triethyl-hexadecyl-ammonium; iodide | 41864-99-7

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: triethyl-hexadecyl-ammonium; iodide
• 英文别名: Triaethyl-hexadecyl-ammonium; Jodid；N,N,N-Triethylhexadecan-1-aminium iodide；triethyl(hexadecyl)azanium;iodide
• CAS: 41864-99-7
• 化学式: C₂₂H₄₈N*I
• 分子量: 453.534
• InChiKey: QFGWYYQGDCVPFQ-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  4.35
• 重原子数：
  24
• 可旋转键数：
  18
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为产物：
  描述：

  N,N-二乙基十六烷基胺 、 碘乙烷 生成 triethyl-hexadecyl-ammonium; iodide
  参考文献：
  名称：

  Krafft; Moye, Chemische Berichte, 1889, vol. 22, p. 812

  摘要：

  DOI：

文献信息

• [EN] AN IMPROVED PROCESS FOR O-DEMETHYLATING METHOXY SUBSTITUTED MORPHINAN-6-ONE DERIVATIVES USING BORON-BASED COMPLEXES<br/>[FR] PROCÉDÉ AMÉLIORÉ POUR LA O-DÉMÉTHYLATION DE DÉRIVÉS DE MORPHINANE-6-ONE À SUBSTITUTION MÉTHOXY À L'AIDE DE COMPLEXES À BASE DE BORE
  申请人：NAVIN SAXENA RESEARCH & TECH PVT LTD

  公开号：WO2020188583A1

  公开（公告）日：2020-09-24

  The present invention discloses an improved process for O-demethylation of methoxy-substituted morphinan-6-one derivatives using boron-based complex as a demethylating boron complex in an inert reaction solvent.

  本发明揭示了一种改进的过程，用硼基复合物作为去甲基硼复合物在惰性反应溶剂中对甲氧基取代的吗啡啶-6-酮衍生物进行O-去甲基化。
• Method of producing propylene and ethylene with a core-shell ZSM catalyst
  申请人：KING FAHD UNIVERSITY OF PETROLEUM AND MINERALS

  公开号：US10016750B1

  公开（公告）日：2018-07-10

  A method of producing propylene and ethylene from a butene-containing hydrocarbon stream by cracking olefin compounds in the butene-containing hydrocarbon stream in the presence of a core-shell ZSM catalyst, wherein the core-shell ZSM catalyst comprises a ZSM-5 core and a silica shell disposed thereon. Various embodiments of the method of producing propylene and ethylene, and the method of making the core-shell ZSM catalyst are also provided.

  通过在含丁烯的烃流中使用核壳ZSM催化剂裂解含丁烯化合物的方法来生产丙烯和乙烯，其中核壳ZSM催化剂包括ZSM-5核和沉积在其上的硅壳。还提供了生产丙烯和乙烯的方法以及制备核壳ZSM催化剂的方法的各种实施例。
• [EN] PROCESS FOR THE PREPARATION OF MORPHINANE COMPOUNDS<br/>[FR] PROCÉDÉ DE PRÉPARATION DE COMPOSÉS DE MORPHINANE
  申请人：SANECA PHARMACEUTICALS A S

  公开号：WO2019009820A1

  公开（公告）日：2019-01-10

  The invention describes the process of catalytic O-demethylation of 3-methoxy-morphinane compounds using boron tribromide. Addition of catalysts reduces the reaction time, improves reacting the substrate to give the product in very good purity and yield. The said approach can be used, for example, for the preparation of oxymorphone, naltrexone, naloxone and nalbuphine from their respective O-methyl derivatives.

  本发明描述了使用三溴化硼催化剂进行3-甲氧基吗啡烷类化合物的催化O-去甲基化过程。添加催化剂可缩短反应时间，提高底物的反应性，从而以非常高的纯度和收率给出产物。该方法可用于制备羟吗啡酮、纳曲酮、纳洛酮和纳布啡等化合物，这些化合物是从它们各自的O-甲基衍生物制备而来的。
• Spurted polyolefin fibers with improved dispersibility in hydrocarbons, including hydrocarbon containing asphalt compositions and method for making the same
  申请人：HERCULES INCORPORATED

  公开号：EP0092917A1

  公开（公告）日：1983-11-02

  To an aqueous dispersion of spurted polyolefin pulp is added from about 1% to about 20%, preferably from about 2% to about 12%, by solid weight based on the weight of spurted polyolefin pulp, of an anionic latex containing a rubber or synthetic resin which is swellable in hydrocarbons. The latex is then precipitated onto the spurted polyolefin pulp with a suitable agent, preferably water-soluble calcium, magnesium, barium or aluminum salts or calcium or barium hydroxides. When the product is recovered, the resulting natural rubber or synthetic resin treated spurted polyolefin pulp is readily dispersible in hydrocarbons. Because of this, the pulp can be added to cutback asphalt to form viscous compositions which can be readily sprayed, brushed and trowled with minimal pulp separation problems.

  在喷浆聚烯烃纸浆的水性分散液中，按喷浆聚烯烃纸浆重量的固体重量计，加入约 1%至约 20%，最好是约 2%至约 12%的阴离子胶乳，其中含有可在碳氢化合物中溶胀的橡胶或合成树脂。然后用适当的制剂，最好是水溶性的钙、镁、钡或铝盐或钙或钡氢氧化物，将胶乳沉淀到喷出的聚烯烃纸浆上。回收产品时，经过天然橡胶或合成树脂处理的喷浆聚烯烃纸浆很容易分散在碳氢化合物中。正因为如此，这种纸浆可以添加到切割后的沥青中，形成粘稠的组合物，这种组合物可以很容易地喷洒、刷涂和镘涂，而纸浆分离的问题却很小。
• Agricultural film
  申请人：MITSUBISHI CHEMICAL CORPORATION

  公开号：EP0500073A2

  公开（公告）日：1992-08-26

  An agricultural film comprising a thermoplastic resin film containing an ethylene copolymer with a hindered amine in its side chain and having coated thereon an anti-fogging agent comprising an inorganic hydrophilic colloidal substance and a hydrophilic organic compound and an anti-fogging agricultural film comprising a thermoplastic resin film containing an ethylene copolymer with a hindered amine in its side chain and, if desired, further containing a hydrotalcite compound, with an anti-fogging agent coated on the inside surface thereof or incorporated therein. The agricultural films have excellent weather resistance, anti-fogging properties, heat-retaining properties, and transparency.

  一种农用薄膜，包括含有乙烯共聚物的热塑性树脂薄膜，其侧链中含有受阻胺，并在其上涂有由无机亲水胶体物质和亲水有机化合物组成的防雾剂；以及一种防雾农用薄膜，包括含有乙烯共聚物的热塑性树脂薄膜，其侧链中含有受阻胺，如果需要，还含有水滑石化合物，在其内表面涂有防雾剂或将防雾剂加入其中。农用薄膜具有出色的耐候性、防雾性、保温性和透明度。