N-methylnaphtho[1,8-de][1,3,2]dioxaphosphinine-2-amine | 1035979-30-6

• 分子结构分类: 有机化合物 - 苯类化合物 - 萘
• 英文名称: N-methylnaphtho[1,8-de][1,3,2]dioxaphosphinine-2-amine
• 英文别名: N-methyl-2,4-dioxa-3-phosphatricyclo[7.3.1.05,13]trideca-1(12),5,7,9(13),10-pentaen-3-amine
• CAS: 1035979-30-6
• 化学式: C₁₁H₁₀NO₂P
• 分子量: 219.18
• InChiKey: ZBNYAQIDAHGNIV-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.8
• 重原子数：
  15
• 可旋转键数：
  1
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.09
• 拓扑面积：
  30.5
• 氢给体数：
  1
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  N-methylnaphtho[1,8-de][1,3,2]dioxaphosphinine-2-amine 、 双(2-甲氧基苯基)氯化膦 在 三乙胺 作用下， 以 甲苯 为溶剂， 生成 Bis(2-methoxyphenyl)-(3-methylimino-2,4-dioxa-3lambda5-phosphatricyclo[7.3.1.05,13]trideca-1(12),5,7,9(13),10-pentaen-3-yl)phosphane 、 2,4-Dioxa-3-phosphatricyclo[7.3.1.05,13]trideca-1(12),5,7,9(13),10-pentaen-3-yl-bis(2-methoxyphenyl)-methylimino-lambda5-phosphane
  参考文献：
  名称：

  WO2008/77908

  摘要：

  公开号：
• 作为产物：
  描述：

  2-氯萘并[1,8-d,e][1,3,2]二噁磷 、 甲胺 在 三乙胺 作用下， 以 四氢呋喃 、 甲苯 为溶剂， 生成 N-methylnaphtho[1,8-de][1,3,2]dioxaphosphinine-2-amine
  参考文献：
  名称：

  WO2008/77908

  摘要：

  公开号：

文献信息

• LIGANDS AND CATALYST SYSTEMS THEREOF FOR THE CATALYTIC OLIGOMERIZATION OF OLEFINIC MONOMERS
  申请人：DE BOER Eric Johannes Maria

  公开号：US20090062493A1

  公开（公告）日：2009-03-05

  The present invention relates to a ligand and its use in a catalyst for the oligomerization of olefinic monomers, the ligand having the general formula (I); P(R 4 )—P(R 1 )(R 2 )═N(R 3 )  (I) wherein: the R 1 group is selected from a hydrocarbyl, substituted hydrocarbyl, heterohydrocarbyl and substituted heterohydrocarbyl group; the R 2 group is selected from hydrocarbyl, substituted hydrocarbyl, heterohydrocarbyl and substituted heterohydrocarbyl groups; the R 3 is selected from hydrogen, a hydrocarbyl group, a substituted hydrocarbyl group, a heterohydrocarbyl group, a substituted heterohydrocarbyl group, a silyl group or derivative thereof; the R 4 group is an optionally substituted alkylenedioxy, alkylenedimercapto or alkylenediamino structure which is bound to the phosphorus atom through the two oxygen, sulphur or nitrogen atoms of the alkylenedioxy, alkylenedimercapto or alkylenediamino structure or an optionally substituted arylenedioxy, arylenedimercapto or arylenediamino structure which is bound to the phosphorus atom through the two oxygen, sulphur or nitrogen atoms of the arylenedioxy, arylenedimercapto or arylenediamino structure.

  本发明涉及一种配体及其在烯烃单体寡聚催化剂中的应用，该配体具有通式（I）： P(R4)—P(R1)(R2)═N(R3)  (I) 其中： R1基团选自烃基、取代烃基、杂原子烃基和取代杂原子烃基； R2基团选自烃基、取代烃基、杂原子烃基和取代杂原子烃基； R3选自氢、烃基、取代烃基、杂原子烃基、取代杂原子烃基、硅基或其衍生物； R4基团为可选取代的烷二氧、烷二硫或烷二氨基结构，通过烷二氧、烷二硫或烷二氨基结构的两个氧、硫或氮原子与磷原子结合，或者为可选取代的芳二氧、芳二硫或芳二氨基结构，通过芳二氧、芳二硫或芳二氨基结构的两个氧、硫或氮原子与磷原子结合。
• Catalyst Systems for the Catalytic Oligomerization of Olefinic Monomers
  申请人：DE BOER Eric Johannes Maria

  公开号：US20110288356A1

  公开（公告）日：2011-11-24

  The present invention relates to a ligand and its use in a catalyst for the oligomerization of olefinic monomers, the ligand comprising the product formed by reacting i) a compound having the general formula (III); (R 1 )(R 2 )P—N(R 3 )—R 5 (III); and ii) a compound of the formula X—P(R 4 ), preferably at a temperature in the range of from −30 to 200° C.

