cis-1,2,3-triphenylaziridine | 968-02-5

• 分子结构分类: 有机化合物 - 苯丙烷和聚酮 - 二苯乙烯类
• 英文名称: cis-1,2,3-triphenylaziridine
• 英文别名: cis-(PhCH)2NPh；1,2,3-Triphenylaziridine
• CAS: 968-02-5
• 化学式: C₂₀H₁₇N
• 分子量: 271.362
• InChiKey: BHAJUXABDQWRKH-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.9
• 重原子数：
  21
• 可旋转键数：
  3
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.1
• 拓扑面积：
  3
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  cis-1,2,3-triphenylaziridine 在 三(五氟苯基)硼烷 、 二异丙胺 作用下， 反应 24.0h， 以27%的产率得到N,N-二苄基苯胺
  参考文献：
  名称：

  B（C 6 F 5）3的无金属转移加氢催化

  摘要：

  B（C 6 F 5）3对胺的活化显示出可催化手性胺的消旋化。使用i Pr 2 NH作为氢源和催化量的路易斯酸B（C 6 F 5）3，证明了将该策略扩展为双分子过程，亚胺，烯胺和N-杂环的催化转移氢化。

  DOI：

  10.1021/om2005832
• 作为产物：
  描述：

  N-(α'-chloro-bibenzyl-α-yl)-aniline 在 氢氧化钾 作用下， 生成 cis-1,2,3-triphenylaziridine
  参考文献：
  名称：

  38.“氮化物”的结构。

  摘要：

  DOI：

  10.1039/jr9380000206

文献信息

• Methods of using heterocycle-amine ligands, compositions, complexes, and catalysts
  申请人：Diamond M. Gary

  公开号：US20060094839A1

  公开（公告）日：2006-05-04

  Ligands, compositions, and metal-ligand complexes that incorporate heterocycle-amine compounds are disclosed that are useful in the catalysis of transformations such as the polymerization of monomers into polymers. The catalysts have high performance characteristics, including higher comonomer incorporation into ethylene/olefin copolymers, where such olefins are for example, 1-octene, propylene or styrene. The catalysts also polymerize propylene to form isotactic polypropylene.

  揭示了包含杂环胺化合物的配体、组合物和金属配体络合物，这些化合物在催化转化中非常有用，例如将单体聚合成聚合物。这些催化剂具有高性能特征，包括将共聚单体更多地并入乙烯/烯烃共聚物中，其中这些烯烃例如为1-辛烯、丙烯或苯乙烯。这些催化剂还可以聚合丙烯形成同向聚丙烯。
• Catalytic carbonylation of three and four membered heterocycles
  申请人：——

  公开号：US20030162961A1

  公开（公告）日：2003-08-28

  Epoxides, aziridines, thiiranes, oxetanes, lactones, lactams and analogous compounds are reacted with carbon monoxide in the presence of a catalytically effective amount of catalyst having the general formula [Lewis acid] z+ {[QM(CO) x ] w− } y where Q is any ligand and need not be present, M is a transition metal selected from the group consisting of Groups 4, 5, 6, 7, 8, 9 and 10 of the periodic table of elements, z is the valence of the Lewis acid and ranges from 1 to 6, w is the charge of the metal carbonyl and ranges from 1 to 4 and y is a number such that w times y equals z, and x is a number such as to provide a stable anionic metal carbonyl for {[QM(CO) x ] w− } y and ranges from 1 to 9 and typically from 1 to 4.

  环氧化物、氮杂环丙烷、硫杂环丙烷、氧杂环丁烷、内酯、内酰胺和类似化合物在存在具有一定催化活性的催化剂的情况下与一般公式为[路易斯酸] z+ {[QM(CO) x ] w− } y的催化剂反应，其中Q是任何配体且不一定存在，M是从元素周期表的4、5、6、7、8、9和10族中选择的过渡金属，z是路易斯酸的化合价，范围从1到6，w是金属羰基的电荷，范围从1到4，y是一个数字，使得w乘以y等于z，x是一个数字，以提供稳定的阴离子金属羰基{[QM(CO) x ] w− } y，范围从1到9，通常从1到4。
• Formation of epoxides and N-arylaziridines via a simple Mg-Barbier reaction in DMF
  作者：Sylvain Oudeyer、Eric Léonel、Jean Paul Paugam、Jean-Yves Nédélec

  DOI：10.1016/j.tet.2013.12.016

  日期：2014.1

  The Mg-activation of benzal bromide 2b in DMF in the presence of carbonyl compounds 1 or imines 4 leads to epoxides 3 and N-arylaziridines 5, respectively, with acceptable isolated yields. It was found that DMF is likely involved in this process to form a nucleophilic intermediate by reaction with a first generated electrophilic carbene. Results obtained in this chemical approach are compared to those

  在羰基化合物1或亚胺4的存在下，在DMF中苯甲酰溴2b的Mg活化分别产生环氧化物3和N-芳基氮丙啶5，并具有可接受的分离产率。已经发现，DMF可能参与该过程以通过与首先产生的亲电卡宾反应而形成亲核中间体。将该化学方法获得的结果与也在DMF中使用电化学活化获得的结果进行比较。
• HYDROGEN SPLITTING COMPOSITION
  申请人：Stephan Douglas W.

