2-(dimethylamino)methylselenophene | 91912-38-8

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: 2-(dimethylamino)methylselenophene
• 英文别名: dimethyl-selenophen-2-ylmethyl-amine；Dimethyl-selenophen-2-ylmethyl-amin；2-Dimethylaminomethyl-selenophen；N,N-dimethyl-1-selenophen-2-ylmethanamine
• CAS: 91912-38-8
• 化学式: C₇H₁₁NSe
• 分子量: 188.131
• InChiKey: USUJYZIWZSVDJR-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  0.81
• 重原子数：
  9
• 可旋转键数：
  2
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.43
• 拓扑面积：
  3.2
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  sodium hexafluoroantimonate 、 丁二炔 、 2-(dimethylamino)methylselenophene 、 cis-[RuCl₂(dppm)2] 以 not given 为溶剂， 生成 [Cl(dppm)2Ru((dimethylamino)(2-methylene-2,3-dihydroselenophen-3-yl-methyl)allenylidene)]SbF6
  参考文献：
  名称：

  Five-Membered 2-Methylene-2,3-dihydro Heterocycles from Ruthenium Butatrienylidene Intermediates and 2-(Dimethylamino)methyl-Substituted Furans, Thiophenes, and Selenophenes

  摘要：

  Trapping of the primary butatrienylidene intermediate trans-[Cl(dppm)(2)Ru=C=C=C=CH2](+) with five-membered 2-(dimethylamino)methyl-substituted heterocycles provides an easy and efficient route to aminoallenylidene complexes with appended 2-methylene-2,3-dihydrofuran, -thiophene, or -selenophene moieties. Upon warming or acid catalysis isomerization to the aromatic 2-methylated isomers is observed.

  DOI：

  10.1021/om030317i
• 作为产物：
  描述：

  硒酚 、 盐酸二甲胺 在 聚合甲醛 、 乙醇 作用下， 生成 2-(dimethylamino)methylselenophene
  参考文献：
  名称：

  Jur'ew et al., Zhurnal Obshchei Khimii, 1959, vol. 29, p. 3647,3651; engl. Ausg. S. 3606, 3609

  摘要：

  DOI：

文献信息

• Five-Membered 2-Methylene-2,3-dihydro Heterocycles from Ruthenium Butatrienylidene Intermediates and 2-(Dimethylamino)methyl-Substituted Furans, Thiophenes, and Selenophenes
  作者：Ralf-Christoph Harbort、Stephan Hartmann、Rainer F. Winter、Karl Wilhelm Klinkhammer

  DOI：10.1021/om030317i

  日期：2003.8.1

  Trapping of the primary butatrienylidene intermediate trans-[Cl(dppm)(2)Ru=C=C=C=CH2](+) with five-membered 2-(dimethylamino)methyl-substituted heterocycles provides an easy and efficient route to aminoallenylidene complexes with appended 2-methylene-2,3-dihydrofuran, -thiophene, or -selenophene moieties. Upon warming or acid catalysis isomerization to the aromatic 2-methylated isomers is observed.
• Jur'ew et al., Zhurnal Obshchei Khimii, 1959, vol. 29, p. 3647,3651; engl. Ausg. S. 3606, 3609
  作者：Jur'ew et al.

  DOI：——

  日期：——