diazabicyclo-octane | 1026872-43-4

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 氮杂环化合物
• 英文名称: diazabicyclo-octane
• 英文别名: diazabicyclooctane；1-(Diazocan-1-yl)diazocane
• CAS: 1026872-43-4
• 化学式: C₁₂H₂₆N₄
• 分子量: 226.365
• InChiKey: LNJBOUKWIPZWMH-UHFFFAOYSA-N

物化性质

• 沸点：
  325.0±25.0 °C(Predicted)
• 密度：
  0.976±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  2.4
• 重原子数：
  16
• 可旋转键数：
  1
• 环数：
  2.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  30.5
• 氢给体数：
  2
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  diazabicyclo-octane 、 三氟乙酸酐 在 双氧水 、 sodium sulfite 作用下， 以 二氯甲烷 、 氯仿 为溶剂， 生成 三氟乙酸
  参考文献：
  名称：

  Cyclic and polycyclic diazadioxides as quenchers and radical inhibitors

  摘要：

  具有两个氮原子作为环原子的杂环二氧二氮化物被用作激发态分子的淬灭剂。这些化合物可以与聚合物和颜料结合使用，以保护免受光和氧化攻击。这些产物也被发现是有效的自由基抑制剂。提供了杂环单环和多环二氧二氮化物。所有这些化合物都具有相对较低的三重能量值。

  公开号：

  US03953444A1

文献信息

• Phenyl-substituted cyclic enaminones
  申请人：Bayer Aktiengesellschaft

  公开号：US06455472B1

  公开（公告）日：2002-09-24

  The present invention relates to novel phenyl-substituted cyclic enaminones of the formula (I): in which Ar, X, Z, Y, K, n and m are each as defined in the description, to a plurality of processes and intermediates for their preparation and to their use as herbicides and pesticides.

  本发明涉及新型苯基取代的环烯酮化合物，化学式为(I)：其中Ar、X、Z、Y、K、n和m在描述中均有定义，涉及它们的制备过程和中间体的多种方法，以及它们作为除草剂和杀虫剂的用途。
• Sulphonyliso(thio)urea derivatives and herbicidal use thereof
  申请人：Bayer Aktiengesellschaft

  公开号：US04840661A1

  公开（公告）日：1989-06-20

  The invention relates relates to new sulphonyliso(thio)-urea derivatives of the general formula (I) ##STR1## in which R.sup.1 represent an optionally substituted radical from the series comprising alkyl, aralkyl, aryl and heteroaryl R.sup.2 represents an optionally substituted and/or optionally fused 6-membered aromatic heterocyclic radial containing at least one nitrogen atom, R.sup.3 represents an optically substituted aromatic or heteroaromatic radical, X represents oxygen or sulphur and M represents hydrogen or an equivalent of a metal, and adducts of compounds of the formula (I) with strong acids, processes for their prepartion, and their use as herbicides.

  该发明涉及一般式（I）的新磺酰基异（硫）脲衍生物，其中R.sup.1代表从包括烷基、芳基、芳基烷和杂环芳基的系列中选择性取代的基团，R.sup.2代表含有至少一个氮原子的选择性取代和/或选择性融合的6元芳香杂环基团，R.sup.3代表选择性取代的芳香或杂芳基团，X代表氧或硫，M代表氢或金属的等效物，以及一般式（I）化合物与强酸的加合物，其制备方法，以及作为除草剂的用途。
• N-phenylsulfonyl-N'-triazinylureas
  申请人：Ciba-Geigy Corporation

