1-allyl-2-naphthylamine | 34884-68-9

• 分子结构分类: 有机化合物 - 苯类化合物 - 萘
• 英文名称: 1-allyl-2-naphthylamine
• 英文别名: 1-allylnaphthalen-2-amine；1-Prop-2-enylnaphthalen-2-amine
• CAS: 34884-68-9
• 化学式: C₁₃H₁₃N
• 分子量: 183.253
• InChiKey: SNWUHPSEGYRGIW-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.6
• 重原子数：
  14
• 可旋转键数：
  2
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.08
• 拓扑面积：
  26
• 氢给体数：
  1
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  1-allyl-2-naphthylamine 生成 1-allyl-2-naphthol
  参考文献：
  名称：

  Marcinkiewicz,S., Bulletin de l'Academie Polonaise des Sciences, Serie des Sciences Chimiques, 1971, vol. 19, p. 603 - 607

  摘要：

  DOI：
• 作为产物：
  描述：

  N-allyl-2-naphthylamine 在 三氟化硼乙醚 作用下， 以 5,5-dimethyl-1,3-cyclohexadiene 为溶剂， 反应 7.0h， 以65%的产率得到1-allyl-2-naphthylamine
  参考文献：
  名称：

  Synthesis of Azepine- and Azocine-Annulated Heterocycles by Aromatic Aza-Claisen Rearrangement and Ring-Closing Metathesis

  摘要：

  Syntheses of hitherto unreported azepine- and azocine-annulated heterocycles have been developed in excellent yields via a catalyzed aromatic aza-Claisen rearrangement followed by ring-closing metathesis using Grubbs first-generation catalyst.

  DOI：

  10.1055/s-0029-1218620

文献信息

• [EN] PHOSPHINYL AMIDINE COMPOUNDS, METAL COMPLEXES, CATALYST SYSTEMS, AND THEIR USE TO OLIGOMERIZE OR POLYMERIZE OLEFINS<br/>[FR] COMPOSÉS DE PHOSPHINYLAMIDINE, COMPLEXES DE MÉTAL, SYSTÈMES DE CATALYSEUR, ET LEUR UTILISATION POUR OLIGOMÉRISER OU POLYMÉRISER DES OLÉFINES
  申请人：CHEVRON PHILLIPS CHEMICAL CO

  公开号：WO2011082192A1

  公开（公告）日：2011-07-07

  N2-phosphinyl amidine compounds, N2-phosphinyl amidinates, N2-phosphinyl amidine metal salt complexes, N2-phosphinyl amidinate metal salt complexes are described. Methods for making N2-phosphinyl amidine compounds, N2-phosphinyl amidinates, N2-phosphinyl amidine metal salt complexes, and N2-phosphinyl amidinate metal salt complexes are also disclosed. Catalyst systems utilizing the N2-phosphinyl amidine metal salt complexes and N2-phosphinyl amidinate metal salt complexes are also disclosed along with the use of the N2-phosphinyl amidine compounds, N2-phosphinyl amidinates, N2-phosphinyl amidine metal salt complexes, and N2-phosphinyl amidinate metal salt complexes for the oligomerization and/or polymerization of olefins.

  描述了N2-膦胺化合物、N2-膦胺酸盐、N2-膦胺金属盐络合物、N2-膦胺酸盐金属盐络合物。还公开了制备N2-膦胺化合物、N2-膦胺酸盐、N2-膦胺金属盐络合物和N2-膦胺酸盐金属盐络合物的方法。还公开了利用N2-膦胺金属盐络合物和N2-膦胺酸盐金属盐络合物的催化剂系统，以及利用N2-膦胺化合物、N2-膦胺酸盐、N2-膦胺金属盐络合物和N2-膦胺酸盐金属盐络合物进行烯烃的寡聚和/或聚合的用途。
• Visible-Light Sensitization of Vinyl Azides by Transition-Metal Photocatalysis
  作者：Elliot P. Farney、Tehshik P. Yoon

  DOI：10.1002/anie.201308820

  日期：2014.1.13

  Irradiation of vinyl and aryl azides with visible light in the presence of Ru photocatalysts results in the formation of reactive nitrenes, which can undergo a variety of CN bond‐forming reactions. The ability to use low‐energy visible light instead of UV in the photochemical activation of azides avoids competitive photodecomposition processes that have long been a significant limitation on the synthetic

