1,3-bis-butylamino-propan-2-ol | 815605-34-6

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: 1,3-bis-butylamino-propan-2-ol
• 英文别名: 1,3-Bis(butylamino)propan-2-ol；1,3-bis(butylamino)propan-2-ol
• CAS: 815605-34-6
• 化学式: C₁₁H₂₆N₂O
• 分子量: 202.34
• InChiKey: IWAYCVLIWPVYTR-UHFFFAOYSA-N

物化性质

• 熔点：
  43-44 °C(Solv: ethyl ether (60-29-7))
• 沸点：
  114-119 °C(Press: 0.5 Torr)
• 密度：
  0.896±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  1.3
• 重原子数：
  14
• 可旋转键数：
  10
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  44.3
• 氢给体数：
  3
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  聚合甲醛 、 膦酸二辛酯 、 1,3-bis-butylamino-propan-2-ol 生成
  参考文献：
  名称：

  Synthesis and Properties of the Novel Functionalized Aminophosphoryl Compounds

  摘要：

  DOI：

  10.1080/10426500213451
• 作为产物：
  描述：

  正丁胺 、 环氧氯丙烷 生成 1,3-bis-butylamino-propan-2-ol
  参考文献：
  名称：

  Aminomethyloxazolidones Derived from Substituted Diamino-2-propanols

  摘要：

  DOI：

  10.1021/ja01640a010

文献信息

• Polyamines, synthesis process thereof and use of same for the selective elimination of H2S from a gaseous effluent comprising CO2
  申请人：IFP Energies nouvelles

  公开号：US10710021B2

  公开（公告）日：2020-07-14

  The invention concerns novel polyamines having formula (I) obtained from the reaction between a polyol diglycidylether and piperazine: in which n is a whole number between 0 and 30, R1 has different forms, R2 has formula (g5), and R2 has formula (g6) when n=0 R6: H, C1-C6 alkyl or hydroxyalkyl radical, R7: C1-C6 alkyl or hydroxyalkyl radical, R6 and R7 may be connected together to form a heterocycle having 5, 6, 7 or 8 atoms when R6 is other than H, R8: H, C1-C4 alkyl or hydroxyalkyl radical. The invention also concerns their preparation method and their use in an absorbing solution based on amines in order to selectively eliminate H2S from a gaseous effluent containing H2S and CO2.

  本发明涉及由多元醇二缩水甘油醚和哌嗪反应得到的具有式 (I) 的新型多胺： 其中 n 为 0 至 30 之间的整数，R1 具有不同的形式，R2 具有式 (g5)，当 n=0 时，R2 具有式 (g6) R6：H、C1-C6 烷基或羟烷基、 R7：C1-C6 烷基或羟基烷基、 R6 和 R7 可连接在一起，形成具有 5、6、7 或 8 个原子的杂环，当 R6 不是 H R8：H、C1-C4 烷基或羟烷基。 本发明还涉及它们的制备方法及其在基于胺的吸收溶液中的用途，以便从含有 H2S 和 CO2 的气态流出物中选择性地消除 H2S。
• Polyamines, synthesis method thereof and use thereof for the selective elimination of H2S from a gaseous effluent comprising CO2
  申请人：IFP Energies Nouvelles

  公开号：US11136434B2

  公开（公告）日：2021-10-05

  Polyamines of formula (I), their preparation method and their use in an absorbing solution based on amines in order to selectively eliminate H2S from a gaseous effluent containing H2S and CO2, which polyamines are obtained by a reaction between piperazine and an epihalohydrin or a 1,3-dihalo-2-propanol

  式(I)的多胺、其制备方法及其在基于胺的吸收液中的用途，以选择性地消除含有H2S和CO2的气态流出物中的H2S，这些多胺是通过哌嗪与表卤代醇或1,3-二卤-2-丙醇反应得到的
• Synthesis and Acid-Base Properties of  -Aminophosphoryl Compounds
  作者：S. V. Zakharov、G. Kh. Nuriazdanova、A. R. Garifzyanov、V. I. Galkin、R. A. Cherkasov

  DOI：10.1023/b:rugc.0000042422.61124.b3

  日期：2004.6

  alpha-Aminophosphoryl compounds of the phosphonate, phosphine oxide, and alpha,omega-bis(phosphine oxide) series and some of their thiophosphoryl analogs were synthesized. Potentiometric measurements of the pK(a) of the conjugate acids revealed an insignificant effect of variation of substituents on the phosphorus, nitrogen, and alpha-carbon atoms on the basicity of the phosphorylated amines. The latter are weak bases. Organophosphorus groups decrease the basicity of the amines by almost 5 pK(a) units. The role of the hydrophobic effect and intramolecular H-bonding in the obtained substances was discussed.
• NOUVELLES POLYAMINES, LEUR PROCEDE DE SYNTHESE ET LEUR UTILISATION POUR L'ELIMINATION SELECTIVE DE L'H2S D'UN EFFLUENT GAZEUX COMPRENANT DU CO2
  申请人：IFP Energies nouvelles

  公开号：EP3397671B1

  公开（公告）日：2020-02-12
• NOVEL POLYAMINES, SYNTHESIS PROCESS THEREOF AND USE OF SAME FOR THE SELECTIVE ELIMINATION OF H2S FROM A GASEOUS EFFLUENT COMPRISING CO2
  申请人：IFP ENERGIES NOUVELLES

  公开号：US20180369743A1

  公开（公告）日：2018-12-27

  The invention concerns novel polyamines having formula (I) obtained from the reaction between a polyol diglycidylether and piperazine: in which n is a whole number between 0 and 30, R 1 has different forms, R 2 has formula (g 5 ), and R 2 has formula (g 6 ) when n=0 R 6 : H, C1-C6 alkyl or hydroxyalkyl radical, R 7 : C1-C6 alkyl or hydroxyalkyl radical, R 6 and R 7 may be connected together to form a heterocycle having 5, 6, 7 or 8 atoms when R 6 is other than H, R 8 : H, C1-C4 alkyl or hydroxyalkyl radical. The invention also concerns their preparation method and their use in an absorbing solution based on amines in order to selectively eliminate H 2 S from a gaseous effluent containing H 2 S and CO 2 .