Phenanthrolin-5-sulfonsaeure | 33388-36-2

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 菲咯啉
• 英文名称: Phenanthrolin-5-sulfonsaeure
• 英文别名: 5-sulfo-1,10-phenanthroline；[1,10]phenanthroline-5-sulfonic acid；1,10-phenanthroline-5-sulphonic acid；1,10-Phenanthroline-5-sulfonic acid
• CAS: 33388-36-2
• 化学式: C₁₂H₈N₂O₃S
• 分子量: 260.273
• InChiKey: AGQSHPFFJUBBHR-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.2
• 重原子数：
  18
• 可旋转键数：
  1
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  88.5
• 氢给体数：
  1
• 氢受体数：
  5

反应信息

• 作为反应物：
  描述：

  cobalt(II) chloride hexahydrate 、 Phenanthrolin-5-sulfonsaeure 在 NaOH 、 H₂O₂ 、 HCl 作用下， 以 水 为溶剂， 生成 [Co(III)(5-sulfonato-1.10-phenanthroline)3]*10H2O
  参考文献：
  名称：

  Kjaer; Ulstrup, Inorganic Chemistry, 1986, vol. 25, # 5, p. 644 - 651

  摘要：

  DOI：

文献信息

• Electronically Neutral Metal Complexes As Biological Labels
  申请人：RUBIPY SCIENTIFIC, INC.

  公开号：US20160146826A1

  公开（公告）日：2016-05-26

  The invention relates to electronically neutral metal complexes as luminescent labels. The positive charge of the metal ion in the complex is neutralized by the negatively charged groups that are covalently linked to the nitrogen-containing diimine ligands, such as 2,2-bipyridine, 1,10-phenanthroline and their derivatives. The electronic neutrality reduces the impact of the metal complexes on the biological and/or biochemical activities of the labeled biomolecules, while the intensity of luminescent emission under electrochemical excitation is enhanced. These luminescent metal complex labels are useful in bioanalytic methodology development, with luminescence as the signal modality, such as electrochemiluminescence.

  该发明涉及作为发光标记的电子中性金属配合物。该配合物中金属离子的正电荷被共价连接到含氮双亚胺配体（如2,2-联吡啶，1,10-邻菲啰啉及其衍生物）上的带负电荷基团中和。电子中性减少了金属配合物对标记生物分子的生物和/或生化活性的影响，同时在电化学激发下增强了发光发射的强度。这些发光金属配合物标记在生物分析方法学的发展中非常有用，发光作为信号模态，如电化学发光。
• Process for the dimerization of olefins
  申请人：SHELL INTERNATIONALE RESEARCH MAATSCHAPPIJ B.V.

  公开号：EP0170311A2

  公开（公告）日：1986-02-05

  A process for the dimerization in the liquid phase of an aliphatic mono-olefin having 2 to 12 carbon atoms with a catalytic system formed by combining, in the presence of water, an alcohol or a carboxylic acid:- a) a palladium compound, b) a chelate ligand having as coordinating atoms at least two Group 5a atoms which are connected through a chain comprising 2 to 6 carbon atoms, and c) a compound containing an anion of an acid, except hydrohalogenic acids.

  一种使具有 2 至 12 个碳原子的脂族单烯烃在液相中进行二聚化的工艺，其催化系 统是在有水、醇或羧酸存在的情况下：a)钯化合物；b)螯合配体，其配位原子为至少两个 5a 族原子，这两个原子通过由 2 至 6 个碳原子组成的链相连；以及 c)含有酸阴离子的化合物，但氢卤酸除外。
• Process for the dimerization of ethylenically unsaturated compounds
  申请人：SHELL INTERNATIONALE RESEARCH MAATSCHAPPIJ B.V.

  公开号：EP0206367A2

  公开（公告）日：1986-12-30

  The dimerization of acrylate esters and of ethene and the codimerization of acrylate esters with C2-4-alkenes or 1,3-butadiene and of 1,3-butadiene with ethene in the presence of: (a) a Pd and/or Ru compound, (b) a compound containing one trivalent N or P atom, and (c) an Ag and/or Cu salt, yields at an increased reaction rate dimers of high linearity, when a quinone is also present.

  丙烯酸酯和乙烯的二聚化，以及丙烯酸酯与 C2-4- 烷烃或 1,3-丁二烯和 1,3-丁二烯与乙烯在下列物质存在下的共聚化： (a) Pd 和/或 Ru 化合物、 (b) 含一个三价 N 原子或 P 原子的化合物，以及 (c) Ag 和/或 Cu 盐，在同时存在醌的情况下，以更高的反应速率生成线性度更高的二聚 物。
• Process for the preparation of organic isocyanates
  申请人：SHELL INTERNATIONALE RESEARCH MAATSCHAPPIJ B.V.

  公开号：EP0224292A1

  公开（公告）日：1987-06-03

  Process for the preparation of organic isocyanates by reacting an aromatic nitro compound with carbon monoxide in the presence of (a) Pd or a Pd compound, (b) a ligand of formula in which X and Y are the same or different bridging groups each of which has 3 or 4 atoms in the bridge, of which atoms at least two are carbon atoms and which groups X and Y may be bound to each other, and (c) one or more protonic acids, except hydrohalogenic acids.

  通过芳香族硝基化合物与一氧化碳在(a)钯或钯化合物，(b)式配位体的存在下反应制备有机异氰酸酯的工艺，其中X和Y为相同或不同的桥基，每个桥基有3或4个原子，其中至少两个原子为碳原子，X和Y基团可相互结合。 其中 X 和 Y 为相同或不同的桥基，每个桥基有 3 或 4 个原子，其中至少有两个原子为碳原子，且基团 X 和 Y 可相互结合，以及 (c) 一种或多种质子酸，但氢卤酸除外。
• Novel catalyst compositions and process for the copolymerization of ethene with carbon monoxide
  申请人：SHELL INTERNATIONALE RESEARCH MAATSCHAPPIJ B.V.

  公开号：EP0229408A1

  公开（公告）日：1987-07-22

  Process for the preparation of copolymers, carbon monoxide with ethene and optionally also another olefinically unsaturated hydrocarbon in the presence of a novel catalyst composition comprising a) a palladium compound, b) an anion of an acid with a pKa of less than 4, with the proviso that the acid is not a hydrohalogenic acid, and c) a nitrogen bidentate ligand of the general formula wherein X and Y represent similar or different organic bridging groups, each containing three or four atoms in the bridge at least two of which are carbon atoms, and optionally, d) an organic oxidant.

  在一种新型催化剂组合物存在下制备一氧化碳与乙烯和另一种烯烃不饱和烃共聚物的工艺，该催化剂组合物包括 a) 钯化合物；b) pKa 小于 4 的酸阴离子，但该酸不是氢卤酸；c) 通式中的氮双齿配位体，其中 X 和 Y 代表相似或不同的有机桥基，每个桥基含有三个或四个原子，其中至少两个是碳原子；以及 d) 有机氧化剂。