1,3-Bis-triethylammonium-propan | 75317-22-5

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: 1,3-Bis-triethylammonium-propan
• 英文别名: Triethyl-[3-(triethylazaniumyl)propyl]azanium
• CAS: 75317-22-5
• 化学式: C₁₅H₃₆N₂
• 分子量: 244.464
• InChiKey: SERGJFNYUXIJMP-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.9
• 重原子数：
  17
• 可旋转键数：
  10
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

文献信息

• IONIC LIQUID CONTAINING ALLYLSULFONATE ANION
  申请人：Watahiki Tsutomu

  公开号：US20120157680A1

  公开（公告）日：2012-06-21

  PROBLEM: Providing a novel ionic liquid, which is low-cost, environment-friendly, and has low viscosity and melting point. MEANS FOR SOLVING THE PROBLEM: The present invention is the invention of the ionic liquid represented by the general formula [1]: wherein, R 1 to R 3 and n pieces of R 4 each independently represent hydrogen atom or alkyl group having 1 to 4 carbon atoms, R 5 to R 7 each independently represent alkyl group, aralkyl group, or aryl group, R 8 represents alkyl group, aralkyl group, aryl group, or the one represented by the general formula [2]: (wherein T represents alkylene chain having 1 to 8 carbon atoms, n represents 1 or 2, and R 1 to R 7 are the same as the above-described), X represents nitrogen atom or phosphorus atom, n represents 1 or 2. When n is 1, R 3 and R 4 are bound and may form cyclohexene ring together with the adjacent carbon atoms. In addition, when X is nitrogen atom, R 5 to R 7 or R 5 to R 6 may form hetero ring with nitrogen atom binding thereto}.

  问题：提供一种新型离子液体，成本低、环保，并具有低粘度和熔点。 解决问题的方法：本发明是一种由通式[1]表示的离子液体的发明：其中，R1到R3和n个R4分别独立表示氢原子或具有1到4个碳原子的烷基基团，R5到R7分别独立表示烷基基团、芳基烷基基团或芳基基团，R8表示烷基基团、芳基烷基基团、芳基基团或由通式[2]表示的基团：（其中T表示具有1到8个碳原子的烷基链，n表示1或2，R1到R7与上述相同），X表示氮原子或磷原子，n表示1或2。当n为1时，R3和R4结合并且可能与相邻碳原子一起形成环己烯环。此外，当X为氮原子时，R5到R7或R5到R6可能与结合在一起的氮原子形成杂环}。
• PROCESS FOR EPOXIDATION OF ARYL ALLYL ETHERS
  申请人：Dow Global Technologies Inc.

  公开号：EP1080084B1

  公开（公告）日：2004-05-06
• US6087513A
  申请人：——

  公开号：US6087513A

  公开（公告）日：2000-07-11
• US8546609B2
  申请人：——

  公开号：US8546609B2

  公开（公告）日：2013-10-01
• [EN] EPOXIDATION PROCESS FOR ARYL ALLYL ETHERS<br/>[FR] PROCEDE D'EPOXYDATION D'ARYL-ALLYL ETHERS
  申请人：——

  公开号：WO1999062894A2

  公开（公告）日：1999-12-09

  [EN] A process for making an aromatic glycidyl ether epoxy compound by contacting an allyl ether made from the hydroxy moiety of a hydroxy-containing aromatic compound with an inorganic or organic hydroperoxide oxidant in the presence of a transition metal complex catalyst, wherein at least (a) the allyl ether is conformationally restricted or (b) the transition metal complex catalyst contains at least one or more stable ligands attached to the transition metal. The process of the present invention provides for epoxidizing aryl allyl ethers with high epoxidation yield (for example, greater than 70 percent to 90 percent) and high hydroperoxide selectivity (for example, greater than 70 percent to 90 percent).
  [FR] La présente invention concerne un procédé permettant la réalisation d'un composé époxy de glycidyl-éther aromatique. En l'occurrence, on prend un allyl-éther issu du groupe fonctionnel hydroxy d'un composé aromatique comportant un hydroxy et on le met en contact avec comme oxydant un hydroperoxyde organique ou inorganique en présence d'un catalyseur à base de métal de transition. Il faut néanmoins (a) que l'allyl-éther emporte des restrictions de conformation ou (b) que le catalyseur à base de métal de tansition contienne au moins un ou plusieurs ligands stables se rattachant au métal de transition. Le procédé de l'invention permet ainsi une époxydation d'aryl-allyl éthers avec un haut degré d'époxydation (typiquement plus de 70 % à 90 %) et une haute sélectivité de l'hydroperoxyde (typiquement plus de 70 % à 90 %).