allyl-trimethyl-ammonium; hydroxide | 503-34-4

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: allyl-trimethyl-ammonium; hydroxide
• 英文别名: Allyl-trimethyl-ammonium; Hydroxid；Homoneurin；Trimethylallylammonium hydroxide；trimethyl(prop-2-enyl)azanium;hydroxide
• CAS: 503-34-4
• 化学式: C₆H₁₄N*HO
• 分子量: 117.191
• InChiKey: JHNLSXMXTIQPSC-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  0.7
• 重原子数：
  8
• 可旋转键数：
  2
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.67
• 拓扑面积：
  1
• 氢给体数：
  1
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  allyl-trimethyl-ammonium; hydroxide 生成 丙炔
  参考文献：
  名称：

  Howton, Journal of Organic Chemistry, 1949, vol. 14, p. 4

  摘要：

  DOI：
• 作为产物：
  描述：

  alkaline earth salt of/the/ methylsulfuric acid 在 氢氧化钾 作用下， 生成 allyl-trimethyl-ammonium; hydroxide
  参考文献：
  名称：

  Lucius, Archiv der Pharmazie, 1907, vol. 245, p. 247

  摘要：

  DOI：

文献信息

• [EN] ACRYLATE-FUNCTIONAL BRANCHED ORGANOSILICON COMPOUND, METHOD OF PREPARING SAME, AND COPOLYMER FORMED THEREWITH<br/>[FR] COMPOSÉ D'ORGANOSILICIUM RAMIFIÉ À FONCTION ACRYLATE, SON PROCÉDÉ DE PRÉPARATION ET COPOLYMÈRE FORMÉ AVEC CELUI-CI
  申请人：DOW SILICONES CORP

  公开号：WO2020142474A1

  公开（公告）日：2020-07-09

  A method of preparing an acrylate-functional branched organosilicon compound ("compound") is provided, and comprises reacting (A) a branched organosilicon compound and (B) an acrylate compound in the presence of (C) a catalyst, wherein component (A) has the general formula X-Si(R1)3, where X comprises a halogen-functional moiety and each R1 is selected from R and –OSi(R4)3, with the proviso that at least one R1 is –OSi(R4)3; each R4 is selected from R, –OSi(R5)3, and –[OSiR2]mOSiR3; each R5 is selected from R, –OSi(R6)3, and –[OSiR2]mOSiR3; each R6 is selected from R and –[OSiR2]mOSiR3; each R is an independently selected hydrocarbyl group; and 0≤m≤100; with the proviso that at least one of R4, R5 and R6 is –[OSiR2]mOSiR3. The compound prepared by the method, a copolymer comprising the reaction product of the compound and a second compound, a method of forming the copolymer, and a composition comprising the copolymer are each also provided.

  提供了一种制备丙烯酸酯官能化分支有机硅化合物（“化合物”）的方法，包括在催化剂存在下，使（A）分支有机硅化合物和（B）丙烯酸酯化合物发生反应，其中组分（A）具有一般式X-Si（R1）3，其中X包括卤素官能基，每个R1从R和–OSi（R4）3中选择，但至少一个R1为–OSi（R4）3；每个R4从R、–OSi（R5）3和–[OSiR2]mOSiR3中选择；每个R5从R、–OSi（R6）3和–[OSiR2]mOSiR3中选择；每个R6从R和–[OSiR2]mOSiR3中选择；每个R是独立选择的烃基；且0≤m≤100；但至少一个R4、R5和R6为–[OSiR2]mOSiR3。还提供了通过该方法制备的化合物，包括化合物和第二化合物的反应产物的共聚物，形成共聚物的方法，以及包含共聚物的组合物。
• Enhanced color deposition for hair with sequestering agents
  申请人：Unilever Home & Personal Care USA, Division of Conopco, Inc.

  公开号：US20030135935A1

  公开（公告）日：2003-07-24

  Hair coloring compositions which comprise: (A) non-nitrogenous chelating agents from the group consisting of polyphosphate; phosphonates; hydroxycarboxylates; polyacrylates; zeolite; and mixtures thereof; (B) an oxidative dye primary intermediate; and (C) an oxidative dye coupler; (D) and water are described. The present invention also relates to a method for coloring hair which comprises contacting said hair with a hair coloring composition as described above.

