C-1-naphthylresorcin[4]arene | 916134-80-0

• 分子结构分类: 有机化合物 - 苯类化合物 - 萘
• 英文名称: C-1-naphthylresorcin[4]arene
• 英文别名: 2,8,14,20-Tetranaphthalen-1-ylpentacyclo[19.3.1.13,7.19,13.115,19]octacosa-1(25),3(28),4,6,9(27),10,12,15,17,19(26),21,23-dodecaene-4,6,10,12,16,18,22,24-octol
• CAS: 916134-80-0
• 化学式: C₆₈H₄₈O₈
• 分子量: 993.124
• InChiKey: CDBKFJRTJGTVJU-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  15.7
• 重原子数：
  76
• 可旋转键数：
  4
• 环数：
  13.0
• sp3杂化的碳原子比例：
  0.06
• 拓扑面积：
  162
• 氢给体数：
  8
• 氢受体数：
  8

反应信息

• 作为反应物：
  描述：

  C-1-naphthylresorcin[4]arene 在 氨 作用下， 以 水 为溶剂， 反应 0.5h， 以45.7%的产率得到4,6,10,12,16,18,22,24-octaamino-2,8,14,20-tetra(1-naphthyl)pentacyclo[19.3.1.1(3.7).1(9.13).1(15.19)]octacosa-1⁽²⁵⁾,3,5,7⁽²⁸⁾,9,11,13⁽²⁷⁾,15,17,19⁽²⁶⁾,21,23-dodecane
  参考文献：
  名称：

  Amination of calix[4]resorcinarenes. First synthesis of calix[4]phenylenediamines

  摘要：

  DOI：

  10.1134/s1070363210030333
• 作为产物：
  描述：

  1-萘甲醛 、 间苯二酚 在 盐酸 作用下， 以 乙醇 、 水 为溶剂， 反应 8.0h， 生成 C-1-naphthylresorcin[4]arene
  参考文献：
  名称：

  Syntheses and characterization of aryl-substituted pyrogallol[4]arenes and resorcin[4]arenes

  摘要：

  合成并表征了十三种芳基取代的焦高酚[4]芳烃和间苯二酚[4]芳烃结构。系统地研究和讨论了不同芳基侧链对π-π距离、侧链-R基团的内倾角、侧链-R基团的扭曲角度以及侧链-R基团之间角度的影响。

  DOI：

  10.1039/c5ce01792k

文献信息

• Regioselective Synthesis and Structure of New Oligophosphorylated <i>rctt</i> Resorcinarenes
  作者：Vera I. Maslennikova、Olga S. Serkova、Tatiana V. Guzeeva、Konstantin A. Lyssenko、Irina I. Levina、Valentina V. Glushko、Eduard E. Nifantyev

  DOI：10.1080/10426507.2010.531489

  日期：2011.8.1
• Pre-organized oligomodified resorcinarene ligands. Preparation, structure, and complex formation
  作者：O. S. Serkova、A. V. Burikhina、L. K. Vasyanina、O. S. Kuprina、V. I. Maslennikova、E. E. Nifantiev

  DOI：10.1134/s1070363214040240

  日期：2014.4

  Interaction of various conformations of resorcinarenes with carbamoyl chloride, thiocarbamoyl chloride, and trifluoromethanesulfonic acid anhydride has resulted in a series of derivatives with certain pre-organization of the macrocyclic scaffold and the immobilized electron-donating groups. Complex formation of the selected prepared compounds towards Pd(II) derivatives has been studied.
• PROCESS FOR PRODUCING CARBON MATERIAL
  申请人：Suzuki Junji

  公开号：US20100298522A1

  公开（公告）日：2010-11-25

  A process for producing a carbon material comprising the following steps (A) and (B): Step (A): a step of reacting a compound represented by the formula (1): wherein R represents a hydrogen atom etc., R′ represents a hydrogen atom etc., and n represents 3, 5 or 7, with an aldehyde compound to obtain a polymer, Step (B): a step of heating the polymer obtained in Step (A) at 600 to 3000° C. under an inert gas atmosphere.
• [EN] PROCESS FOR PRODUCING CARBON MATERIAL<br/>[FR] PROCÉDÉ DE FABRICATION D'UNE MATIÈRE CARBONÉE
  申请人：SUMITOMO CHEMICAL CO

  公开号：WO2009101947A2

  公开（公告）日：2009-08-20

  A process for producing a carbon material comprising the following steps (A) and (B): Step (A): a step of reacting a compound represented by the formula (1): wherein R represents a hydrogen atom etc., R' represents a hydrogen atom etc., and n represents 3, 5 or 7, with an aldehyde compound to obtain a polymer, Step (B): a step of heating the polymer obtained in Step (A) at 600 to 3000oC under an inert gas atmosphere.