded dinaphthylmethane derivatives containing carbamothioyloxy, carbamoylsulfanyl, and sulfanyl groups.