  描述了包括以下成分的染发配方：(A) 来自聚磷酸盐、膦酸盐、羟基羧酸盐、聚丙烯酸盐、沸石及其混合物等组成的非氮螯合剂；(B) 一种氧化染料的主要中间体；和(C) 一种氧化染料偶联剂；(D) 以及水。本发明还涉及一种染发方法，该方法包括将头发与上述描述的染发配方接触。
• Aminofunctional silicone resins and emulsions containing them
  申请人：Gordon Glenn

  公开号：US20070104674A1

  公开（公告）日：2007-05-10

  This invention relates to aminofunctional silicone resins having high aryl content R 2 SiO 2/2 content and amine content. The aminofunctional silicone resins of this invention are useful in making tough, water, solvent, and heat resistant hybrid materials when used in combination with selected organic materials, particularly epoxy-containing organic materials. The aminofunctional resins of this invention have the ability to flexibilize epoxy compounds while maintaining low CTE and solvent resistance. This invention also relates to emulsion compositions containing the above described aminofunctional silicone resins.

  这项发明涉及具有高芳基含量R2SiO2/2含量和胺含量的氨基硅树脂。该发明的氨基硅树脂在与选定的有机材料，特别是含环氧基的有机材料结合使用时，可用于制备坚固、耐水、耐溶剂和耐热的混合材料。该发明的氨基功能树脂具有使环氧化合物变得柔软的能力，同时保持低CTE和耐溶剂性。该发明还涉及含有上述描述的氨基功能硅树脂的乳液组合物。
• PROCESS FOR PRODUCING CYCLOALKANOL AND/OR CYCLOALKANONE
  申请人：HOSHINO Masahiro

  公开号：US20090036714A1

  公开（公告）日：2009-02-05

  An object of the present invention is to provide a process capable of producing cycloalkanol and/or cycloalkanone with a favorable selectivity by oxidizing cycloalkane with a favorable conversion. Disclosed is a process for producing cycloalkanol and/or cycloalkanone, which comprises oxidizing cycloalkane with oxygen in the presence of mesoporous silica, wherein (1) the mesoporous silica contains at least one transition metal, and (2) a ratio of total volume of mesoporous silica particles having a particle diameter of 20 μm or less to total volume of entire mesoporous silica particles is 25% or more in the mesoporous silica.

  本发明的一个目的是提供一种能够通过在介孔硅胶存在的条件下氧化环烷烃来产生具有良好选择性的环烷醇和/或环烷酮的方法。公开了一种生产环烷醇和/或环烷酮的方法，包括在介孔硅胶存在的条件下将环烷烃与氧气氧化，其中（1）介孔硅胶含有至少一种过渡金属，且（2）具有粒径小于20μm的介孔硅胶颗粒的总体积与整个介孔硅胶颗粒的总体积之比在介孔硅胶中为25％或更高。
• METHOD FOR PRODUCING CYCLOALKANOL AND/OR CYCLOALKANONE
  申请人：HOSHINO Masahiro

  公开号：US20090227814A1

  公开（公告）日：2009-09-10

  An object of the present invention is to provide a method capable of producing a cycloalkanol and/or a cycloalkanone with a favorable selectivity coefficient by oxidizing a cycloalkane with a favorable conversion ratio. Disclosed is a method for producing a cycloalkanol and/or a cycloalkanone, which comprises oxidizing a cycloalkane with oxygen in the presence of a mesoporous silica which contains at least one transition metal and has been also subjected to contact treatment with an amine and/or ammonia. Preferably, a crystal obtained by mixing a compound containing the metal, a silicon compound, a structure-directing agent and water is subjected to contact treatment with an amine and/or ammonia and then fired to obtain a mesoporous silica, and a cycloalkane is oxidized with oxygen in the presence of the mesoporous silica.

  本发明的一个目的是提供一种能够通过在含有至少一种过渡金属的介孔二氧化硅存在的情况下氧化环烷烃来产生具有良好选择性系数的环烷醇和/或环烷酮的方法。揭示了一种生产环烷醇和/或环烷酮的方法，该方法包括在存在氧气的情况下，通过与胺和/或氨接触处理的介孔二氧化硅氧化环烷烃。最好是，通过混合含有金属的化合物、硅化合物、结构定向剂和水获得的晶体经过与胺和/或氨的接触处理，然后经过烧结得到介孔二氧化硅，然后在介孔二氧化硅存在的情况下，氧化环烷烃。