Effect of the surfactant head-group size dependence of the dye-surfactant interactions on the lyotropic uniaxial to biaxial nematic phase transitions
作者:Erol Akpinar、Nazli Uygur、Oznur Demir Ordu、Dennys Reis、Antônio Martins Figueiredo Neto
DOI:10.1016/j.molliq.2021.115842
日期:2021.6
surfactants in lyotropic mixtures have been investigated for the stabilization of the different lyotropic nematic phases. Sunset Yellow doped mixtures of DAABr surfactants, with different head-group size, were studied by polarizing optical microscopy, laser conoscopy, and small-angle X-ray scattering. It was found that the extent of the interaction of Sunset Yellow with DAABr surfactant head groups on micelle
Heating-Induced Micelle to Vesicle Transition in the Cationic−Anionic Surfactant Systems: Comprehensive Study and Understanding
作者:Haiqing Yin、Jianbin Huang、Yiyang Lin、Yongyi Zhang、Shunchen Qiu、Jianping Ye
DOI:10.1021/jp045158a
日期:2005.3.1
Heating-induced micelle to vesicle transition (MVT), which has been rarely reported in surfactant systems, was systemically studied in a number of mixed cationic-anionic surfactant systems. According to the turbidity measurements, the investigated systems can be divided into two classes: Class A and B. Heating-induced MVT was observed in Class A at certain total surfactant concentrations and mixed surfactant ratios, while no such transition was found in Class B. Further investigations revealed that the heating-induced MVT is more likely to take place in the cationic-anionic surfactant systems with relatively stronger molecule interaction and larger micelle aggregation number. The effects of several physicochemical factors, such as the variation of mixed surfactant ratios and the addition of n-decanol on the heating-induced MVT, were also studied.