vinyltriallylsilane | 17988-47-5

• 分子结构分类: 有机化合物 - 有机金属化合物 - 有机类金属化合物
• 英文名称: vinyltriallylsilane
• 英文别名: triallyl-vinyl-silane；Triallyl-vinyl-silan；Triallylvinylsilane；ethenyl-tris(prop-2-enyl)silane
• CAS: 17988-47-5
• 化学式: C₁₁H₁₈Si
• 分子量: 178.349
• InChiKey: OYQOGVCXOXDUNO-UHFFFAOYSA-N

物化性质

• 沸点：
  32-33.5 °C(Press: 3 Torr)
• 密度：
  0.788±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  3.72
• 重原子数：
  12
• 可旋转键数：
  7
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.27
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  vinyltriallylsilane 在 三氯化铝 作用下， 反应 3.0h， 以8%的产率得到氯三烯丙基硅烷
  参考文献：
  名称：

  Reactions of organochlorosilanes with chloro-and organogermanes in the presence of aluminum chloride

  摘要：

  The effect of substituents at the silicon and germanium atoms in reactions of organochlorosilanes with chloro- and organogermanes in the presence Of aluminum chloride was studied. The only occurring process is the exchange of the chlorine atoms at Ge for the phenyl groups from Si; an increase in the number of methyl groups or chlorine atoms at Si promotes formation of phenyltrichlorogermane, and an increase in the number of phenyl groups or replacement of the chlorine atom at the Si atom by hydrogen leads to the formation of di- and triphenylchlorogrmanes. Neither phenyl nor other radicals are transferred back from Ge to Si in the course of reactions of phenylgermanes with methylchlorosilanes in the presence of aluminum chloride; the only occurring processes are the exchange of the phenyl or methyl radicals bonded to Ge for the Cl atom bonded to Al and the disproportionation of phenylchlorogermanes.

  DOI：

  10.1134/s1070363206100100
• 作为产物：
  描述：

  乙烯基三氯硅烷 、 氯丙烯镁 在 3-氯丙烯 作用下， 以 四氢呋喃 为溶剂， 反应 3.0h， 以68.2%的产率得到vinyltriallylsilane
  参考文献：
  名称：

  Zhun', V.I.; Tsvetkov, A. L.; Sheludyakov, V. D., Journal of general chemistry of the USSR, 1988, vol. 58, # 7, p. 1425 - 1431

  摘要：

  DOI：

文献信息

• Gmelin Handbuch der Anorganischen Chemie, Gmelin Handbook: Si: MVol.C, 16, page 48 - 53
  作者：

  DOI：——

  日期：——
• Studies in Silico-Organic Compounds. XXI. Alkyl and Phenyl Derivatives of vinyltrichlorosilane
  作者：Roger Nagel、Howard W. Post

  DOI：10.1021/jo50010a016

  日期：1952.10
• ZHUN, V. I.;TSVETKOV, A. L.;SHELUDYAKOV, V. D.;LAVYGIN, I. A.;LEJTAN, O. +, ZH. OBSHCH. XIMII, 58,(1988) N 7, 1599-1606
  作者：ZHUN, V. I.、TSVETKOV, A. L.、SHELUDYAKOV, V. D.、LAVYGIN, I. A.、LEJTAN, O. +

  DOI：——

  日期：——
• Zhun', V.I.; Tsvetkov, A. L.; Sheludyakov, V. D., Journal of general chemistry of the USSR, 1988, vol. 58, # 7, p. 1425 - 1431
  作者：Zhun', V.I.、Tsvetkov, A. L.、Sheludyakov, V. D.、Lavygin, I. A.、Leitan, O. V.、et al.

  DOI：——

  日期：——
• Reactions of organochlorosilanes with chloro-and organogermanes in the presence of aluminum chloride
  作者：V. I. Zhun’、I. V. Sbitneva、A. N. Polivanov、E. A. Chernyshev

  DOI：10.1134/s1070363206100100

  日期：2006.10

  The effect of substituents at the silicon and germanium atoms in reactions of organochlorosilanes with chloro- and organogermanes in the presence Of aluminum chloride was studied. The only occurring process is the exchange of the chlorine atoms at Ge for the phenyl groups from Si; an increase in the number of methyl groups or chlorine atoms at Si promotes formation of phenyltrichlorogermane, and an increase in the number of phenyl groups or replacement of the chlorine atom at the Si atom by hydrogen leads to the formation of di- and triphenylchlorogrmanes. Neither phenyl nor other radicals are transferred back from Ge to Si in the course of reactions of phenylgermanes with methylchlorosilanes in the presence of aluminum chloride; the only occurring processes are the exchange of the phenyl or methyl radicals bonded to Ge for the Cl atom bonded to Al and the disproportionation of phenylchlorogermanes.