tris(4-N,N-dimethylaminophenyl)antimony | 201742-17-8

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: tris(4-N,N-dimethylaminophenyl)antimony
• 英文别名: tris(4-N,N-dimethylaminophenyl)stibine；tris(4-dimethylaminophenyl)stibine；tris-(4-dimethylamino-phenyl)-stibine；Tris-(4-dimethylamino-phenyl)-antimon；Tris-(4-dimethylamino-phenyl)-stibin；Tris(4-(dimethylamino)phenyl)antimony；4-bis[4-(dimethylamino)phenyl]stibanyl-N,N-dimethylaniline
• CAS: 201742-17-8
• 化学式: C₂₄H₃₀N₃Sb
• 分子量: 482.272
• InChiKey: IEUSPXVQVBDXPY-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.4
• 重原子数：
  28
• 可旋转键数：
  6
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.25
• 拓扑面积：
  9.7
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  tris(4-N,N-dimethylaminophenyl)antimony 在 碘 作用下， 以 氯仿 为溶剂， 生成 4,4',4''-(diiodo-l5-stibanetriyl)tris(N,N-dimethylaniline)
  参考文献：
  名称：

  Keck, J. M., Zeitschrift fur Naturforschung. Teil B: Chemie, Biochemie, Biophysik, Biologie, 1972, vol. 27, p. 596 - 599

  摘要：

  DOI：
• 作为产物：
  描述：

  tris(4-N,N-dimethylaminophenyl)stibonium iodide 以 水 为溶剂， 反应 0.5h， 以60%的产率得到tris(4-N,N-dimethylaminophenyl)antimony
  参考文献：
  名称：

  Synthesis and Structure of Antimony Complex Compounds [(4-N,N-Me2C6H4)3MeSb]I and [(4-N,N-Me2C6H4)3MeSb]2[Hg2I6]·2DMSO

  摘要：

  DOI：

  10.1134/s1070363221070148

文献信息

• Electron spin resonance spectra of dinitrosyltriorganoantimony-ironbromides in solution
  作者：J. Schmidt、W.L. Dorn、R. Kramolowsky

  DOI：10.1016/s0020-1693(00)94858-8

  日期：1973.1

  ESR data of the complexes Fe(NO)2SbR3Br (R = C2H5, C6H5, and 4—(H3C)2NC6H4) in solution are presented. The observed hyperfine coupling due to bromine and antimony is interpreted including second order contributions. Nuclear quadrupole effects are discussed and found to be detectable in the antimony hyperfine pattern.

  给出了溶液中Fe（NO）2SbR3Br（R = C2H5，C6H5和4-（H3C）2NC6H4）配合物的ESR数据。解释了由于溴和锑引起的超精细偶合，包括二阶贡献。讨论了核四极效应，发现在锑超细粉中可检测到。
• Woods, L. W., Iowa State College Journal of Science, 1944, vol. 19, p. 61 - 63
  作者：Woods, L. W.

  DOI：——

  日期：——
• Gmelin Handbuch der Anorganischen Chemie, Gmelin Handbook: Sb: Org.Comp.1, 1.1.1.1.7, page 87 - 96
  作者：

  DOI：——

  日期：——
• Two-step synthesis of triarylmetals (As, Sb, Bi) starting from the metal oxides and 2,6-dimethoxybenzenethiol
  作者：Masanori Wada、Satoko Natsume、Shinobu Suzuki、Uo Akira、Michiaki Nakamura、Shuichi Hayase、Tatsuo Erabi

  DOI：10.1016/s0022-328x(97)00421-x

  日期：1997.12

  Reported here is a new synthetic method of triarylmetals MAr3 (M = As, Sb, Bi). It is composed of two-step reactions starting from the metal oxides: (1) A reaction of the metal oxide with 2,6-dimethoxybenzenethiol Phi SH [Phi = 2,6-(MeO)(2)C6H3] in the presence of acid to give the thiolatometals M(S Phi)(3), and (2) A reaction of M(S Phi)(3) with organolithium reagent LiAr to give MAr3 (Ar = Ph, 4-MeC6H4, 4-Me2NC6H4, Phi). Since Phi SH is odorless and crystalline, most of it can be recovered after the reactions without difficulty for repeated usages. The intermediates M(S Phi)(3) are also crystalline and inert against hydrolysis. (C) 1997 Elsevier Science S.A.
• Synthesis and structure of tris(4-N,N-dimethylaminophenyl) antimony(V) dicarboxylates and diaroxides
  作者：V. V. Shaturin、V. S. Senchurin、O. K. Shaturina、O. V. Chagarova

  DOI：10.1134/s0036023611070254

  日期：2011.7

  Tris(4-N,N-dimethylaminophenyl) antimony dicarboxylates (4-Me(2)NC(6)H(4))(3)Sb[OC(O)R](2) (R = C(6)H(4)Me-2 (I), C(6)H(4)Me-4 (II), CH=CHPh (III)), (4-Me(2)NC(6)H(4))(3)Sb[OC(O)C(O)O] (IV), and (4-Me(2)NC(6)H(4))(3)Sb[OC(O)C(6)Cl(4)C(O)O] (V)) and tris(4-N,N-dimethylaminophenyl)antimony diaroxides (4-Me(2)NC(6)H(4))(3)Sb(OAr)(2) (Ar = Ph (VI), C(6)H(2)Br(3)-2,4,6 (VII), and C(6)H(3)Me(2)-2,6 (VIII)) have been synthesized by the reaction of tris(4-N,N-dimethylaminophenyl) antimony in ether with carboxylic acids or phenols in the presence of hydrogen peroxide. According to X-ray diffraction analysis data, the Sb atoms in compounds I and VII have a distorted trigonal-bipyramidal coordination, and the axial OSbO angles are 175.4(1)degrees and 177.9(3)degrees, respectively. The Sb-O bond lengths are 2.133(3) and 2.142(2) angstrom in compound I and 2.089(5) angstrom in compound VII.