1,2-bis(4'-methylbiphenyl-4-yl)ethane | 43012-23-3

• 分子结构分类: 有机化合物 - 苯丙烷和聚酮 - 二苯乙烯类
• 英文名称: 1,2-bis(4'-methylbiphenyl-4-yl)ethane
• 英文别名: 1.2-Bis(4'-methyl-4-biphenyl)-aethan；4,4'-di-p-tolyl-bibenzyl；1-Methyl-4-[4-[2-[4-(4-methylphenyl)phenyl]ethyl]phenyl]benzene；1-methyl-4-[4-[2-[4-(4-methylphenyl)phenyl]ethyl]phenyl]benzene
• CAS: 43012-23-3
• 化学式: C₂₈H₂₆
• 分子量: 362.514
• InChiKey: YDOVDUCHCMWAJC-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  8.1
• 重原子数：
  28
• 可旋转键数：
  5
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.14
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为产物：
  描述：

  C₂₈H₂₄S₂ 生成 1,2-bis(4'-methylbiphenyl-4-yl)ethane
  参考文献：
  名称：

  Staab,H.A.; Haenel,M., Chemische Berichte, 1973, vol. 106, p. 2190 - 2202

  摘要：

  DOI：

文献信息

• Szperl, IX. Congr. int. Quim. Madrid 1934 Bd. 4 S. 233, 236
  作者：Szperl

  DOI：——

  日期：——
• Straightforward synthesis of substituted dibenzyl derivatives
  作者：Clève D. Mboyi、Sylvain Gaillard、Mbaye D. Mabaye、Nicolas Pannetier、Jean-Luc Renaud

  DOI：10.1016/j.tet.2013.04.073

  日期：2013.6

  The C-C bond formation by homogeneous catalysis is a powerful tool in organic synthesis. The replacement of noble metal by cheaper one for already reported methodologies is of interest for an economical purpose. The attractivity of such replacement is also enhanced if a first raw transition metal is found to be active in several processes.This work demonstrates that a common nickel complex can be used for a two-step cross-coupling procedure, namely a homocoupling reaction of benzyl derivatives and a subsequent Suzuki reaction. These consecutive reactions permit the synthesis of new polyfunctionalized dibenzyl compounds. (C) 2013 Elsevier Ltd. All rights reserved.
• Staab,H.A.; Haenel,M., Chemische Berichte, 1973, vol. 106, p. 2190 - 2202
  作者：Staab,H.A.、Haenel,M.

  DOI：——

  日期：——