bis(methoxyethoxyethyl) peroxydicarbonate | 40835-42-5

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 有机碳酸及其衍生物
• 英文名称: bis(methoxyethoxyethyl) peroxydicarbonate
• 英文别名: 2-(2-Methoxyethoxy)ethoxycarbonyloxy 2-(2-methoxyethoxy)ethyl carbonate
• CAS: 40835-42-5
• 化学式: C₁₂H₂₂O₁₀
• 分子量: 326.301
• InChiKey: WVWKYLXLHCQSQR-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  0.4
• 重原子数：
  22
• 可旋转键数：
  17
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.83
• 拓扑面积：
  108
• 氢给体数：
  0
• 氢受体数：
  10

反应信息

• 作为反应物：
  描述：

  bis(methoxyethoxyethyl) peroxydicarbonate 以 苯 为溶剂， 生成 二乙二醇单甲醚 、 二乙二醇二甲醚 、 二氧化碳 、 羟乙醛 、
  参考文献：
  名称：

  Fomin, V. A.; Etlis, V. S.; Nozrina, F. D., Journal of Organic Chemistry USSR (English Translation), 1982, vol. 18, p. 26 - 31

  摘要：

  DOI：
• 作为产物：
  描述：

  二乙二醇单甲醚 在 sodium peroxide 、 水 作用下， 以 乙醚 为溶剂， 反应 3.5h， 生成 bis(methoxyethoxyethyl) peroxydicarbonate
  参考文献：
  名称：

  Fomin, V. A.; Etlis, V. S.; Nozrina, F. D., Journal of Organic Chemistry USSR (English Translation), 1982, vol. 18, p. 26 - 31

  摘要：

  DOI：

文献信息

• Highly concentrated, stable, and safe diacyl peroxide and peroxydicarbonate emulsions with a low chemical oxygen demand value
  申请人：De Jong Theodorus Johannes Jacobus

  公开号：US20050171275A1

  公开（公告）日：2005-08-04

  The invention relates to highly concentrated aqueous emulsions of peroxides comprising an anti-freeze agent, a polyvinyl acetate with a degree of hydrolysis between 45 and 80%, and optionally a non-ionic surfactant with an HLB value greater than 10 selected from alkylene oxide block-copolymers, ethoxylated fatty alcohols, and ethoxyfated fatty acids. The emulsions have a low COD value and are safe, storage stable, and generally applicable.

  本发明涉及高浓度过氧化物水乳剂，包含一种防冻剂、一种水解度在 45% 至 80% 之间的聚醋酸乙烯酯，以及一种 HLB 值大于 10 的非离子表面活性剂，该表面活性剂可选自环氧亚 烷嵌段共聚物、乙氧基化脂肪醇和乙氧基化脂肪酸。这种乳剂的 COD 值低，安全、储存稳定且普遍适用。
• FOMIN, V. A.;EHTLIS, V. S.;NOZRINA, F. D., ZH. ORGAN. XIMII, 1982, 18, N 1, 32-38
  作者：FOMIN, V. A.、EHTLIS, V. S.、NOZRINA, F. D.

  DOI：——

  日期：——
• HIGHLY CONCENTRATED, STABLE, AND SAFE DIACYL PEROXIDE AND PEROXYDICARBONATE EMULSIONS WITH A LOW CHEMICAL OXYGEN DEMAND VALUE
  申请人：Akzo Nobel N.V.

  公开号：EP1501875A1

  公开（公告）日：2005-02-02
• COMPOSITION COMPRENANT AU MOINS UN PEROXYDE ORGANIQUE, AU MOINS UN ÉMULSIFIANT, ET DE L'EAU OXYGÉNÉE
  申请人：ARKEMA FRANCE

  公开号：EP4103548A1

  公开（公告）日：2022-12-21
• AQUEOUS EMULSION COMPOSITION OF ORGANIC PEROXIDE
  申请人：ARKEMA FRANCE

  公开号：US20150218293A1

  公开（公告）日：2015-08-06

  An aqueous emulsion composition of organic peroxide, including from 10 to 65% by weight of one or a plurality of organic peroxides, from 2 to 25% by weight of at least one antifreeze agent, from 0.01 to 10% by weight of at least one emulsifying agent, optionally at least one additive, water, of which the quantity is defined in order to form the remainder of the total composition (100%), wherein the emulsifying agent is a colloid agent of a polyvinyl acetate having a degree of hydrolysis greater than 80% and a viscosity, measured in solution in water at 4% by weight at 20° C., less than or equal to 5 mPa·s, said viscosity being measured with a Brookfield RVT viscometer, needle no. 3, 20 rpm, in accordance with the ISO 2555 standard. Also, to the method of preparing same and the use thereof.