6-Chloro-3-methyl-1,3-hexadiene | 216018-88-1

• 分子结构分类: 有机化合物 - 有机卤素化合物 - 有机氯化物
• 英文名称: 6-Chloro-3-methyl-1,3-hexadiene
• 英文别名: 6-chloro-3-methyl-hexa-1,3-diene；6-Chloro-3-methylhexa-1,3-diene；6-chloro-3-methylhexa-1,3-diene
• CAS: 216018-88-1
• 化学式: C₇H₁₁Cl
• 分子量: 130.617
• InChiKey: ROTSLPGVEGSGDO-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.2
• 重原子数：
  8
• 可旋转键数：
  3
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.43
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  6-Chloro-3-methyl-1,3-hexadiene 在 盐酸 、 水 、 sodium thiosulfate 作用下， 生成 3-Methyl-6-sulfanyl-1,3-hexadiene
  参考文献：
  名称：

  Colloid-Bound Catalysts for Ring-Opening Metathesis Polymerization: A Combination of Homogenous and Heterogeneous Properties

  摘要：

  Tailor-made thiols allow a ruthenium-based catalyst for ring-opening metathesis polymerization (ROMP) to be tethered to bulk gold surfaces and to gold colloids (see picture). The functionalized gold colloids combine the properties of homogeneous and heterogeneous catalyst systems. Tethering of the catalyst leads to a pronounced increase in its catalytic activity.

  DOI：

  10.1002/(sici)1521-3773(19981002)37:18<2466::aid-anie2466>3.0.co;2-3
• 作为产物：
  描述：

  1-氯-4-甲基-5-己烯-4-醇 在 phosphorus pentoxide 作用下， 以 甲苯 为溶剂， 反应 1.0h， 以55%的产率得到6-Chloro-3-methyl-1,3-hexadiene
  参考文献：
  名称：

  Colloid-Bound Catalysts for Ring-Opening Metathesis Polymerization: A Combination of Homogenous and Heterogeneous Properties

  摘要：

  Tailor-made thiols allow a ruthenium-based catalyst for ring-opening metathesis polymerization (ROMP) to be tethered to bulk gold surfaces and to gold colloids (see picture). The functionalized gold colloids combine the properties of homogeneous and heterogeneous catalyst systems. Tethering of the catalyst leads to a pronounced increase in its catalytic activity.

  DOI：

  10.1002/(sici)1521-3773(19981002)37:18<2466::aid-anie2466>3.0.co;2-3

文献信息

• Colloid-Bound Catalysts for Ring-Opening Metathesis Polymerization: A Combination of Homogenous and Heterogeneous Properties
  作者：Marcus Bartz、Jörg Küther、Ram Seshadri、Wolfgang Tremel

  DOI：10.1002/(sici)1521-3773(19981002)37:18<2466::aid-anie2466>3.0.co;2-3

  日期：1998.10.2

  Tailor-made thiols allow a ruthenium-based catalyst for ring-opening metathesis polymerization (ROMP) to be tethered to bulk gold surfaces and to gold colloids (see picture). The functionalized gold colloids combine the properties of homogeneous and heterogeneous catalyst systems. Tethering of the catalyst leads to a pronounced increase in its catalytic activity.