4,4-dichloro-1-pentene | 49771-39-3

• 分子结构分类: 有机化合物 - 有机卤素化合物 - 有机氯化物
• 英文名称: 4,4-dichloro-1-pentene
• 英文别名: 4,4-dichloro-pent-1-ene；4,4-Dichlor-pent-1-en；1,1-(2,2-Dichloropropyl)-ethylene；4,4-dichloropent-1-ene
• CAS: 49771-39-3
• 化学式: C₅H₈Cl₂
• 分子量: 139.025
• InChiKey: ILSNLCRIGREMTG-UHFFFAOYSA-N

物化性质

• 沸点：
  137.2±20.0 °C(Predicted)
• 密度：
  1.077±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  2.9
• 重原子数：
  7
• 可旋转键数：
  2
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.6
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为产物：
  描述：

  三氯乙烷 、 烯丙基三(三甲基硅基)硅烷 在 2-(2-cyanopropan-2-yldiazenyl)-2-methylpropanenitrile 作用下， 以 苯 为溶剂， 反应 1.0h， 以49%的产率得到4,4-dichloro-1-pentene
  参考文献：
  名称：

  Allyltris(trimethylsilyl)silane as Radical Allylating Agent for Organic Halides

  摘要：

  在自由基条件下，烯丙基三(三甲基硅基)硅烷与有机卤化物发生反应，从而使卤化物发生烯丙基化反应，产率达到良好水平。硅上三个三甲基硅基的存在可增强 β-硅烷基自由基中 Si-C 键的同解。

  DOI：

  10.1246/cl.1991.1327

文献信息

• Free Radical Chain Reaction of Allylic Tin Compounds with Organic Halides Involving S_H′ Process
  作者：Toshihiko Migita、Kazukiyo Nagai、Masanori Kosugi

  DOI：10.1246/bcsj.56.2480

  日期：1983.8

  Negatively substituted halomethanes were allylated easily by allyltin compounds via radical chain reaction involving SH′ process. Aryl, aralkyl, and alkyl halides underwent similar chain reactions only when the tin compound was charged in excessive amounts.

  负取代的卤代甲烷很容易被烯丙基锡化合物通过涉及 SH' 过程的自由基链反应进行烯丙基化。只有当锡化合物加入过量时，芳基、芳烷基和烷基卤才会经历类似的链式反应。
• RESIN COMPOSITION FOR INK-JET RECORDING SHEET AND RECORDING SHEET MADE WITH THE SAME
  申请人：DAICEL CHEMICAL INDUSTRIES, Ltd.

