申请人:Asahi Kasei Kogyo Kabushiki Kaisha
公开号:EP0429672A1
公开(公告)日:1991-06-05
An acetal copolymer having a viscosity number of 0.1 to 10 dl/g and an excellent isotropy and being constituted of a polyacetal unit and a particulate cross-linked polymer unit is produced by reacting a polyacetal particulate cross-linked polymer other than polyacetal, said polymer having mean particle diameter of 0.01 to 10 µ and functional groups selected from among hydroxyl, carboxyl, amino, amide, alkoxy, acid anhydride, and epoxy groups, to unite them with each other through said functional groups. Another acetal copolymer having a viscosity number of 0.1 to 10 dl/g and being constituted of a polyacetal unit and another polymer unit is produced by either homopolymerizing formaldehyde or trioxane or copolymerizing formaldehyde or trioxane with a cyclic ether in the presence of a polymer other than polyacetal, said polymer having a mean dispersion diameter of 0.01 to 2,000 µ and functional groups selected from among hydroxyl, carboxyl, amino, amide, alkoxy, acid anhydride, and epoxy groups, to unite the formed polyacetal with the polymer other than polyacetal through said functional groups.
一种乙缩醛共聚物具有 0.1 至 10 dl/g 的粘度值和极好的各向同性,由聚缩醛单元和微粒交联聚合物单元构成,其制备方法是将聚缩醛以外的微粒交联聚合物(所述聚合物的平均颗粒直径为 0.01 至 10 µ)和从羟基、羧基、氨基、酰胺、烷氧基、酸酐和环氧基团中选出的官能团进行反应,通过所述官能团使它们相互结合。另一种缩醛共聚物的粘度值为 0.1 至 10 dl/g,由聚缩醛单元和另一种聚合物单元构成,其生产方法为:在聚缩醛以外的聚合物存在下,将甲醛或三氧杂环己烷均聚,或将甲醛或三氧杂环己烷与环醚共聚,所述聚合物的平均分散直径为 0.01至2,000微米,官能团选自羟基、羧基、氨基、酰胺、烷氧基、酸酐和环氧基团,通过所述官能团使形成的聚缩醛与聚缩醛以外的聚合物结合。