  公开号：US20100048949A1

  公开（公告）日：2010-02-25

  A compound having the formula (I) where each of R 1 , R 2 , R 3 and R 4 is independently C 6 -C 18 aryl-, C 5 -C 8 cycloalkyl-, C 6 -C 18 aryl having at least one C 1 -C 20 alkyl substituent, C 5 -C 8 cycloalkyl having at least one C 1 -C 20 alkyl substituent, C 4 -C 20 branched alkyl-, C 16 -C 20 linear alkyl-, RO—, —NRR′, —PRR′, —SR, fluoro substituted forms thereof, and perfluoro forms thereof: and R 5 is C 6 -C 18 aryl-, C 5 -C 8 cycloalkyl-, C 6 -C 18 aryl having at least one C 1 -C 20 alkyl substituent, C 5 -C 8 cycloalkyl having at least one C 1 -C 20 alkyl substituent, C 3 -C 20 branched alkyl-, C 2 -C 30 linear alkyl-, fluoro substituted forms thereof, and perfluoro forms thereof; where R and R′ are each independently C 6 -C 18 aryl-, C 5 -C 8 cycloalkyl-, C 6 -C 18 aryl having at least one C 1 -C 20 alkyl substituent, C 5 -C 8 cycloalkyl having at least one C 1 -C 20 alkyl substituent, C 4 -C 20 branched alkyl-, C 2 -C 30 linear alkyl-, fluoro substituted forms thereof, and perfluoro forms thereof; A is N, P, S, or O with the proviso that when A is S, R 2 is a nullify; and M is B, Al, Ga or In.

  化合物的化学式为（I），其中R1，R2，R3和R4各自独立地为C6-C18芳基，C5-C8环烷基，具有至少一个C1-C20烷基取代基的C6-C18芳基，具有至少一个C1-C20烷基取代基的C5-C8环烷基，C4-C20支链烷基，C16-C20线性烷基，RO—，—NRR′，—PRR′，—SR，其氟代取代物和全氟代取代物：而R5为C6-C18芳基，C5-C8环烷基，具有至少一个C1-C20烷基取代基的C6-C18芳基，具有至少一个C1-C20烷基取代基的C5-C8环烷基，C3-C20支链烷基，C2-C30线性烷基，其氟代取代物和全氟代取代物；其中R和R′各自独立地为C6-C18芳基，C5-C8环烷基，具有至少一个C1-C20烷基取代基的C6-C18芳基，具有至少一个C1-C20烷基取代基的C5-C8环烷基，C4-C20支链烷基，C2-C30线性烷基，其氟代取代物和全氟代取代物；A为N，P，S或O，但当A为S时，R2为零；而M为B，Al，Ga或In。
• Frustrated Lewis Pair Compositions
  申请人：Stephan Douglas W.

  公开号：US20130018207A1

  公开（公告）日：2013-01-17

  A compound having the formula (I) where each of R 1 , R 2 , R 3 and R 4 is independently C 6 -C 18 aryl-, C 5 -C 8 cycloalkyl-, C 6 -C 18 aryl having at least one C 1 -C 20 alkyl substituent, C 5 -C 8 cycloalkyl having at least one C 1 -C 20 alkyl sυbstituent, C 4 -C 20 branched alkyl-, C 16 -C 20 linear alkyl-, RO—, —NRR′, —PRR′, —SR, fluoro substituted forms thereof, and perfluoro forms thereof: and R 5 is C 6 -C 18 aryl-, C 5 -C 8 cycloalkyl-, C 6 -C 18 aryl having at least one C 1 -C 20 alkyl substituent, C 5 -C 8 cycloalkyl having at least one C 1 -C 20 alkyl substituent, C 3 -C 20 branched alkyl-, C 2 -C 30 linear alkyl-, fluoro substituted forms thereof, and perfluoro forms thereof; where R and R′ are each independently C 6 -C 18 aryl-, C 5 -C 8 cycloalkyl-, C 6 -C 18 aryl having at least one C 1 -C 20 alkyl substituent, C 5 -C 8 cycloalkyl having at least one C 1 -C 20 alkyl substituent, C 4 -C 20 branched alkyl-, C 2 -C 30 linear alkyl-, fluoro substituted forms thereof, and perfluoro forms thereof; A is N, P, S, or O with the proviso that when A is S, R 2 is a nullity; and M is B, Al, Ga or In.

  化合物的化学式为（I），其中R1、R2、R3和R4各自独立地为C6-C18芳基、C5-C8环烷基、至少有一个C1-C20烷基取代基的C6-C18芳基、至少有一个C1-C20烷基取代基的C5-C8环烷基、C4-C20支链烷基、C16-C20直链烷基、RO-、-NRR'、-PRR'、-SR、其氟代取代物和全氟代取代物；R5为C6-C18芳基、C5-C8环烷基、至少有一个C1-C20烷基取代基的C6-C18芳基、至少有一个C1-C20烷基取代基的C5-C8环烷基、C3-C20支链烷基、C2-C30直链烷基、其氟代取代物和全氟代取代物；其中R和R'各自独立地为C6-C18芳基、C5-C8环烷基、至少有一个C1-C20烷基取代基的C6-C18芳基、至少有一个C1-C20烷基取代基的C5-C8环烷基、C4-C20支链烷基、C2-C30直链烷基、其氟代取代物和全氟代取代物；A为N、P、S或O，但当A为S时，R2为零；M为B、Al、Ga或In。