  公开号：US04618363A1

  公开（公告）日：1986-10-21

  N-Phenylsulfonyl-N'-pyrimidinylureas and -N'-triazinylureas of the general formula ##STR1## and the salts of these compounds with amines, alkali metal bases and alkaline earth metal bases or with quaternary ammonium bases, have good selective herbicidal and plant growth regulating properties when applied pre- and postemergence. In the formula R.sub.1 is hydrogen, halogen, nitro, C.sub.1 -C.sub.4 haloalkyl, C.sub.1 -C.sub.4 alkyl, C.sub.1 -C.sub.4 alkoxy, C.sub.2 -C.sub.5 alkenyl or C.sub.1 -C.sub.4 alkoxycarbonyl, R.sub.2 is C.sub.1 -C.sub.3 alkyl or C.sub.1 -C.sub.3 alkoxy, each unsubstituted or substituted by 1 to 3 halogen atoms, R.sub.3 is halogen, hydrogen, --NR.sub.4 R.sub.5, C.sub.1 -C.sub.3 alkyl, unsubstituted or substituted by 1 to 3 halogen atoms or C.sub.1 -C.sub.4 alkoxy, or is C.sub.1 -C.sub.3 alkoxy, unsubstituted or substituted by methoxy, ethoxy, or 1 to 3 halogen atoms, R.sub.4 is hydrogen or methyl, R.sub.5 is hydrogen, C.sub.1 -C.sub.2 alkyl or methoxy, A is C.sub.1 -C.sub.4 alkylene or C.sub.2 -C.sub.4 alkenylene, each unsubstituted or substituted by C.sub.1 -C.sub.4 alkyl, m is 0 or 1, E is nitrogen or the methine group, X is oxygen, sulfur, --SO-- or --SO.sub.2 --, and Q is hydroxyl, cyano or radicals selected from the group consisting of 5- or 6-membered heterocyclic rings and fused homologues, amines, acetals, esters, ketones, phenyls, sulfonic acid and carboxylic acids, which radicals may be further substituted and have functional structures.

  通式为##STR1##的N-苯磺酰-N'-嘧啶基脲和-N'-三嗪基脲，以及这些化合物与胺、碱金属碱和碱土金属碱或季铵碱的盐，在施用前和施用后具有良好的选择性除草和植物生长调节性能。 在公式中，R.sub.1是氢、卤素、硝基、C.sub.1-C.sub.4卤代烷基、C.sub.1-C.sub.4烷基、C.sub.1-C.sub.4烷氧基、C.sub.2-C.sub.5烯基或C.sub.1-C.sub.4烷氧羰基，R.sub.2是C.sub.1-C.sub.3烷基或C.sub.1-C.sub.3烷氧基，每个未取代或取代1至3个卤素原子，R.sub.3是卤素、氢、-NR.sub.4R.sub.5、C.sub.1-C.sub.3烷基，未取代或取代1至3个卤素原子或C.sub.1-C.sub.4烷氧基，或是C.sub.1-C.sub.3烷氧基，未取代或取代甲氧基、乙氧基或1至3个卤素原子，R.sub.4是氢或甲基，R.sub.5是氢、C.sub.1-C.sub.2烷基或甲氧基，A是C.sub.1-C.sub.4亚烷基或C.sub.2-C.sub.4烯基，每个未取代或取代C.sub.1-C.sub.4烷基，m为0或1，E是氮或亚甲基基，X是氧、硫、-SO-或-SO.sub.2-，Q是羟基、氰基或从5-或6-成员杂环环和融合同系物、胺、缩醛、酯、酮、苯基、磺酸和羧酸中选择的基团，这些基团可能进一步取代并具有功能结构。
• Disperse dyes which are convertible into a thermo-migration fast form
  申请人：Ciba-Geigy Corporation

  公开号：US05055567A1

  公开（公告）日：1991-10-08

  The dyes according to the invention consist of a chromophore and a radical which, on heating, forms an isocyanate or isothiocyanate group. The latter reacts with a suitable group in the environment. Dyeings of excellent thermomigration fastness are obtained. The disclosed dyes are of the formulae ##STR1## where F is the radical of an azo, anthraquinone or tricyanovinyl dye which is free of water-solubilizing groups, B and B' are each independently of the other a direct bond or a bridge member, selected from the group consisting of a straight-chain or branched alkylene group having 2 to 8 C atoms or one of the following groups ##STR2## where R is hydrogen or C.sub.1 -C.sub.6 alkyl, n is an integer from 1 to 8 and m is an integer from 2 to 4, Z is O or S, V is a group which at a temperature between 180.degree. and 240.degree. C. is eliminated as a radical HV, and V' is a direct bond which is cleaved at a temperature between 180.degree. and 240.degree. C. or is a group which at such temperature turns, by ring opening and cleavage of the bond V'-C, into a group V'H, with the provisos that in the azo dyes the diazo component is not aminobenzisothiazole and the coupling component is not N-(.beta.-phenylureidoethyl)-1-naphthylamine when the diazo component is 2,4-dinitro-6-bromoaniline.

