furan-2-ylcarboxylic acid tetrahydrofuran-2-ylmethyl ester | 4623-04-5

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 呋喃
• 英文名称: furan-2-ylcarboxylic acid tetrahydrofuran-2-ylmethyl ester
• 英文别名: furan-2-carboxylic acid tetrahydrofurfuryl ester；Furan-2-carbonsaeure-tetrahydrofurfurylester；<2>Furancarbonsaeure-tetrahydrofurfurylester；2-Furancarboxylic acid, 2-tetrahydrofurylmethyl ester；oxolan-2-ylmethyl furan-2-carboxylate
• CAS: 4623-04-5
• 化学式: C₁₀H₁₂O₄
• 分子量: 196.203
• InChiKey: VTGUMPUFLSYIEV-UHFFFAOYSA-N

物化性质

• 沸点：
  96 °C(Press: 0.25 Torr)
• 密度：
  1.182±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  1.6
• 重原子数：
  14
• 可旋转键数：
  4
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.5
• 拓扑面积：
  48.7
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为产物：
  描述：

  四氢糠醇 、 糠酸（呋喃甲酸） 在 硫酸 作用下， 生成 furan-2-ylcarboxylic acid tetrahydrofuran-2-ylmethyl ester
  参考文献：
  名称：

  ESTERS OF ALPHA-TETRAHYDROFURFURYL ALCOHOL

  摘要：

  DOI：

  10.1021/ja01393a053

文献信息

• Catalytic pyrolysis of cellulose in ionic liquid [bmim]OTf
  作者：Guangfei Qu、Weiwei He、Yingying Cai、Xi Huang、Ping Ning

  DOI：10.1016/j.carbpol.2016.04.052

  日期：2016.9

  This study discussed the catalytic cracking process of cellulose in ionic liquid 1-butyl-3-methylimidazolium trifluoromethanesulfonate ([bmim]OTF) under 180°C, 240°C and 340°C, found that [bmim]OTF is an effective catalyst which can effectively reduce the pyrolysis temperature(nearly 200°C) of the cellulose. FRIR, XRD and SEM were used to analyze the structure characterization of fiber before and after

  这项研究探讨了纤维素在离子液体1-丁基-3-甲基咪唑鎓三氟甲磺酸盐（[bmim] OTF）中在180°C，240°C和340°C下的纤维素催化裂化过程，发现[bmim] OTF是一种有效的催化剂。可以有效降低纤维素的热解温度（近200℃）。FRIR，XRD和SEM分析了开裂前后纤维的结构特征。GC-MS用于液相产物分析；气相色谱用于分析气相产物。结果表明，[bmim] OTf中的纤维素热解主要生成CO2，CO和H2，还生成2-糠醇，2,5-二甲基-1,5-二烯丙基-3-醇，1,4-丁内酯，5 -甲基糠醛，4-羟基丁酸，丙酸乙烯酯，1-乙酰氧基-2-丁酮，呋喃甲酸四氢呋喃甲酯液体产品，
• Yarn conditioning process
  申请人：EASTMAN KODAK CO

  公开号：US02198000A1

  公开（公告）日：1940-04-23
• [EN] ELECTROCATALYTIC HYDROGENATION AND HYDRODEOXYGENATION OF OXYGENATED AND UNSATURATED ORGANIC COMPOUNDS<br/>[FR] HYDROGÉNATION ET HYDRODÉSOXYGÉNATION ÉLECTROCATALYTIQUES DE COMPOSÉS ORGANIQUES OXYGÉNÉS ET INSATURÉS
  申请人：UNIV MICHIGAN STATE

  公开号：WO2013134220A1

  公开（公告）日：2013-09-12

  A process and related electrode composition are disclosed for the electrocatalytic hydrogenation and/or hydrodeoxygenation of biomass-derived bio-oil components by the production of hydrogen atoms on a catalyst surface followed by the reaction of the hydrogen atoms with the organic compounds in bio-oil. The catalyst is a metal supported on a monolithic high surface area material such as activated carbon cloth. Electrocatalytic hydrogenation and/or hydrodeoxygenation stabilizes the bio-oil under mild conditions to reduce coke formation and catalyst deactivation. The process converts oxygen-containing functionalities and unsaturated bonds into chemically reduced forms with an increased hydrogen content. The process is operated at mild conditions, which enables it to be a good means for stabilizing bio-oil to a form that can be stored and transported using metal containers and pipes.