5,6-dichloronorbornene | 59975-41-6

• 分子结构分类: 有机化合物 - 有机卤素化合物 - 有机氯化物
• 英文名称: 5,6-dichloronorbornene
• 英文别名: 5,6-dichloro-norborn-2-ene；5,6-Dichlor-norborn-2-en；endo-5,endo-6-Dichlorobicyclo<2.2.1>hept-2-en；trans-5,6-Dichlorobicyclo<2.2.1>hept-2-en；5,6-Dichlor-bicyclo<2.2.1>hepten-(2)；2,3-Dichlor-bicyclo<2.2.1>hept-5-en；5,6-dichlorobicyclo[2.2.1]hept-2-ene
• CAS: 59975-41-6
• 化学式: C₇H₈Cl₂
• 分子量: 163.047
• InChiKey: ZFSMTYOLNXPHEU-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.4
• 重原子数：
  9
• 可旋转键数：
  0
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.71
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  5,6-dichloronorbornene 在 氢氧化钾 作用下， 以 乙二醇 为溶剂， 以36%的产率得到2-chloronorbornadiene
  参考文献：
  名称：

  Adam, Waldemar; Lucchi, Ottorino de; Pasquato, Lucia, Chemische Berichte, 1987, vol. 120, p. 531 - 536

  摘要：

  DOI：
• 作为产物：
  描述：

  1,2-二氯乙烯 、 环戊二烯 以to produce 5,6-dichloronorbornene (called "DCN" hereinafter)的产率得到5,6-dichloronorbornene
  参考文献：
  名称：

  Metathesis polymerization cross-linked halogen-containing copolymer

  摘要：

  一种交联共聚物，其中含有从二环戊二烯和可通过交换反应聚合的含卤环烷衍生的重复单元，以及制备该共聚物的方法、制备由该共聚物制成的成型品的方法和用于该成型品的可聚合组成物。

  公开号：

  US04994535A1

文献信息

• THERMOPLASTIC RESIN COMPOSITION, OPTICAL FILM AND RETARDATION FILM
  申请人：Okaniwa Motoki

  公开号：US20090209705A1

  公开（公告）日：2009-08-20

  Each of the thermoplastic resin composition and the optical film of the present invention comprises a cycloolefin-based polymer (A) and a vinyl-based polymer (B) having a structural unit derived from p-isopropenylphenol. The thermoplastic resin composition and the optical film exhibit excellent compatibility of their components with keeping property of low birefringence inherent in the thermoplastic resin composition comprising the cycloolefln-based polymer and the vinyl-based polymer, and they are excellent in weathering resistance and heat resistance.

  本发明的热塑性树脂组合物和光学膜均包含环氧烷基聚合物（A）和含有源自对异丙基苯酚的结构单元的乙烯基聚合物（B）。热塑性树脂组合物和光学膜展现出其组分的优异相容性，同时保持了环氧烷基聚合物和乙烯基聚合物组成的热塑性树脂组合物固有的低双折射率特性，且它们具有优异的耐候性和耐热性。
• Metathesis polymerized cross-linked halogen-containing copolymer
  申请人：HERCULES INCORPORATED

  公开号：EP0283719A2

  公开（公告）日：1988-09-28

  A cross-linked copolymer containing repeating units derived from dicyclopentadiene and metathesis polymerizable halogen-containing cycloalkenes, a process for producing the copolymer, a process for producing a molded article from the copolymer and a polymerizable composition therefor.

  一种交联共聚物，其含有由双环戊二烯和可偏聚的含卤环烯衍生的重复单元；一种生产该共聚物的工艺；一种用该共聚物和可聚合组合物生产模塑制品的工艺。
• Process for producing cycloolefin random copolymers
  申请人：MITSUI PETROCHEMICAL INDUSTRIES, LTD.

  公开号：EP0358516A2

  公开（公告）日：1990-03-14

  A process for the production of a cycloolefin random copolymer comprises flash drying a solution in a hydrocarbon of a cycloolefin random copolymer obtained by copolymerization of ethylene and a specific cycloolefin in said hydrocarbon in the presence of a catalyst and a process for the production of a cycloolefin random copolymer which comprises copolymerizing ethylene with a specific cycloolefin in a hydrocarbon in the presence of a catalyst in a polymerization reactor in the substantial absence of a gas phase.

  一种生产环烯烃无规共聚物的工艺，包括闪蒸干燥乙烯与特定环烯烃在催化剂存在下在烃中共聚得到的环烯烃无规共聚物的烃溶液，以及一种生产环烯烃无规共聚物的工艺，该工艺包括乙烯与特定环烯烃在催化剂存在下在聚合反应器中基本上无气相的烃中共聚。
• Process for producing flame-retarded polymer molded articles
  申请人：HERCULES INCORPORATED

  公开号：EP0374903A2

  公开（公告）日：1990-06-27

  A process for producing a flame-retarded polymer molded article wherein a crosslinked polymer molded article is produced by the simultaneous polymerization and molding of at least one kind of metathesis polymerizable cycloolefins in the presence of a metathesis polymerization catalyst, and said molded article; i) is contacted with a halogen molecule, ii) is contacted with a hydrogen halide, iii) is contacted with a halogenation agent or a hydrohalogenation agent which has a similar reactivity as halogen or halogen halide, or iv) is contacted with a halogenated hydrocarbon acting as a strong radical chain transfer agent and said molded article is treated with said halogenated hydrocarbon under the condition to enable the reaction of the halogenated hydrocarbon with the unsaturated bond in the crosslinked polymer by the radical chain transfer reaction.

  一种生产阻燃聚合物模塑制品的工艺，其中至少一种可偏析聚合的环烯烃在偏析聚合催化剂存在下通过同时聚合和模塑生产交联聚合物模塑制品，以及所述模塑制品； i) 与卤素分子接触、 ii) 与卤化氢接触 与卤素或卤化氢反应活性相似的卤化剂或氢卤化剂接触，或 iv) 与作为强自由基链转移剂的卤代烃接触，并在能使卤代烃通过自由基链转移反应与交联聚合物中的不饱和键发生反应的条件下，用所述卤代烃处理所述模制件。
• Thermoplastic resin composition
  申请人：JAPAN SYNTHETIC RUBBER CO., LTD.

  公开号：EP0409291A2

  公开（公告）日：1991-01-23

  A thermoplastic resin composition consisting essentially of (A) 5 to 99% by weight of a hydrogenated polymer which is a hydrogenation product of a polymer represented by general formula (I): or a mixture of the norbornene derivative and a monomer copolymerizable therewith to ring-opening polymerization and (B) 95 to 1% by weight of at least one member selected from the group consisting of (B-1) a rubbery polymer and (B-2) a thermoplastic resin. The thermoplastic resin composition has excellent impact resistance and ductility.

  一种热塑性树脂组合物，其主要成分为：(A) 5-99%（按重量计）的氢化聚合物，它是通式(I)所代表的聚合物的氢化产物： 或降冰片烯衍生物与可与之开环聚合的单体的混合物，以及 (B) 95-1%（按重量计）的至少一种选自(B-1)橡胶聚合物和(B-2)热塑性树脂的成员。热塑性树脂组合物具有优异的抗冲击性和延展性。