3-(naphthalen-1-ylamino)-butan-2-ol | 1220968-74-0

• 分子结构分类: 有机化合物 - 苯类化合物 - 萘
• 英文名称: 3-(naphthalen-1-ylamino)-butan-2-ol
• 英文别名: 3-(Naphthalen-1-ylamino)butan-2-ol；3-(naphthalen-1-ylamino)butan-2-ol
• CAS: 1220968-74-0
• 化学式: C₁₄H₁₇NO
• 分子量: 215.295
• InChiKey: XYOQJDLUSIHZDU-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.1
• 重原子数：
  16
• 可旋转键数：
  3
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.29
• 拓扑面积：
  32.3
• 氢给体数：
  2
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  乙醇 、 1-萘胺 在 叔丁基过氧化氢 、 titanium(III) chloride 作用下， 以 水 为溶剂， 以48%的产率得到3-(naphthalen-1-ylamino)-butan-2-ol
  参考文献：
  名称：

  Efficient radical domino approach to β-aminoalcohols from arylamines and alcohols triggered by Ti(III)/t-BuOOH

  摘要：

  We report that an aqueous Ti(III)/t-BuOOH system promotes the efficient domino radical reaction of arylamines with alcohol cosolvents leading to beta-aminoalcohols in good yields, in less than ten minutes at room temperature. The free-radical mechanism according to which the amine reacts with two molecules of the alcohol is discussed. (C) 2010 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tet.2010.01.039

文献信息

• COLORING CURABLE RESIN COMPOSITION, CURED FILM, COLOR FILTER, METHOD FOR MANUFACTURING COLOR FILTER, SOLID-STATE IMAGING DEVICE, IMAGE DISPLAY DEVICE, COMPOUND, AND CATION
  申请人：FUJIFILM Corporation

  公开号：US20160376234A1

  公开（公告）日：2016-12-29

  The present invention provides a colored curable resin composition that exhibits good heat resistance and durability in a sputtering process, a cured film, a color filter, a method for manufacturing a color filter, a solid-state image device, an image display device, a compound, and a cation. The colored curable resin composition contains a colorant represented by Formula (1), Formula (2), or Formula (3), a resin, a polymerizable compound, and a polymerization initiator. In Formula (1), R 101 and R 102 each independently represent a hydrogen atom or a substituent, R 103 to R 106 each independently represent a hydrogen atom, an alkyl group, an aryl group, or a heteroaryl group, R 107 to R 111 each independently represent a hydrogen atom or a substituent, n1 to n4 each independently represent an integer of 0 to 4, n5 represents an integer of 0 to 6, X represents an anion or is not present, and at least one of R 101 , . . . , or R 111 includes an anion; and in the case where R 101 and R 102 represent hydrogen atoms, R 103 represents an aryl group having a substituent at at least the ortho-position.

  本发明提供了一种在溅射工艺中具有良好耐热性和耐久性的着色可固化树脂组合物、固化膜、色滤光器、制造色滤光器的方法、固态图像设备、图像显示设备、化合物和阳离子。该着色可固化树脂组合物含有由公式(1)、公式(2)或公式(3)表示的着色剂、树脂、可聚合化合物和聚合引发剂。在公式(1)中，R101和R102各自独立地表示氢原子或取代基，R103至R106各自独立地表示氢原子、烷基、芳基或杂芳基，R107至R111各自独立地表示氢原子或取代基，n1至n4各自独立地表示0至4的整数，n5表示0至6的整数，X表示阴离子或不出现，且至少R101、…或R111中包括阴离子；且在R101和R102表示氢原子的情况下，R103表示在至少邻位具有取代基的芳基。
• Coloring curable resin composition, cured film, color filter, method for manufacturing color filter, solid-state imaging device, image display device, compound, and cation
  申请人：FUJIFILM Corporation

  公开号：US10351526B2

  公开（公告）日：2019-07-16

  The present invention provides a colored curable resin composition that exhibits good heat resistance and durability in a sputtering process, a cured film, a color filter, a method for manufacturing a color filter, a solid-state image device, an image display device, a compound, and a cation. The colored curable resin composition contains a colorant represented by Formula (1), Formula (2), or Formula (3), a resin, a polymerizable compound, and a polymerization initiator. In Formula (1), R101 and R102 each independently represent a hydrogen atom or a substituent, R103 to R106 each independently represent a hydrogen atom, an alkyl group, an aryl group, or a heteroaryl group, R107 to R111 each independently represent a hydrogen atom or a substituent, n1 to n4 each independently represent an integer of 0 to 4, n5 represents an integer of 0 to 6, X represents an anion or is not present, and at least one of R101, . . . , or R111 includes an anion; and in the case where R101 and R102 represent hydrogen atoms, R103 represents an aryl group having a substituent at at least the ortho-position.

  本发明提供了一种在溅射工艺中表现出良好耐热性和耐久性的有色可固化树脂组合物、固化膜、彩色滤光片、彩色滤光片的制造方法、固态图像设备、图像显示设备、化合物和阳离子。有色可固化树脂组合物包含由式（1）、式（2）或式（3）表示的着色剂、树脂、可聚合化合物和聚合引发剂。在式 (1) 中，R101 和 R102 各自独立地代表氢原子或取代基，R103 至 R106 各自独立地代表氢原子、烷基、芳基或杂芳基，R107 至 R111 各自独立地代表氢原子或取代基，n1 至 n4 各自独立地代表 0 至 4 的整数，n5 代表 0 至 6 的整数，X 代表阴离子或不存在，且 R101、......或 R111 中至少有一个包括阴离子。在 R101 和 R102 代表氢原子的情况下，R103 代表至少在正交位置具有取代基的芳基。
• Efficient radical domino approach to β-aminoalcohols from arylamines and alcohols triggered by Ti(III)/t-BuOOH
  作者：Raffaele Spaccini、Alessandra Ghilardi、Nadia Pastori、Angelo Clerici、Carlo Punta、Ombretta Porta

  DOI：10.1016/j.tet.2010.01.039

  日期：2010.3

  We report that an aqueous Ti(III)/t-BuOOH system promotes the efficient domino radical reaction of arylamines with alcohol cosolvents leading to beta-aminoalcohols in good yields, in less than ten minutes at room temperature. The free-radical mechanism according to which the amine reacts with two molecules of the alcohol is discussed. (C) 2010 Elsevier Ltd. All rights reserved.