2,4,6-tris-(N,N-dibutylamino)-1,3,5-triazine | 7285-99-6

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: 2,4,6-tris-(N,N-dibutylamino)-1,3,5-triazine
• 英文别名: 2,4,6-tris-(di-n-butylamino)-s-triazine；hexa-N-butyl-[1,3,5]triazine-2,4,6-triamine；2,4,6-Tris-(di-n-butylamino)-s-triazin；2,4,6-Tris(dibutylamino)-s-triazin；1,3,5-Triazine-2,4,6-triamine, N,N,N',N',N'',N''-hexabutyl-；2-N,2-N,4-N,4-N,6-N,6-N-hexabutyl-1,3,5-triazine-2,4,6-triamine
• CAS: 7285-99-6
• 化学式: C₂₇H₅₄N₆
• 分子量: 462.766
• InChiKey: VCPUPPVDZCTSMI-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  8.8
• 重原子数：
  33
• 可旋转键数：
  21
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.89
• 拓扑面积：
  48.4
• 氢给体数：
  0
• 氢受体数：
  6

反应信息

• 作为产物：
  描述：

  三聚氯氰 、 三正丁胺 以 二氯甲烷 为溶剂， 以96%的产率得到2,4,6-tris-(N,N-dibutylamino)-1,3,5-triazine
  参考文献：
  名称：

  取代基的作用在亲核芳族取代中起作用。在温和的反应条件下合成N，N-二取代的三聚氰胺（triazine triskelions）的新方法

  摘要：

  通过取代基作用的增强，在温和的反应条件下，通过用叔胺处理氰尿酰氯，制备了被三个二烷基氨基取代的1,3,5-三嗪。季Ñ -triazinylammonium盐被鉴定为活性中间体活化三嗪环，并强烈促进所有氯原子的persubstitution。在适当的氯烷烃不可逆转的释放过程中，中间体N-三叠氮基氯化铵的最终降解在室温下或在沸腾的二氯甲烷中自发进行。

  DOI：

  10.1016/j.tet.2009.03.017

文献信息

• 4,6-Bis- and 2,4,6-tris-(N,N-dialkylamino)-s-triazines: synthesis, NMR spectra and restricted rotations
  作者：Alan R. Katritzky、Daniela C. Oniciu、Ion Ghiviriga、Richard A. Barcock

  DOI：10.1039/p29950000785

  日期：——

  Syntheses of various symmetrically and non-symmetrically trisubstituted triazines are reported. Dynamic NMR (1H and 13C) experiments demonstrate that 2,4,6-tris(dialkylamino)-s-triazines show correlated rotations of the alkyl groups in the dialkylamino moieties. Unsymmetrical 2-chloro-, 2-alkoxy- and 2-aryloxy-4,6-bis(di-n-alkylamino)-s-triazines display two non-equivalent n-alkyl groups, due to the

  报道了各种对称和非对称三取代的三嗪的合成。动态NMR（1 H和13 C）的实验表明，2,4,6-三（二烷基氨基） -小号-triazines示出了在二烷基氨基部分相关联的烷基的旋转。不对称2-氯- ，2-烷氧基和2-芳基-4,6-双（二- ñ -烷基氨基） -小号-triazines显示两个非等价Ñ烷基基团，由于周围的AR-受限旋转N个债券。
• METHODS FOR MODIFYING 1,3,5-TRIAZINE DERIVATIVES
  申请人：NISSAN CHEMICAL INDUSTRIES, LIMITED

  公开号：EP0882720A1

  公开（公告）日：1998-12-09

  A method for modifying 1,3,5-triazine derivatives characterized by reacting a 1,3,5-triazine derivative having at least one amino or monosubstituted amino group on any of the ring carbon atoms with an alcohol by heating in the presence of a metallic catalyst and hydrogen to thereby introduce an alkyl or alkenyl group into each amino or monosubstituted amino group; another method for modifying 1,3,5-triazine derivatives characterized by reacting a 1,3,5-triazine derivative having at least one amino or monosubstituted amino group on any of the ring carbon atoms with a dihydric alcohol by heating in the presence of a metallic catalyst and hydrogen to thereby introduce a hydroxylated alkyl group into each amino or monosubstituted amino group; and 1,3,5-triazine derivatives obtained by the methods. The various modified substituted 1,3,5-triazine derivatives thus produced are generally obtained as a mixture. These derivatives can be isolated as high-purity compounds by a general separation method for organic compounds, and the compounds are usable in the various applications mentioned in the specification. According to applications (for example, use as modifier additives, in particular a flame-retardant and a plasticizer for resins), the reaction mixture can be used as it is without being separated. Many of the substituted triazine derivatives obtained have been relatively difficult to synthesize or expensive. Since many of the derivatives are interesting with respect to their physical properties, e.g., solubility in water and in various organic solvents, high-temp. stability, melting point, boiling point, and basicity, they are thought to have a wider range of applications than conventional ones.

  一种改性 1，3，5-三嗪衍生物的方法，其特征在于在金属催化剂和氢的存在下，通过加热使任一环碳原子上具有至少一个氨基或单取代氨基的 1，3，5-三嗪衍生物与醇反应，从而在每个氨基或单取代氨基中引入一个烷基或烯基；另一种改性 1,3,5-三嗪衍生物的方法，其特征在于在金属催化剂和氢气存在下，使任一环碳原子上具有至少一个氨基或单取代氨基的 1,3,5-三嗪衍生物与二元醇反应，从而在每个氨基或单取代氨基中引入羟基烷基；以及通过上述方法获得的 1,3,5-三嗪衍生物。这样制得的各种改性取代的 1,3,5-三嗪衍生物通常以混合物的形式获得。这些衍生物可作为高纯度化合物通过有机化合物的一般分离方法分离出来，这些化合物可用于说明书中提到的各种应用中。根据用途（例如用作改性添加剂，特别是阻燃剂和树脂增塑剂），反应混合物可以不经分离直接使用。所获得的许多取代三嗪衍生物都比较难以合成或价格昂贵。由于许多衍生物在物理性质（如在水和各种有机溶剂中的溶解性、高温稳定性、熔点、沸点和碱性）方面都很有趣，因此它们被认为比传统的衍生物具有更广泛的用途。
• SYNTHETIC LUBRICANT ANTIOXIDANT FROM MONOSUBSTITUTED DIPHENYLAMINES
  申请人：The B.F. Goodrich Company

  公开号：EP0799289A1

  公开（公告）日：1997-10-08
• COLORING COMPOSITION, CURED FILM, COLOR FILTER, METHOD OF MANUFACTURING COLOR FILTER, SOLID IMAGE PICKUP ELEMENT, AND IMAGE DISPLAY APPARATUS
  申请人：FUJIFILM Corporation

  公开号：US20170146904A1

  公开（公告）日：2017-05-25

  The coloring composition includes a curable compound and a colorant represented by (D-L 1 -Y—X—) n —R 1 —(R 2 ) m ; R 1 represents a (m+n)-valent linking group, X represents —C(═O)O—, Y represents an alkylene group, L 1 represents a single bond or a divalent linking group, D represents a colorant structure. R 2 represents a monovalent substituent, m represents an integer of 1 to 13, n represents an integer of 2 to 14, m+n represents an integer of 3 to 15, L 1 (in a case where L 1 represents a single bond, D) and X are separated by Y by a distance of three or more carbon atoms, and at least one of D, L 1 , R 1 , R 2 , X, or Y has an acid group.
• US3988292A
  申请人：——

  公开号：US3988292A

  公开（公告）日：1976-10-26