N-(2-hydroxy)dodecyl bis(hexamethylene)triamine | 271592-30-4

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: N-(2-hydroxy)dodecyl bis(hexamethylene)triamine
• 英文别名: 1-[6-(6-Aminohexylamino)hexylamino]dodecan-2-ol
• CAS: 271592-30-4
• 化学式: C₂₄H₅₃N₃O
• 分子量: 399.704
• InChiKey: NRSNPVFQQQUKNE-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.7
• 重原子数：
  28
• 可旋转键数：
  24
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  70.3
• 氢给体数：
  4
• 氢受体数：
  4

反应信息

• 作为产物：
  描述：

  1,2-环氧十二烷 、 双(六亚甲基)三胺 以 乙醇 、 水 、 甲苯 为溶剂， 生成 N-(2-hydroxy)dodecyl bis(hexamethylene)triamine
  参考文献：
  名称：

  Process and compositions promoting biological effectiveness of exogenous chemical substances in plants

  摘要：

  提供一种植物处理组合物，用于将阴离子外源化学物质（如草甘膦）应用于植物叶片。该组合物除了包括外源化学物质外，还包括一种或多种氨基化合物，每种化合物具有n个可质子化氨基团，其中n至少为1，具有下列式(I)R—NR—((CH2)p—CHR4—NR)q—R  (I)其中q为0至9的整数，每个p独立为1至5的整数，每个R4基团独立地为氢或C1-5烷基基团，R基团独立地选自氢、C1-5烃基团和线性或支链、饱和或不饱和的C6-22烃基或酰基链，该链未经取代或在一个或多个碳原子上与一个独立选择的羟基、羧基、氨基、巯基和氰基等功能团之一取代，以及未经中断或在一个或多个独立选择的醚、硫醚、亚砜、酯、硫酯和酰胺键之一中断，以至少有6个碳原子的未中断烃基段终止；但至少有一个到三个R基团是这样的C6-22烃基或酰基链，其中至少有一个被取代和/或中断。式(I)的外源化学物质和氨基化合物溶解或分散在农学上可接受的液体载体中，最好是水。还提供了一种液体浓缩组合物，稀释后与水形成植物处理组合物，以及制备这种液体浓缩组合物的过程。该发明的植物处理组合物可用于引发植物中的生物活性，例如除草活性。

  公开号：

  US06500783B1

文献信息

• PROMOTING BIOLOGICAL EFFECTIVENESS OF EXOGENOUS CHEMICAL SUBSTANCES IN PLANTS
  申请人：FLAMEL TECHNOLOGIES

  公开号：EP1135024B1

  公开（公告）日：2004-12-29
• US6500783B1
  申请人：——

  公开号：US6500783B1

  公开（公告）日：2002-12-31
• [EN] PROMOTING BIOLOGICAL EFFECTIVENESS OF EXOGENOUS CHEMICAL SUBSTANCES IN PLANTS<br/>[FR] AMELIORATION DE L'EFFICACITE BIOLOGIQUE DE SUBSTANCES CHIMIQUES EXOGENES CHEZ LES VEGETAUX
  申请人：MONSANTO CO

  公开号：WO2000032045A1

  公开（公告）日：2000-06-08

  A plant treatment composition for application of an anionic exogenous chemical substance such as glyphosate to foliage of a plant comprising in addition to the exogenous chemical substance, one or more amine compound(s) each having a number n of protonatable amino groups, n being at least 1, and having the formula (I) R-NR-((CH2)p-CHR4-NR)q-R wherein q is an integer of 0 to 9, each p is independently an integer of 1 to 5, each R4 group is independently hydrogen or a C¿1-5? alkyl group, and R groups are independently selected from hydrogen, C1-5 hydrocarbyl groups and linear or branched, saturated or unsaturated C6-22 hydrocarbyl or acyl chains that are (a) unsubstituted or substituted at one or a plurality of carbon atoms with a functional group independently selected from hydroxyl, carboxy, carbamyl, mercapto and cyano groups and (b) uninterrupted or interrupted by one or a plurality of functional linkages, and terminated by an uninterrupted hydrocarbyl segment having at least 6 carbon atoms; with the proviso that one to three R groups are such C6-22 hydrocarbyl or acyl chains, of which at least one is so substituted and/or interrupted.
• Process and compositions promoting biological effectiveness of exogenous chemical substances in plants
  申请人：Monsanto Technology LLC

  公开号：US06500783B1

  公开（公告）日：2002-12-31

  A plant treatment composition for application of an anionic exogenous chemical substance such as glyphosate to foliage of a plant is provided. The composition comprises, in addition to the exogenous chemical substance, one or more amine compound(s) each having a number n of protonatable amino groups, n being at least 1, and having the formula (I) R—NR—((CH2)p—CHR4—NR)q—R  (I) wherein q is an integer of 0 to 9, each p is independently an integer of 1 to 5, each R4 group is independently hydrogen or a C1-5 alkyl group, and R groups are independently selected from hydrogen, C1-5 hydrocarbyl groups and linear or branched, saturated or unsaturated C6-22 hydrocarbyl or acyl chains that are (a) unsubstituted or substituted at one or a plurality of carbon atoms with a functional group independently selected from hydroxyl, carboxy, carbamyl, mercapto and cyano groups and (b) uninterrupted or interrupted by one or a plurality of functional linkages independently selected from ether, thioether, sulfoxide, ester, thioester and amide linkages, and terminated by an uninterrupted hydrocarbyl segment having at least 6 carbon atoms; with the proviso that one to three R groups are such C6-22 hydrocarbyl or acyl chains, of which at least one is so substituted and/or interrupted. The exogenous chemical substance and amine compound(s) of formula (I) are dissolved or dispersed in an agronomically acceptable liquid carrier, preferably water. Also provided are a liquid concentrate composition which, upon dilution with water, forms a plant treatment composition, and a process for making such a liquid concentrate composition. Plant treatment compositions of the invention are useful for eliciting a biological activity, for example herbicidal activity, in a plant.

  提供一种植物处理组合物，用于将阴离子外源化学物质（如草甘膦）应用于植物叶片。该组合物除了包括外源化学物质外，还包括一种或多种氨基化合物，每种化合物具有n个可质子化氨基团，其中n至少为1，具有下列式(I)R—NR—((CH2)p—CHR4—NR)q—R  (I)其中q为0至9的整数，每个p独立为1至5的整数，每个R4基团独立地为氢或C1-5烷基基团，R基团独立地选自氢、C1-5烃基团和线性或支链、饱和或不饱和的C6-22烃基或酰基链，该链未经取代或在一个或多个碳原子上与一个独立选择的羟基、羧基、氨基、巯基和氰基等功能团之一取代，以及未经中断或在一个或多个独立选择的醚、硫醚、亚砜、酯、硫酯和酰胺键之一中断，以至少有6个碳原子的未中断烃基段终止；但至少有一个到三个R基团是这样的C6-22烃基或酰基链，其中至少有一个被取代和/或中断。式(I)的外源化学物质和氨基化合物溶解或分散在农学上可接受的液体载体中，最好是水。还提供了一种液体浓缩组合物，稀释后与水形成植物处理组合物，以及制备这种液体浓缩组合物的过程。该发明的植物处理组合物可用于引发植物中的生物活性，例如除草活性。