1-thiocyanato-2-naphthol | 78315-87-4

• 分子结构分类: 有机化合物 - 苯类化合物 - 萘
• 英文名称: 1-thiocyanato-2-naphthol
• 英文别名: 1-Thiocyanato-2-hydroxy-naphthalin；1-Thiocyanato-β-naphthol；Thiocyansaeure-(2-hydroxy-naphthyl-(1)-ester)；2-Hydroxy-1-thiocyanato-naphthalin；2-Hydroxy-naphthyl-(1)-thiocyanat；(2-Oxy-naphthyl-(1))-rhodanid；1-Rhodan-naphthol-(2)；2-Hydroxynaphthalen-1-yl thiocyanate；(2-hydroxynaphthalen-1-yl) thiocyanate
• CAS: 78315-87-4
• 化学式: C₁₁H₇NOS
• 分子量: 201.249
• InChiKey: GVYSGTDSLZPWSC-UHFFFAOYSA-N

物化性质

• 熔点：
  113 °C
• 沸点：
  374.3±25.0 °C(Predicted)
• 密度：
  1.38±0.1 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  3.4
• 重原子数：
  14
• 可旋转键数：
  1
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  69.3
• 氢给体数：
  1
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  1-thiocyanato-2-naphthol 在 盐酸 、 乙醇 、 锌 作用下， 生成 1-sulfanyl-2-naphthalenol
  参考文献：
  名称：

  Kaufmann; Liepe, Berichte der Deutschen Pharmazeutischen Gesellschaft, vol. 33, p. 147

  摘要：

  DOI：
• 作为产物：
  描述：

  lead(II) thiocyanate 在 四氯化碳 、 磺酰氯 作用下， 生成 1-thiocyanato-2-naphthol
  参考文献：
  名称：

  DE439604

  摘要：

  公开号：

文献信息

• Oxidant-free thiocyanation of phenols and carbonyl compounds under solvent-free conditions by AlCl₃/NH₄SCN
  作者：Kobra Nikoofar、Samareh Gorji

  DOI：10.1080/17415993.2015.1091888

  日期：2016.1.2

  A simple, efficient, solvent-free, and mild method for thiocyanation of phenols by ammonium thiocyanate (NH4SCN) in the presence of AlCl3 has been developed. This new methodology was used to prepare para-thiocyanated products in good to excellent yields at 70 degrees C. In addition, the successful alpha-thiocyanation of various ketones has also been described. Finally, a plausible mechanism of thiocyanation has been suggested.[GRAPHICS]
• Career management practices: An empirical survey and implications
  作者：Yehuda Baruch、Maury Peiperl

  DOI：10.1002/1099-050x(200024)39:4<347::aid-hrm6>3.0.co;2-c

  日期：——

  A key ingredient in the knowledge economy is the development of people's careers. Companies approach career development in a variety of ways. To better understand how these approaches fit together and how they are used to address different situations, the authors surveyed 194 United Kingdom companies and identified five groups of practices. These groups were associated with certain organizational characteristics. Drawing on concepts from the careers literature, the authors suggest a two-dimensional model to explore how these groups of practices can be systematically understood and applied. (C) 2000 John Wiley & Sons, Inc.
• Tsukamoto et al., Yakugaku Zasshi/Journal of the Pharmaceutical Society of Japan, 1953, vol. 73, p. 1083
  作者：Tsukamoto et al.

  DOI：——

  日期：——
• 192. Halogen derivatives of dehydro-2-naphthol 1-disulphide
  作者：John A. C. McClelland、Samuel Smiles

  DOI：10.1039/jr9330000786

  日期：——
• Lichoschersstow; Petrow, Zhurnal Obshchei Khimii, 1933, vol. 3, p. 183,196
  作者：Lichoschersstow、Petrow

  DOI：——

  日期：——