  本发明涉及一种配体及其在寡聚烯烃单体催化剂中的使用，该配体包括通过反应以下化合物形成的产物：i) 具有通式（III）的化合物；(R1)(R2)P—N(R3)—R5(III)；和ii) 通式为X—P(R4)的化合物，优选温度在-30至200℃范围内。
• Ligands and catalyst systems thereof for the catalytic oligomerization of olefinic monomers
  申请人：Shell Oil Company

  公开号：US08022007B2

  公开（公告）日：2011-09-20

  The present invention relates to a ligand and its use in a catalyst for the oligomerization of olefinic monomers, the ligand having the general formula (II); P(R1)(R2)—P(R4)═N(R3)  (II) wherein: the R1 group is selected from a hydrocarbyl, substituted hydrocarbyl, heterohydrocarbyl and substituted heterohydrocarbyl group; the R2 group is selected from a hydrocarbyl, substituted hydrocarbyl, heterohydrocarbyl and substituted heterohydrocarbyl group; the R3 is selected from hydrogen, a hydrocarbyl group, a substituted hydrocarbyl group, a heterohydrocarbyl group, a substituted heterohydrocarbyl group, a silyl group or derivative thereof; the R4 group is an optionally substituted alkylenedioxy, alkylenedimercapto or alkylenediamino structure which is bound to the phosphorus atom through the two oxygen, sulphur or nitrogen atoms of the alkylenedioxy, alkylenedimercapto or alkylenediamino structure or an optionally substituted arylenedioxy, arylenedimercapto or arylenediamino structure which is bound to the phosphorus atom through the two oxygen, sulphur or nitrogen atoms of the arylenedioxy, arylenedimercapto or arylenediamino structure.

  本发明涉及一种配体及其在寡聚烯烃单体催化剂中的应用，该配体具有一般式（II）： P(R1)(R2)-P(R4)=N(R3)  (II) 其中：R1基从烃基、取代烃基、杂烃基和取代杂烃基组中选择；R2基从烃基、取代烃基、杂烃基和取代杂烃基组中选择；R3选择自氢、烃基、取代烃基、杂烃基、取代杂烃基、硅基或其衍生物；R4基是一个可选择取代的烷二氧、烷二硫或烷二氨基结构，通过烷二氧、烷二硫或烷二氨基结构的两个氧、硫或氮原子结合到磷原子上，或者是一个可选择取代的芳二氧、芳二硫或芳二氨基结构，通过芳二氧、芳二硫或芳二氨基结构的两个氧、硫或氮原子结合到磷原子上。
• Catalyst systems for the catalytic oligomerization of olefinic monomers
  申请人：De Boer Eric Johannes Maria

  公开号：US08680220B2

  公开（公告）日：2014-03-25

  The present invention relates to a ligand and its use in a catalyst for the oligomerization of olefinic monomers, the ligand having the general formula (VI): (R9)(R10)P—N(R3)—P(R4)  (VI) wherein: the R9 and R10 groups are independently selected from optionally substituted alkyl or heteroalkyl groups; the R3 group is selected from hydrogen, a hydrocarbyl group, a substituted hydrocarbyl group, a heterohydrocarbyl group, a substituted heterohydrocarbyl group, a silyl group or derivative thereof; the R4 group is an optionally substituted alkylenedioxy or alkylenedimercapto structure which is bound to the phosphorus atom through the two oxygen or sulphur atoms of the alkylenedioxy or alkylenedimercapto structure or an optionally substituted arylenedioxy or arylenedimercapto structure which is bound to the phosphorus atom through the two oxygen or sulphur atoms of the arylenedioxy or arylenedimercapto structure.

  本发明涉及一种配体及其在寡聚烯烃单体催化剂中的使用，所述配体具有通式(VI):(R9)(R10)P—N(R3)—P(R4)  (VI)，其中：R9和R10基团分别选自可选取代的烷基或杂烷基基团；R3基团选自氢、烃基基团、取代烃基基团、杂氢烃基团、取代杂氢烃基团、硅基或其衍生物；R4基团是通过烷基二氧或烷基二硫原子或取代的芳基二氧或芳基二硫原子与磷原子结合的可选取代的烷基二氧或烷基二硫结构或可选取代的芳基二氧或芳基二硫结构。
• CATALYST SYSTEMS FOR THE CATALYTIC OLIGOMERIZATION OF OLEFINIC MONOMERS
  申请人：Shell Oil Company

  公开号：US20140107304A1

  公开（公告）日：2014-04-17

  The present invention relates to a ligand and its use in a catalyst for the oligomerization of olefinic monomers, the ligand having the general formula (IV); (R 8 )(R 1 )P—N(R 3 )—P(R 4 )  (IV).

  本发明涉及一种配体及其在寡聚烯烃单体催化剂中的应用，该配体具有通式（IV）；(R8)(R1)P—N(R3)—P(R4)  (IV)。