2-methyl-1,4-bis[4-(4-butenyloxy)benzoyl]hydroquinone | 188639-00-1

• 分子结构分类: 有机化合物 - 苯丙烷和聚酮 - 缩酚酸和缩酚酸环醚类
• 英文名称: 2-methyl-1,4-bis[4-(4-butenyloxy)benzoyl]hydroquinone
• 英文别名: 2-methyl-1,4-bis[4-(4-butenyloxy)benzoyloxy]benzene；[4-(4-But-3-enoxybenzoyl)oxy-3-methylphenyl] 4-but-3-enoxybenzoate
• CAS: 188639-00-1
• 化学式: C₂₉H₂₈O₆
• 分子量: 472.538
• InChiKey: WXNNNKPEWFUTGI-UHFFFAOYSA-N

物化性质

• 沸点：
  634.8±55.0 °C(Predicted)
• 密度：
  1.153±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  7.3
• 重原子数：
  35
• 可旋转键数：
  14
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.17
• 拓扑面积：
  71.1
• 氢给体数：
  0
• 氢受体数：
  6

反应信息

• 作为反应物：
  描述：

  2-methyl-1,4-bis[4-(4-butenyloxy)benzoyl]hydroquinone 在 N-溴代丁二酰亚胺(NBS) 、 偶氮二异丁腈 作用下， 以 四氢呋喃 、 二甲基亚砜 、 甲苯 、 苯 为溶剂， 反应 28.0h， 生成 endo-5-{[[2',5'-bis[(4''-(n-(perfluoropropyl)butoxy)benzoyl)oxy]benzyl]oxy]carbonyl}bicyclo[2.2.1]hept-2-ene
  参考文献：
  名称：

  Induction of Smectic Layering in Nematic Liquid Crystals Using Immiscible Components. 5. Laterally Attached Side-Chain Liquid Crystalline Poly(norbornene)s and Their Low Molar Mass Model Compounds with Short Fluorocarbon Segments

  摘要：

  5-[[[2',5'-Bis[(4"-n-((perfluoroalkyl)alkoxy)benzoyl)oxy]benzyl]oxy]carbonyl]bicyclo[2.2.1]hept-2-enes with short fluorocarbon segments were polymerized by ring-opening metathesis polymerization in THF at room temperature using Mo(CHCMe2Ph)(N-2,6-'Pr2Ph)(O'Bu)(2) as the initiator. Although hydrocarbon and fluorocarbon segments as short as three methylenic units each induce smectic layering in the corresponding 2,5-bis{[4'-(n-(perfluoroalkyl)alkoxy)benzoyl]oxy}toluene model compounds, the polymers require at least eight and three, or five and four methylenic units in the hydrocarbon and fluorocarbon segments, respectively, to organize into smectic layers; polymers with shorter hydrocarbon and/or fluorocarbon segments are nematic.

  DOI：

  10.1021/ma0113430
• 作为产物：
  描述：

  4-(3-丁烯氧基)苯甲酸乙酯 在 4-二甲氨基吡啶 、 sodium hydroxide 、 对甲苯磺酸 、 N,N'-二环己基碳二亚胺 作用下， 以 乙醇 、 二氯甲烷 、 水 为溶剂， 反应 24.0h， 生成 2-methyl-1,4-bis[4-(4-butenyloxy)benzoyl]hydroquinone
  参考文献：
  名称：

  使用不混溶成分在向列液晶中诱导近晶分层。1. 横向连接的侧链液晶聚（降冰片烯）及其具有烃/氟烃取代基的低摩尔质量类似物

  摘要：

  与仅表现出向列中间相的烃类似物相比，聚{5-[[[[2',5'-双[(4''-(n-(二甲基甲硅烷氧基)烷氧基)苯甲酰基)氧基]苄基]氧基]羰基]双环[2.2.1]hept-2-ene}及其低摩尔质量模型化合物表现出近晶C中间相。由于向列液晶可以通过不仅用碳氟化合物链段而且用柔性硅氧烷链段终止它们的烃取代基而被迫成层，这支持了这样的假设，即含有线性碳氟化合物链段的两亲分子的近晶介晶主要是由于碳氢化合物的不混溶性和碳氟化合物段，而不是“介晶全氟烷基棒”的形状持久性。2、5-双[(4'-(n-(低聚二甲基甲硅烷氧基)烷氧基)苯甲酰基)氧基]甲苯模拟聚合物形成的相和它们转变的一般温度，因此是聚合物的极好模型。5-{[[2',5'-双[(4''-(n-(低聚二甲基甲硅烷氧基)烷氧基)苯甲酰基)氧基]苄基]氧基]...

