(9E,12E)-octadeca-9,12-dienenitrile

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: (9E,12E)-octadeca-9,12-dienenitrile
• 化学式: C₁₈H₃₁N
• 分子量: 261.4
• InChiKey: FIHZPUAKGUAAJK-AVQMFFATSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6.5
• 重原子数：
  19
• 可旋转键数：
  13
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.72
• 拓扑面积：
  23.8
• 氢给体数：
  0
• 氢受体数：
  1

文献信息

• Process for preparing linear monofunctional and telechelic difunctional polymers and compositions obtained thereby
  申请人：AMOCO CORPORATION

  公开号：EP0626402A2

  公开（公告）日：1994-11-30

  This invention relates to a process for preparation of non-crosslinked linear monofunctional and telechelic difunctional unsaturated polymers wherein the functional groups are reactive terminal groups other than vinyl groups. The average functionality number of the monofunctional unsaturated polymers is at least 0.7, as determined by nuclear magnetic resonance spectroscopy (NMR). The average functionality number of the telechelic difunctional polymers is at least 1.6-1.7, as determined by NMR. Monofunctional olefins and difunctional olefins are reacted with cyclic olefins or unsaturated polymers to prepare difunctional polymers. The process is substantially free of side reactions comprising double bond migration and cyclization. The unsaturated functional polymers can be reacted in condensation, addition and transesterification reactions to prepare polyesters, graft copolymers, polyurethanes, polyureas, polyamides, thermoplastic and thermosetting resins, block copolymers, ion exchange resins, adhesives, films, fibers, foams and flocculants.

  本发明涉及一种非交联线性单官能团和远志双官能团不饱和聚合物的制备工艺，其中的官能团是乙烯基以外的活性末端基团。通过核磁共振光谱（NMR）测定，单官能团不饱和聚合物的平均官能度数至少为 0.7。通过核磁共振光谱测定，双官能团聚合物的平均官能度数至少为 1.6-1.7。单官能烯烃和双官能烯烃与环状烯烃或不饱和聚合物反应制备双官能聚合物。该工艺基本上不存在包括双键迁移和环化在内的副反应。不饱和官能团聚合物可通过缩合、加成和酯交换反应制备聚酯、接枝共聚物、聚氨酯、聚氨酯、聚酰胺、热塑性和热固性树脂、嵌段共聚物、离子交换树脂、粘合剂、薄膜、纤维、泡沫和凝聚剂。
• Linear telechelic difunctional polymers and process for their preparation.
  申请人：CALIFORNIA INSTITUTE OF TECHNOLOGY

  公开号：EP0626402B1

  公开（公告）日：2002-07-31
• US3974196A
  申请人：——

  公开号：US3974196A

  公开（公告）日：1976-08-10
• US4217299A
  申请人：——

  公开号：US4217299A

  公开（公告）日：1980-08-12
• US5403904A
  申请人：——

  公开号：US5403904A

  公开（公告）日：1995-04-04