  根据该发明，染料由一个色团和一个基团组成，当加热时，形成异氰酸酯或异硫氰酸酯基团。后者与环境中的适当基团发生反应。获得了具有优异热迁移牢固性的染色。所披露的染料为以下公式的其中之一：其中F为不含水溶性基团的偶氮染料、蒽醌染料或三氰乙烯染料的基团，B和B'各自独立于另一个，选自直链或支链烷基基团，其碳原子数为2至8，或以下列基团之一的桥联成员：其中R为氢或C1-C6烷基，n为1至8的整数，m为2至4的整数，Z为O或S，V为在180度至240度C之间温度下作为基团HV消除的基团，V'为在180度至240度C之间温度下断裂的直链或转变为基团V'H的基团，但在偶氮染料中，偶氮组分不是氨基苯并异噻唑，偶联组分不是N-（β-苯基脲基乙基）-1-萘胺，当偶氮组分为2,4-二硝基-6-溴苯胺时。
• Multifunctional lubricant additives
  申请人：Ciba-Geigy Corporation

  公开号：US05320764A1

  公开（公告）日：1994-06-14

  Novel compounds of the formula (I) ##STR1## in which X is oxygen or sulfur, R and R.sub.1 independently of one another are C.sub.3 -C.sub.30 alkyl, R.sub.2 is C.sub.4 -C.sub.18 alkyl and R.sub.3, R.sub.4, R.sub.5 and R.sub.6 independently of one another are H, C.sub.1 -C.sub.20 alkyl, C.sub.3 -C.sub.20 alkenyl, benzyl, phenyl or phenyl which is substituted by C.sub.1 -C.sub.12 alkyl, and in which R.sub.5 and R.sub.6 can also be a direct bond, or R.sub.3 and R.sub.4 together are trimethylene, tetramethylene, ##STR2## and R.sub.5 and R.sub.6 are a direct bond or H, or in each case R.sub.3 and R.sub.6 together are a group .dbd.CH.sub.2 and R.sub.4 and R.sub.5 are H, or R.sub.4 and R.sub.5 together are a group .dbd.CH.sub.2 and R.sub.3 and R.sub.6 are H, or R.sub.3, R.sub.4, R.sub.5 and R.sub.6 together are ##STR3## and salts of these compounds, are described. They can be employed as multipurpose additives, in particular as anticorrosion, high pressure and antiwear additives, and as antioxidants in the lubricants and hydraulic or metalworking fluids.

  化合物的新型式(I)##STR1##其中X为氧或硫，R和R.sub.1独立地为C.sub.3-C.sub.30烷基，R.sub.2为C.sub.4-C.sub.18烷基，R.sub.3，R.sub.4，R.sub.5和R.sub.6独立地为H，C.sub.1-C.sub.20烷基，C.sub.3-C.sub.20烯基，苄基，苯基或被C.sub.1-C.sub.12烷基取代的苯基，并且其中R.sub.5和R.sub.6也可以是直接键，或者R.sub.3和R.sub.4一起是三亚甲基，四亚甲基，##STR2##和R.sub.5和R.sub.6是直接键或H，或者在每种情况下，R.sub.3和R.sub.6一起是群.dbd.CH.sub.2，R.sub.4和R.sub.5是H，或者R.sub.4和R.sub.5一起是群.dbd.CH.sub.2，R.sub.3和R.sub.6是H，或者R.sub.3，R.sub.4，R.sub.5和R.sub.6一起是##STR3##以及这些化合物的盐被描述。它们可以用作多用途添加剂，特别是作为防腐，高压和抗磨添加剂，并且作为润滑剂和液压或金属加工液中的抗氧化剂。