N-[1]Naphthyl-N'-phenyl-hydrazin | 34139-25-8

• 分子结构分类: 有机化合物 - 苯类化合物 - 萘
• 英文名称: N-[1]Naphthyl-N'-phenyl-hydrazin
• 英文别名: N-Phenyl-N'--hydrazin；N-Naphthyl-(1)-N'-phenyl-hydrazin；N-[1]naphthyl-N'-phenyl-hydrazine；N-Phenyl-N'-α-naphthyl-hydrazin；1-(1-Naphthalenyl)-2-phenylhydrazine；1-naphthalen-1-yl-2-phenylhydrazine
• CAS: 34139-25-8
• 化学式: C₁₆H₁₄N₂
• 分子量: 234.301
• InChiKey: YYFZAOFDCWVRLQ-UHFFFAOYSA-N

物化性质

• 熔点：
  170 °C
• 沸点：
  331.6±15.0 °C(Predicted)
• 密度：
  1.230±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  4.8
• 重原子数：
  18
• 可旋转键数：
  3
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  24.1
• 氢给体数：
  2
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  N-[1]Naphthyl-N'-phenyl-hydrazin 在 acid 作用下， 生成 1-Amino-4-(4-amino-phenyl)-naphthalin
  参考文献：
  名称：

  Nietzki; Zehntner, Chemische Berichte, 1893, vol. 26, p. 145

  摘要：

  DOI：
• 作为产物：
  描述：

  1-phenylazonaphthalene 在 ammonium sulfide 作用下， 生成 N-[1]Naphthyl-N'-phenyl-hydrazin
  参考文献：
  名称：

  Nietzki; Zehntner, Chemische Berichte, 1893, vol. 26, p. 145

  摘要：

  DOI：

文献信息

• Ni(II)-Catalyzed Transfer Hydrogenation of Azoarenes with NH₃BH₃
  作者：Dawei Gong、Degong Kong、Yufei Li、Caiyu Gao、Lina Zhao

  DOI：10.1021/acs.orglett.3c01529

  日期：2023.6.9

  A nickel-catalyzed semihydrogenation of azoarenes to hydrazoarenes with NH3BH3 is developed. The catalytic system exhibits good functional group tolerance and a high turnover frequency at room temperature. Results of control and deuterium-labeling experiments indicate that the ethanol hydroxyl and BH3 groups each donated one hydrogen to this transfer hydrogenation, and the main byproducts were B(OEt)3

  开发了使用 NH 3 BH 3将偶氮芳烃镍催化半氢化为氢化偶氮芳烃。该催化体系在室温下表现出良好的官能团耐受性和高周转频率。对照和氘标记实验结果表明，乙醇羟基和BH 3基团各向该转移氢化提供一个氢，主要副产物为B(OEt) 3和H 2。此外，密度泛函理论计算表明反应通过配体到配体的氢转移机制进行。本研究提出了一种用于偶氮芳烃半氢化的新型镍催化体系。
• Process for production of vinyl chloride polymer
  申请人：Shin-Etsu Chemical Co., Ltd.

  公开号：EP0172427A2

  公开（公告）日：1986-02-26

  This process is a process for production of a vinyl chloride polymer by suspension polymerization or emulsion polymerization of vinyl chloride monomer or a mixture of vinyl chloride monomer with a vinyl monomer copolymerizable with said vinyl chloride monomer in an aqueous medium, characterized in that the polymerization is carried out in a polymerizer, the inner wall surface and portions of the auxiliary equipment thereof which may come into contact with the monomer during polymerization being previously coated with a scaling preventive comprising at least one selected from dyes, pigments and aromatic or heterocyclic compounds having at least 5 conjugated π bonds, while controlling the chloride ion concentration in the reaction mixture to not higher than 100 ppm. According to said process, scaling onto the inner wall surface of a polymerizer, etc. during polymerization can be prevented effectively and surely.

  该工艺是通过氯乙烯单体或氯乙烯单体与可与所述氯乙烯单体共聚的乙烯基单体混合物在水介质中进行悬浮聚合或乳液聚合来生产氯乙烯聚合物的工艺，其特征在于聚合是在聚合器中进行的、内壁表面及其辅助设备中可能在聚合过程中与单体接触的部分事先涂上一层防垢剂，该防垢剂至少包括一种选自染料、颜料和至少有 5 个共轭 π 键的芳香族或杂环化合物的防垢剂，同时控制反应混合物中的氯离子浓度不高于 100 ppm。根据上述工艺，可有效、可靠地防止聚合过程中聚合器等内壁表面结垢。
• Polyaniline membranes, uses, and methods thereto
  申请人：The Regents of the University of California

  公开号：US10265662B2

  公开（公告）日：2019-04-23

  Disclosed herein are methods of increasing the hydrophilicity of a membrane. Membranes comprising polyaniline or co-polymer thereof and one or more gel inhibiting agents are treated with one or more hydrophilicity restoration agents, thereby increasing the hydrophilicity of a membrane. Also disclosed are membranes produced by the disclosed methods. This abstract is intended as a scanning tool for purposes of searching in the particular art and is not intended to be limiting of the present invention.

  本文公开了增加膜亲水性的方法。用一种或多种亲水性恢复剂处理包含聚苯胺或其共聚物和一种或多种凝胶抑制剂的膜，从而增加膜的亲水性。还公开了用公开方法生产的膜。本摘要旨在作为特定技术领域的扫描工具，用于搜索目的，并非对本发明的限制。
• Banthorpe et al., Journal of the Chemical Society, 1962, p. 2418,2428
  作者：Banthorpe et al.

  DOI：——

  日期：——
• POLYANILINE MEMBRANES, USES, AND METHODS THERETO
  申请人：The Regents of the University of California

  公开号：EP2906608A1

  公开（公告）日：2015-08-19