1-Chloroethyl 2,2,2-Trifluoroethyl Carbonate | 91507-75-4

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 有机碳酸及其衍生物
• 英文名称: 1-Chloroethyl 2,2,2-Trifluoroethyl Carbonate
• CAS: 91507-75-4
• 化学式: C₅H₆ClF₃O₃
• 分子量: 206.549
• InChiKey: LCIBVQZEJYVYTR-UHFFFAOYSA-N

物化性质

• 沸点：
  54-56 °C(Press: 5 Torr)
• 密度：
  1.385±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  2.8
• 重原子数：
  12
• 可旋转键数：
  4
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.8
• 拓扑面积：
  35.5
• 氢给体数：
  0
• 氢受体数：
  6

反应信息

• 作为反应物：
  描述：

  1-Chloroethyl 2,2,2-Trifluoroethyl Carbonate 在 18-冠醚-6 potassium fluoride 作用下， 以 苯甲腈 为溶剂， 25.0 ℃ 、1.33 kPa 条件下， 反应 24.0h， 以75%的产率得到2,2,2-Trifluoroethyl Fluoroformate
  参考文献：
  名称：

  A simple conversion of 1-chloroethyl carbonates to fluoroformates: value in the preparation of tertiary alkyl fluoroformates

  摘要：

  DOI：

  10.1021/jo00293a032
• 作为产物：
  描述：

  2,2,2-三氟乙醇 、 1-氯乙基氯甲酸酯 在 吡啶 作用下， 以 二氯甲烷 为溶剂， 反应 15.0h， 以91%的产率得到1-Chloroethyl 2,2,2-Trifluoroethyl Carbonate
  参考文献：
  名称：

  A simple conversion of 1-chloroethyl carbonates to fluoroformates: value in the preparation of tertiary alkyl fluoroformates

  摘要：

  DOI：

  10.1021/jo00293a032

文献信息

• Synthesis, acaricidal activities and docking study of novel acrylonitrile derivatives
  作者：Liang-Kun Zhong、Sheng-Jie Kang、Cheng-Xia Tan、Jian-Quan Weng、Tian-Ming Xu、Xing-Hai Liu

  DOI：10.24820/ark.5550190.p011.074

  日期：——

  A series of novel acrylonitrile derivatives containing a flexible chain were designed using cyflumetofen as lead compound. They were synthesized via two steps. The structures were confirmed by 1H NMR, 13C NMR and HRMS. The title acrylonitrile derivatives exhibited good acaricidal activity against Tetranchus urticae. In particular, 3j possessed excellent activity in the green house, at the same level

  以氟虫腈为先导化合物，设计了一系列含有柔性链的新型丙烯腈衍生物。它们通过两个步骤合成。结构经1H NMR、13C NMR和HRMS证实。标题丙烯腈衍生物对荨麻疹表现出良好的杀螨活性。尤其是，3j 在温室中具有极好的活性，在 4 天或 7 天时与对照氟美托芬处于同一水平。
• Process for the preparation of fluoroalkyl (fluoro)alkyl carbonates and carbamates
  申请人：Bomkamp Martin

  公开号：US20120116111A1

  公开（公告）日：2012-05-10

  Fluoroalkyl alkyl carbonates and fluorosubstituted carbamates which are suitable as additives or solvents in lithium ion batteries are prepared from fluoroalkyl fluoroformates and the respective alcohol or amine. Methanol is the preferred alcohol, dimethylamine and diethylamine are preferred amines. Fluoromethyl methyl carbonate is the preferred compound to be produced. Fluoroalkyl fluoroformates can be prepared from aldehydes and carbonyl fluoride.

  氟烷基烷基碳酸酯和氟代氨基甲酸酯，可用作锂离子电池中的添加剂或溶剂。它们是由氟烷基氟甲酸酯和相应的醇或胺制备而成。甲醇是首选醇，二甲胺和二乙胺是首选胺。氟甲基甲基碳酸酯是首选要制备的化合物。氟烷基氟甲酸酯可以由醛和羰基氟制备。
• PROCESS FOR THE PREPARATION OF FLUOROALKYL (ALKYL CARBONATES AND CARBAMATES
  申请人：SOLVAY FLUOR GMBH

  公开号：US20150191414A1

  公开（公告）日：2015-07-09

  Fluoroalkyl alkyl carbonates and fluorosubstituted carbamates which are suitable as additives or solvents in lithium ion batteries are prepared from fluoroalkyl fluoroformates and the respective alcohol or amine. Methanol is the preferred alcohol, dimethylamine and diethylamine are preferred amines. Fluoromethyl methyl carbonate is the preferred compound to be produced. Fluoroalkyl fluoroformates can be prepared from aldehydes and carbonyl fluoride.

  氟烷基烷基碳酸酯和氟代氨基甲酸酯可用作锂离子电池中的添加剂或溶剂，它们是由氟烷基氟甲酸酯和相应的醇或胺制备而成。甲醇是首选的醇，二甲胺和二乙胺是首选的胺。氟甲基甲基碳酸酯是首选的化合物。氟烷基氟甲酸酯可以由醛和羰基氟制备。
• PROCESS FOR THE PREPARATION OF FLUOROALKYL FLUOROFORMATES
  申请人：Solvay Fluor GmbH

  公开号：EP3214066A2

  公开（公告）日：2017-09-06

  Fluoroalkyl alkyl carbonates and fluorosubstituted carbamates which are suitable as additives or solvents in lithium ion batteries are prepared from fluoroalkyl fluoroformates and the respective alcohol or amine. Methanol is the preferred alcohol, dimethylamine and diethylamine are preferred amines. Fluoromethyl methyl carbonate is the preferred compound to be produced. Fluoroalkyl fluoroformates can be prepared from aldehydes and carbonyl fluoride.

  适用于锂离子电池添加剂或溶剂的氟烷基烷基碳酸盐和氟代氨基甲酸酯是由氟烷基氟甲酸酯和相应的醇或胺制备而成。甲醇是首选的醇，二甲胺和二乙胺是首选的胺。氟甲基碳酸甲酯是首选化合物。 氟烷基氟甲酸酯可由醛和羰基氟化物制备。
• DANG, VU ANH;OLOFSON, R. A.;WOLF, PATRICK R.;PITEAU, MARC D.;SENET, JEAN-+, J. ORG. CHEM., 55,(1990) N, C. 1847-1851
  作者：DANG, VU ANH、OLOFSON, R. A.、WOLF, PATRICK R.、PITEAU, MARC D.、SENET, JEAN-+

  DOI：——

  日期：——