11-dodecenyl chloride | 117599-67-4

• 分子结构分类: 有机化合物 - 有机卤素化合物 - 有机氯化物
• 英文名称: 11-dodecenyl chloride
• 英文别名: 12-Chlorododec-1-ene
• CAS: 117599-67-4
• 化学式: C₁₂H₂₃Cl
• 分子量: 202.768
• InChiKey: QPKMYSABIIWIIS-UHFFFAOYSA-N

物化性质

• 沸点：
  255.3±9.0 °C(Predicted)
• 密度：
  0.869±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  5.9
• 重原子数：
  13
• 可旋转键数：
  10
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.83
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  11-dodecenyl chloride 在 sodium tetrahydroborate 、 mercury(II) diacetate 作用下， 以90%的产率得到12-chlorododecanol
  参考文献：
  名称：

  官能化烯烃与乙酰氧基硼氢化物的硼氢化

  摘要：

  据报道，乙酰氧基硼氢化物使官能化的烯烃的CC氢硼化而不影响官能团。

  DOI：

  10.1016/s0040-4039(00)61114-0

文献信息

• [EN] NOVEL RUTHENIUM COMPLEX, METHOD OF ITS PRODUCTION AND ITS USE IN REACTION OF OLEFINE METATHESIS<br/>[FR] NOUVEAU COMPLEXE DE RUTHÉNIUM, SON PROCÉDÉ DE PRODUCTION ET SON UTILISATION DANS LA RÉACTION DE MÉTATHÈSE D'OLÉFINES
  申请人：UNIV WARSZAWSKI

  公开号：WO2018100515A1

  公开（公告）日：2018-06-07

  The invention relates to novel ruthenium complexes of formula (9). The invention also relates to the method for preparation of novel metal complexes of formula (9) and their use in olefin metathesis reactions.

  该发明涉及公式（9）的新型钌配合物。该发明还涉及制备公式（9）的新金属配合物的方法以及它们在烯烃交换反应中的应用。
• Cyclic Alkyl Amino Carbene (CAAC) Ruthenium Complexes as Improved Catalysts for Ethenolysis Reactions
  申请人：Marx Vanessa M.

  公开号：US20140309433A1

  公开（公告）日：2014-10-16

  Described herein are compounds and methods of catalyzing ethenolysis reactions, optionally on an industrial scale. In certain embodiments, the catalysts bear cyclic alkyl amino carbene (CAAC) ligands with an ortho substituent, such as a methyl substituent, on an N-aryl ring. When used to catalyze ethenolysis reactions, certain such compounds produce a turnover number greater than 50,000.

  本文描述了化合物和催化乙烯裂解反应的方法，可选择在工业规模上进行。在某些实施例中，催化剂带有带有一个N-芳基环上的一个类环烷基氨基甲烷（CAAC）配体的邻位取代基，例如一个甲基取代基。当用于催化乙烯裂解反应时，某些这样的化合物产生的周转次数大于50,000。
• PROCESSES FOR PREPARING ESTOLIDE BASE OILS AND OLIGOMERIC COMPOUNDS THAT INCLUDE CROSS METATHESIS
  申请人：Thompson Travis

  公开号：US20130158277A1

  公开（公告）日：2013-06-20

  Provided herein are estolide base oils and oligomeric compounds prepared from processes that include cross metathesis. Exemplary processes include the preparation of terminally-unsaturated fatty acids by cross metathesis, and the subsequent oligomerization of terminally-unsaturated fatty acids to provide estolide compounds, such as the process set forth below:

  本文提供了通过交叉重合反应制备的酯基油和寡聚化合物。示例过程包括通过交叉重合反应制备末端不饱和脂肪酸，以及随后的末端不饱和脂肪酸寡聚化制备酯基化合物，例如下面所述的过程：
• Methods of Making Functionalized Internal Olefins and Uses Thereof
  申请人：Elevance Renewable Sciences, Inc.

  公开号：US20140171677A1

  公开（公告）日：2014-06-19

  A method of isomerizing a substance includes combining a substance including a terminal alkenyl group and a substance including a fluorosulfonic acid group in a reaction mixture, and forming a substance including a 2-alkenyl group from the substance including a terminal alkenyl group in the reaction mixture. The method may be used to functionalize a substance, as the substance including a 2-alkenyl group can be reacted with a functionalizing agent to form a substance including a first functional group. The methods may be used to form a dicarboxylic acid, such as suberic acid, from a renewable feedstock.

  一种异构化物质的方法包括将包含末端烯基基团的物质和包含氟磺酸基团的物质组合在反应混合物中，并从反应混合物中的包含末端烯基基团的物质形成包含2-烯基基团的物质。该方法可用于官能化物质，因为包含2-烯基基团的物质可以与官能化剂反应，形成包含第一官能团的物质。该方法可用于从可再生原料形成二羧酸，例如戊二酸。
• PROCESSES FOR PREPARING ESTOLIDE BASE OILS AND BIOBASED COMPOUNDS THAT INCLUDE ETHYLENEOLYSIS
  申请人：BIOSYNTHETIC TECHNOLOGIES, LLC.

  公开号：US20160244397A1

  公开（公告）日：2016-08-25

  Provided herein are compounds prepared from processes that include ethyleneolysis. Exemplary processes include the preparation of terminally-unsaturated fatty acid reactant by ethyleneolysis catalyzed by a cyclic alkyl amino carbene ruthenium complex. The subsequent oligomerization of terminally-unsaturated fatty acid reatants provides estolide compounds, as exemplified by the process set forth below:

  本文提供的化合物是通过乙烯解聚等过程制备的。其中，乙烯解聚催化剂采用环状烷基氨基卡宾钌配合物，用于制备末端不饱和脂肪酸反应物。随后，末端不饱和脂肪酸反应物的寡聚化提供了酯酰化合物，例如下面所示的过程：