  DOI：

  10.1021/ja963687p

文献信息

• SHAPE MEMORY MAIN-CHAIN SMECTIC-C ELASTOMERS
  申请人：Mather Patrick T.

  公开号：US20090240075A1

  公开（公告）日：2009-09-24

  Shape memory main-chain smectic-C elastomers are described, as are methods for their preparation and monomers used in such methods. The elastomers are prepared by hydrosilylation of a reaction mixture including a liquid crystalline diene, a crosslinking agent, and a bis(silyl hydride) compound. The elastomers exhibit shape-memory properties and spontaneously reversible shape changes. They are useful for fabrication of shape memory articles including, for example, implantable medical devices, contact lenses, reversible embossing media, and Fresnel lenses.

  本文描述了形状记忆主链液晶C相弹性体，以及用于制备这些弹性体的方法和用于这些方法的单体。通过氢硅化反应混合物制备弹性体，包括液晶二烯，交联剂和双（硅烷氢）化合物。这些弹性体具有形状记忆性能和自发可逆形状变化。它们可用于制造形状记忆制品，例如可植入医疗器械，隐形眼镜，可逆压花介质和菲涅耳透镜。
• US7601274B2
  申请人：——

  公开号：US7601274B2

  公开（公告）日：2009-10-13
• US7799243B2
  申请人：——

  公开号：US7799243B2

  公开（公告）日：2010-09-21
• Induction of Smectic Layering in Nematic Liquid Crystals Using Immiscible Components. 1. Laterally Attached Side-Chain Liquid Crystalline Poly(norbornene)s and Their Low Molar Mass Analogs with Hydrocarbon/Fluorocarbon Substituents
  作者：Stephen V. Arehart、Coleen Pugh

  DOI：10.1021/ja963687p

  日期：1997.4.1

  contrast to their hydrocarbon analogues which exhibit only nematic mesophases, poly5-[[[2‘,5‘-bis[(4‘‘-(n-(dimethylsiloxyl)alkoxy)benzoyl)oxy]benzyl]oxy]carbonyl]bicyclo[2.2.1]hept-2-ene}s and their low-molar-mass model compounds exhibit smectic C mesophases. Since nematic liquid crystals can be forced into layers by terminating their hydrocarbon substituents not only with fluorocarbon segments but also

  与仅表现出向列中间相的烃类似物相比，聚5-[[[[2',5'-双[(4''-(n-(二甲基甲硅烷氧基)烷氧基)苯甲酰基)氧基]苄基]氧基]羰基]双环[2.2.1]hept-2-ene}及其低摩尔质量模型化合物表现出近晶C中间相。由于向列液晶可以通过不仅用碳氟化合物链段而且用柔性硅氧烷链段终止它们的烃取代基而被迫成层，这支持了这样的假设，即含有线性碳氟化合物链段的两亲分子的近晶介晶主要是由于碳氢化合物的不混溶性和碳氟化合物段，而不是“介晶全氟烷基棒”的形状持久性。2、5-双[(4'-(n-(低聚二甲基甲硅烷氧基)烷氧基)苯甲酰基)氧基]甲苯模拟聚合物形成的相和它们转变的一般温度，因此是聚合物的极好模型。5-[[2',5'-双[(4''-(n-(低聚二甲基甲硅烷氧基)烷氧基)苯甲酰基)氧基]苄基]氧基]...
• Induction of Smectic Layering in Nematic Liquid Crystals Using Immiscible Components. 5. Laterally Attached Side-Chain Liquid Crystalline Poly(norbornene)s and Their Low Molar Mass Model Compounds with Short Fluorocarbon Segments
  作者：Aaron C. Small、Coleen Pugh

  DOI：10.1021/ma0113430

  日期：2002.3.1

  5-[[[2',5'-Bis[(4"-n-((perfluoroalkyl)alkoxy)benzoyl)oxy]benzyl]oxy]carbonyl]bicyclo[2.2.1]hept-2-enes with short fluorocarbon segments were polymerized by ring-opening metathesis polymerization in THF at room temperature using Mo(CHCMe2Ph)(N-2,6-'Pr2Ph)(O'Bu)(2) as the initiator. Although hydrocarbon and fluorocarbon segments as short as three methylenic units each induce smectic layering in the corresponding 2,5-bis[4'-(n-(perfluoroalkyl)alkoxy)benzoyl]oxy}toluene model compounds, the polymers require at least eight and three, or five and four methylenic units in the hydrocarbon and fluorocarbon segments, respectively, to organize into smectic layers; polymers with shorter hydrocarbon and/or fluorocarbon segments are nematic.