N¹,N¹,N³,N³-tetraethyl-2-phenylnaphthalene-1,3-diamine | 1403688-82-3

• 分子结构分类: 有机化合物 - 苯类化合物 - 萘
• 英文名称: N¹,N¹,N³,N³-tetraethyl-2-phenylnaphthalene-1,3-diamine
• 英文别名: 1-N,1-N,3-N,3-N-tetraethyl-2-phenylnaphthalene-1,3-diamine
• CAS: 1403688-82-3
• 化学式: C₂₄H₃₀N₂
• 分子量: 346.516
• InChiKey: MRGFJWOTSLHTFZ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6.5
• 重原子数：
  26
• 可旋转键数：
  7
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.33
• 拓扑面积：
  6.5
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  (碘乙炔基)苯 、 二乙胺 在 copper(II) tetrafluroborate hexahydrate 作用下， 反应 6.0h， 以62%的产率得到N¹,N¹,N³,N³-tetraethyl-2-phenylnaphthalene-1,3-diamine
  参考文献：
  名称：

  Cu(II)-Catalyzed Synthesis of Naphthalene-1,3-diamine Derivatives from Haloalkynes and Amines

  摘要：

  An efficient procedure for the preparation of naphthalene-1,3-diamine derivatives by copper-catalyzed haloalkynes with amines has been reported. The reaction was supposed to proceed through a coupling reaction followed by the dimerization of ynamines.

  DOI：

  10.1021/ol302486h

文献信息

• Cu(II)-Catalyzed Synthesis of Naphthalene-1,3-diamine Derivatives from Haloalkynes and Amines
  作者：Zhengwang Chen、Wei Zeng、Huanfeng Jiang、Liangxian Liu

  DOI：10.1021/ol302486h

  日期：2012.11.2

  An efficient procedure for the preparation of naphthalene-1,3-diamine derivatives by copper-catalyzed haloalkynes with amines has been reported. The reaction was supposed to proceed through a coupling reaction followed by the dimerization of ynamines.