bis-(2-ethylcarbonate)ethyl sulfide | 500798-11-8

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 有机碳酸及其衍生物
• 英文名称: bis-(2-ethylcarbonate)ethyl sulfide
• 英文别名: 2-(2-Ethoxycarbonyloxyethylsulfanyl)ethyl ethyl carbonate
• CAS: 500798-11-8
• 化学式: C₁₀H₁₈O₆S
• 分子量: 266.315
• InChiKey: VVSCRDVFQXBWEN-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.2
• 重原子数：
  17
• 可旋转键数：
  12
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.8
• 拓扑面积：
  96.4
• 氢给体数：
  0
• 氢受体数：
  7

反应信息

• 作为反应物：
  描述：

  bis-(2-ethylcarbonate)ethyl sulfide 、 4-羟基苯甲腈 以 neat (no solvent) 为溶剂， 反应 24.0h， 生成 1,5-bis(4-cyanophenoxy)-3-thiapentane
  参考文献：
  名称：

  Behaviour of iprit carbonate analogues in solventless reactions

  摘要：

  硫代碳酸硫酯类似物在常压下，在无溶剂条件下，存在或不存在催化剂量的碱的情况下，与多种底物发生亲核取代反应。

  DOI：

  10.1039/c4ra03254c
• 作为产物：
  描述：

  硫二甘醇 、 碳酸二乙酯 反应 17.0h， 以90%的产率得到bis-(2-ethylcarbonate)ethyl sulfide
  参考文献：
  名称：

  Behaviour of iprit carbonate analogues in solventless reactions

  摘要：

  硫代碳酸硫酯类似物在常压下，在无溶剂条件下，存在或不存在催化剂量的碱的情况下，与多种底物发生亲核取代反应。

  DOI：

  10.1039/c4ra03254c

文献信息

• PROCESS FOR PREPARING A POLYMER FROM MUSTARD CARBONATE ANALOGUES
  申请人：Tundo, Pietro Rosario

  公开号：EP3642259A1

  公开（公告）日：2020-04-29
• [EN] PROCESS FOR PREPARING A POLYMER FROM MUSTARD CARBONATE ANALOGUES<br/>[FR] PROCÉDÉ DE PRÉPARATION D'UN POLYMÈRE À PARTIR D'ANALOGUES CARBONATES DE MOUTARDE
  申请人：TUNDO PIETRO ROSARIO

  公开号：WO2018235046A1

  公开（公告）日：2018-12-27

  The present invention relates to a process for preparing a polymer that comprises at least a step of carrying out a mass polymerization of a reaction mixture comprising at least one mustard carbonate analogue of general formula R1OOCO-R2-Z-R3-OCOOR4 (I) and at least one hydroxy-subst ituted aromatic compound of general formula Ar(OH)n (II), wherein in said general formulas: R1 and R4, equal or different, are linear or branched C1-C6 alkyl; R2 and R3, equal or different, are a linear or branched C2 -C4 alkylene, preferably ethylene; Z is a radical selected from: S; N-Y, wherein Y is selected from: hydrogen, linear or branched C1-C6 alkyl, or a radical -R6OCOOR5 where R6 is a linear or branched C2 -C4 alkyl and R5 is a linear or branched C1-C6 alkyl; Ar is an aromatic radical selected from: benzene, naphthalene, phenanthrene, anthracene, biaryl radical or two or more aromatic radicals bridged by a linear or branched C1-C10 alkylene group, said Ar group being optionally substituted; n is an integer from 2 to 5. The present invention further relates to the polymer obtainable with the aforesaid process.
• Behaviour of iprit carbonate analogues in solventless reactions
  作者：F. Arico'、S. Evaristo、P. Tundo

  DOI：10.1039/c4ra03254c

  日期：——

  Sulfur iprit carbonate analogues showed to undergo nucleophilic substitution with several substrates in neat conditions at atmospheric pressure, in the presence and in the absence of a catalytic amount of base.

  硫代碳酸硫酯类似物在常压下，在无溶剂条件下，存在或不存在催化剂量的碱的情况下，与多种底物发生亲核取代反应。