  公开号：EP1114734A1

  公开（公告）日：2001-07-11

  The present invention Nos. I-VII are a resin composition for an ink-jet recording sheet for constructing an image-receiving layer which is formed on at least one surface of a base material for an ink-jet recording sheet. The present invention No. I relates to a resin composition for an ink-jet recording sheet which comprises (1) 2-80% by mass of a cationic acrylic copolymer (A) having a crosslinkable group, (2) 5-80% by mass of a saponified product (B) of a vinyl acetate-based copolymer having a polymerization degree of 200-1000, and (3) 0-80% by mass of a modifier (R), the present invention No. II relates to a resin composition for an ink-jet recording sheet which contains (1) 2-80 wt% of a cationic acrylic copolymer (A) having a crosslinkable group, (2) 5-80 wt% of a saponified product (B) of a vinyl acetate-based copolymer, (3) (n1-80) wt% of a water-based polyurethane resin (C), (4) (n2-60) wt% of a polyurethane-based graft polymer mixture (D), and (5) (n3-60) wt% of a polyester-based graft polymer mixture (E) in a solid content-based ratio, and total is 100 wt%, in which there are satisfied conditions that a minimum value in n1, n2, and n3 is 0, and (n1+n2+n3) is ≥5, the present invention No. III relates to a resin composition for an ink-jet recording sheet which comprises, [1] 2-80% by weight of a cationic acrylic copolymer (A) having a crosslinkable group, [2] 5-60% by weight of a saponified product (B) of a vinyl acetate-based copolymer, and [3] 0-80% by weight of a water-based polyurethane resin (C) total of the (A), (B), and (C) is 100% by weight}, and [4] 0.05-10 parts by weight of a block isocyanate compound (F) based on 100 parts by weight of the saponified product (B) of a vinyl acetate-based copolymer, the present invention No. IV relates to a resin composition for an ink-jet recording sheet which comprises the use of 2-100% by weight of a cationic acrylic copolymer (A) composed of a monomer having an alkylene oxide group, a monomer having a hydrophilic group, a monomer having a crosslinkable group, a monomer containing cationic group, 0-90% by weight of a saponified product (B) of a vinyl acetate-based copolymer, and 5-60% by weight of a modifier (R), and an image-receiving layer is formed over at least one surface, the present invention No. V relates to a resin composition for an ink-jet recording sheet which comprises formulating 70-100% by weight of a cationic (meth)acrylic polymer (A) in which there are copolymerized a cationic (meth)acrylate monomer having a polyalkylene oxide group, a monomer having a hydrophilic group, a monomer having a crosslinkable group, a monomer containing cationic group, and a cationic monomer, 0-30% by weight of a saponified product (B) of a vinyl acetate-based copolymer (total thereof is 100% by weight), and 0-15 parts by weight of a modifier (R) based on 100 parts by weight of the (A) and the (B), the present invention No. VI relates to an ink-jet recording sheet which comprises being constructed by a composition containing a (meth)acrylic-based copolymer having a hydrolyzable silyl group in which a polymerizable unsaturated monomer having a hydrolyzable silyl group is copolymerized with monomers containing a (meth)acrylate-based polymerizable unsaturated monomer, and inorganic compound fine particles, the present invention No. VII relates to a resin composition for an ink-jet recording sheet characterized by containing 100 parts by weight of a resin composition composed of (1) 1-30% by weight of a cellulose derivative (A) and (2) 70-99% by weight of a good solvent (B) for the cellulose derivative (total is 100% by weight), (3) 0.1-20 parts by weight of an organic acid (C) which can dissolve in the good solvent (B) or a weak solvent (D) for the cellulose derivative, and optionally, (4) 0-150 parts by weight of a weak solvent (D) for the cellulose derivative, and relates to a recording sheet in which an image-receiving layer is formed on a body to be recorded composed of the resin composition. the present invention No. VIII is to provide a heat transfer sheet which is excellent in an ink-absorbing ability, an ink-fixing ability, and a printing ability in the case of molding into the heat transfer sheet, and which is high in a water resistance, durability, particularly, micro cracks resistance of a recorded picture, and in which an ink-receiving layer is formed on an elastic material, and micro cracks are not caused even though the recorded picture is expanded and shrunk, and a resin composition for constructing thereof, a resin composition containing a polymer (A) containing a monomer unit shown by a specified formula (1) and a hot-melt adhesive resin (B), a heat transfer sheet comprised the resin composition, and a method for the preparation thereof.

  本发明第I-VII号是一种喷墨记录薄片用树脂组合物，用于在喷墨记录薄片基材的至少一个表面上形成图像接收层。 本发明 I 涉及一种用于喷墨记录薄片的树脂组合物，该树脂组合物包括：(1) 2-80% （质量百分比）具有可交联基团的阳离子丙烯酸共聚物 (A)；(2) 5-80% （质量百分比）聚合度为 200-1000 的醋酸乙烯酯基共聚物的皂化产物 (B)；(3) 0-80% （质量百分比）改性剂 (R)、 本发明第II 涉及一种用于喷墨记录片材的树脂组合物，它含有 (1) 2-80 wt%的具有可交联基团的阳离子丙烯酸共聚物 (A)，(2) 5-80 wt%的醋酸乙烯酯基共聚物的皂化产物 (B)，(3) (n1-80) wt%的水基聚氨酯树脂 (C)、(4)(n2-60)重量％的聚氨酯基接枝聚合物混合物(D)，和(5)(n3-60)重量％的聚酯基接枝聚合物混合物(E)，以固含量为基础的比例，总计为100重量％，其中满足的条件是n1、n2和n3中的最小值为0，且(n1+n2+n3)≥5、 本发明 III 号涉及一种用于喷墨记录片材的树脂组合物，它包括：[1] 2-80% （重量比）具有可交联基团的阳离子丙烯酸共聚物 (A)、 [2] 5-60% （重量百分比）醋酸乙烯共聚物的皂化产品 (B)，以及 [3] 0-80%（重量）的水性聚氨酯树脂（C）(A)、(B)和(C)的总和为 100%（重量）}，以及 [4] 以 100 份醋酸乙烯酯基共聚物的皂化产物（B）为基数，加入 0.05-10 份 （重量）的嵌段异氰酸酯化合物（F）、 本发明 No.IV涉及一种用于喷墨记录片材的树脂组合物，它包括使用 2-100%（重量）的阳离子丙烯酸共聚物（A），该共聚物由具有环氧烷基的单体、具有亲水基团的单体、具有可交联基团的单体、含有阳离子基团的单体、0-90%（重量）的醋酸乙烯酯基共聚物的皂化产物（B）和 5-60%（重量）的改性剂（R）组成，并在至少一个表面上形成图像接收层、 本发明第V 涉及一种用于喷墨记录片材的树脂组合物，它包括配制 70-100% （重量）的阳离子（甲基）丙烯酸聚合物 (A)，其中共聚有一个具有聚氧化亚烷基的阳离子（甲基）丙烯酸酯单体、一个具有亲水基团的单体、具有可交联基团的单体、含有阳离子基团的单体和阳离子单体，0-30%（重量）的醋酸乙烯酯基共聚物的皂化产物（B）（其总重量为 100%（重量）），以及 0-15 份（重量）的改性剂（R）（以 100 份（重量）的（A）和（B）为基准）、 本发明之六涉及一种喷墨记录片材，其包括由含有可水解硅烷基的(甲基)丙烯酸基共聚物的组合物构成，在该组合物中，具有可水解硅烷基的可聚合不饱和单体与含有(甲基)丙烯酸基可聚合不饱和单体的单体共聚，以及无机化合物细颗粒、 本发明第 VII 号涉及一种用于喷墨记录片材的树脂组合物，其特征在于含有 100 份(重量)的树脂组合物，其组成为(1)1-30%(重量)的纤维素衍生物(A)和(2)70-99%(重量)的纤维素衍生物的良好溶剂(B)(总计为 100%(重量))，(3)0.1-20份(重量)能溶解在纤维素衍生物的良好溶剂(B)或弱溶剂(D)中的有机酸(C)，以及任选地，(4)0-150份(重量)纤维素衍生物的弱溶剂(D)，并涉及一种在由树脂组合物构成的待记录体上形成图像接收层的记录片材。 本发明的第VIII 是要提供一种热转印片材，它在模压成热转印片材的情况下具有优异的吸墨能力、固墨能力和印刷能力，并具有较高的耐水性、耐久性，特别是记录图像的抗微裂纹能力，而且其中的受墨层是在弹性材料上形成的、以及用于构建这种材料的树脂组合物、含有指定式（1）所示单体单元的聚合物（A）和热熔粘合剂树脂（B）的树脂组合物、由该树脂组合物构成的热转印片材及其制备方法。
• COATING COMPOSITION FOR INK-JET RECORDING MEDIUM AND INK-JET RECORDING MEDIUM
  申请人：Clariant International Ltd.