  在 Ru 光催化剂存在下用可见光照射乙烯基和芳基叠氮化物会导致反应性氮烯的形成，氮烯可以进行各种 C  N 键形成反应。在叠氮化物的光化学活化中使用低能可见光代替紫外线的能力避免了竞争性光分解过程，而竞争性光分解过程长期以来一直是这些反应合成应用的重大限制。
• Hg(OTf)2-BINAPHANE-Catalyzed Enantioselective Anilino Sulfonamide Allyl Alcohol Cyclization
  作者：Hirofumi Yamamoto、Elisabeth Ho、Kosuke Namba、Hiroshi Imagawa、Mugio Nishizawa

  DOI：10.1002/chem.201001656

  日期：——

  Chiral ligands: Hg(OTf)2‐catalyzed cyclization of anilino sulfonamide allyl alcohol is described; this reaction gives 2‐vinyl indoline derivatives in good yields and excellent enantioselectivity by using a chiral BINAPHANE ligand (see scheme).

  手性配体：Hg（OTf）2催化苯胺磺酰胺烯丙醇的环化反应；通过使用手性BINAPHANE配体，该反应可得到高收率和出色的对映选择性的2-乙烯基二氢吲哚衍生物（参见方案）。
• [EN] PHOSPHINYL FORMAMIDINE COMPOUNDS, METAL COMPLEXES, CATALYST SYSTEMS, AND THEIR USE TO OLIGOMERIZE OR POLYMERIZE OLEFINS<br/>[FR] COMPOSÉS PHOSPHINYL FORMAMIDINE, COMPLEXES MÉTALLIQUES, SYSTÈMES DE CATALYSEUR, ET LEUR UTILISATION POUR OLIGOMÉRISER OU POLYMÉRISER DES OLÉFINES
  申请人：CHEVRON PHILLIPS CHEMICAL CO

  公开号：WO2015094207A1

  公开（公告）日：2015-06-25

  N2-phosphinyl formamidine compounds and N2-phosphinyl formamidine metal salt complexes are described. Methods for making N2-phosphinyl formamidine compounds and N2-phosphinyl formamidine metal salt complexes are also disclosed. Catalyst systems utilizing the N2-phosphinyl formamidine metal salt complexes are also disclosed along with the use of the N2-phosphinyl amidine compounds and N2- phosphinyl amidinate metal salt complexes for the oligomerization and/or polymerization of olefins.

  描述了N2-磷酰基甲酰胺化合物和N2-磷酰基甲酰胺金属盐配合物。还公开了制备N2-磷酰基甲酰胺化合物和N2-磷酰基甲酰胺金属盐配合物的方法。还公开了利用N2-磷酰基甲酰胺金属盐配合物的催化剂体系，以及利用N2-磷酰基胺化合物和N2-磷酰基胺金属盐配合物进行烯烃的寡聚和/或聚合的用途。
• [EN] BENZODIOXOLE, BENZOFURAN, DIHYDROBENZOFURAN, AND BENZODIOXANE MELATONERGIC AGENTS<br/>[FR] LES BENZODIOXOLE, BENZOFURAN, DIHYDROBENZOFURAN, ET BENZODIOXANE: DES AGENTS MELATONERGIQUES
  申请人：BRISTOL-MYERS SQUIBB COMPANY

  公开号：WO1998025606A1

  公开（公告）日：1998-06-18

  (EN) Novel derivatives of benzodioxole, benzofuran, 2,3-dihydrobenzofuran, and benzodioxane are useful as melatonergic agents.(FR) La présente invention concerne de nouveaux dérivés des benzodioxole, benzofuran, 2,3-dihydrobenzofuran, et benzodioxane qui conviennent particulièrement comme agents mélatonergiques.

  这段话的中文翻译如下： (EN) Novel derivatives of benzodioxole, benzofuran, 2,3-dihydrobenzofuran, and benzodioxane are useful as melatonergic agents. (中) 新型苯并二氧杂环、苯并呋喃、2,3-二氢苯并呋喃和苯并二氧杂环的衍生物可作为褪黑素能药物使用。 (FR) La présente invention concerne de nouveaux dérivés des benzodioxole, benzofuran, 2,3-dihydrobenzofuran, et benzodioxane qui conviennent particulièrement comme agents mélatonergiques. (中) 本发明涉及苯并二氧杂环、苯并呋喃、2,3-二氢苯并呋喃和苯并二氧杂环的新型衍生物，特别适用于作为褪黑素能药物。