  公开号：EP1470928A1

  公开（公告）日：2004-10-27

  The present invention relates to a coating composition for an ink jet recording medium comprising a synthetic resin emulsion having a particle diameter of 100 nm or less and colloidal silica, said synthetic resin emulsion being obtained by, in the presence of (A) an emulsifier containing a radical-polymerizable emulsifier having a sulfonic acid group, emulsion-polymerizing (B) an unsaturated monomer having a silyl group and (C) an unsaturated monomer having a six-membered ring as a side chain and, optionally, (D) another radical-polymerizable unsaturated monomer which is copolymerizable with (B) and (C).

  本发明涉及一种用于喷墨记录介质的涂料组合物，该组合物包含粒径为 100 nm 或更小的合成树脂乳液和胶体二氧化硅，所述合成树脂乳液是通过以下方法获得的：(A) 含有磺酸基团的可自由基聚合乳化剂的乳化剂、乳液聚合(B) 具有硅基的不饱和单体和(C) 具有六元环作为侧链的不饱和单体，以及(D) 可与(B)和(C)共聚的另一种可自由基聚合的不饱和单体。
• Coating composition for ink-jet recording medium and ink-jet recording medium
  申请人：Murase Naokazu

  公开号：US20050124747A1

  公开（公告）日：2005-06-09

  The present invention relates to a coating composition for an ink jet recording medium comprising a synthetic resin emulsion having a particle diameter of 100 nm or less and colloidal silica, said synthetic resin emulsion being obtained by, in the presence of (A) an emulsifier containing a radical-polymerizable emulsifier having a sulfonic acid group, emulsion-polymerizing (B) an unsaturated monomer having a silyl group and (C) an unsaturated monomer having a six-membered ring as a side chain and, optionally, (D) another radical-polymerizable unsaturated monomer which is copolymerizable with (B) and (C).

  本发明涉及一种用于喷墨记录介质的涂料组合物，该组合物包含粒径为 100 nm 或更小的合成树脂乳液和胶体二氧化硅，所述合成树脂乳液是通过以下方法获得的：(A) 含有磺酸基团的可自由基聚合乳化剂的乳化剂、乳液聚合(B) 具有硅基的不饱和单体和(C) 具有六元环作为侧链的不饱和单体，以及(D) 可与(B)和(C)共聚的另一种可自由基聚合的不饱和单体。
• Reaction of 1,1,1-trichloroethane or carbon tetrachloride with allyl chloride, initiated by the Fe(CO)5-isopropanol system
  作者：A. A. Kamyshova、E. Ts. Chukovskaya、R. Kh. Freidlina

  DOI：10.1007/bf00929383

  日期：1973.9