decyl-trimethyl-ammonium; hydroxide | 62417-63-4

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: decyl-trimethyl-ammonium; hydroxide
• 英文别名: Decyl-trimethyl-ammonium; Hydroxid；Decyl trimethyl ammonium hydroxide；decyl(trimethyl)azanium;hydroxide
• CAS: 62417-63-4
• 化学式: C₁₃H₃₀N*HO
• 分子量: 217.395
• InChiKey: HQDFXHKYURDVIO-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  3.66
• 重原子数：
  15
• 可旋转键数：
  9
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  1
• 氢给体数：
  1
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  phosphotungstic acid 、 decyl-trimethyl-ammonium; hydroxide 以 水 为溶剂， 生成 tri(decyltrimethylammonium) dodecatungstophosphate
  参考文献：
  名称：

  催化多金属氧酸盐纳米颗粒稳定的Pickering乳液：一种新型的氧化反应有效介质。

  摘要：

  将癸基，十二烷基和十四烷基三甲基铵阳离子与催化性多金属氧酸盐[PW 12 O 40 ] 3-阴离子结合，得到球形和单分散的纳米颗粒，能够在水和芳族溶剂存在下稳定乳液。基于催化表面活性剂的这种三相液体/固体/液体系统作为涉及过氧化氢的环氧化反应的反应介质特别有效。反应以竞争性速率进行，通过离心直接分离各相。这种催化“选择”乳液结合了非均相催化和双相催化的优点，而没有缺点（例如，催化剂浸出或分离时间）。

  DOI：

  10.1002/chem.201201799
• 作为产物：
  描述：

  十烷基三甲基溴化铵 在 hydroxide ion exchange resin 作用下， 以 水 为溶剂， 生成 decyl-trimethyl-ammonium; hydroxide
  参考文献：
  名称：

  催化多金属氧酸盐纳米颗粒稳定的Pickering乳液：一种新型的氧化反应有效介质。

  摘要：

  将癸基，十二烷基和十四烷基三甲基铵阳离子与催化性多金属氧酸盐[PW 12 O 40 ] 3-阴离子结合，得到球形和单分散的纳米颗粒，能够在水和芳族溶剂存在下稳定乳液。基于催化表面活性剂的这种三相液体/固体/液体系统作为涉及过氧化氢的环氧化反应的反应介质特别有效。反应以竞争性速率进行，通过离心直接分离各相。这种催化“选择”乳液结合了非均相催化和双相催化的优点，而没有缺点（例如，催化剂浸出或分离时间）。

  DOI：

  10.1002/chem.201201799

文献信息

• QUATERNARY AMMONIUM SALT-CONTAINING CATALYST FOR DISSOCIATION OF BLOCKING AGENT AND USE THEREOF
  申请人：TOSOH CORPORATION

  公开号：US20150344727A1

  公开（公告）日：2015-12-03

  A catalyst containing a quaternary ammonium salt represented by the following general formula (1) is used as a catalyst for dissociation of a blocking agent. [In the formula, each of R 1 to R 3 represents an aliphatic hydrocarbon group having 1 to 8 carbon atoms or an aromatic hydrocarbon group having 6 to 14 carbon atoms; R 4 represents an aliphatic hydrocarbon group having 9 to 20 carbon atoms; X represents at least one member selected from the group consisting of a phosphate group, a borate group, a hydrogencarbonate group, a monoalkylcarbonate group and a carbonate group; a is an integer in the range of 1 to 3; and b is an integer in the range of 1 to 3.]

  一种催化剂包含一个由以下通用公式（1）表示的季铵盐，用作分解阻塞剂的催化剂。【在公式中，R1至R3中的每一个代表具有1至8个碳原子的脂肪烃基或具有6至14个碳原子的芳香烃基；R4代表具有9至20个碳原子的脂肪烃基；X代表选择自磷酸盐、硼酸盐、碳酸氢盐、单烷基碳酸盐和碳酸盐组成的至少一种成员；a是在1到3范围内的整数；b是在1到3范围内的整数。】
• Method for Producing Fluorine-Containing Cyclopropane Carboxylic Acid Compound
  申请人：CENTRAL GLASS COMPANY, LIMITED

  公开号：US20180186763A1

  公开（公告）日：2018-07-05

  The present invention provides an industrially applicable method for production of a fluorine-containing cyclopropane carboxylic acid compound useful as an intermediate for pharmaceutical and agrichemical products. A fluorine-containing cyclopropane monoester is obtained by: forming a fluorine-containing cyclic sulfate with the use of a fluorine-containing dial compound and sulfuryl fluoride (as a cyclic sulfuric esterification step); reacting the fluorine-containing cyclic sulfate with a malonic diester, thereby forming a fluorine-containing cyclopropane diester (as a cyclopropanation step); and hydrolyzing the fluorine-containing cyclopropane diester (as a hydrolysis step). The fluorine-containing cyclopropane carboxylic acid compound, such as fluorine-containing cyclopropane monoester or its salt, can be obtained with high chemical and optical purity by mixing the fluorine-containing cyclopropane monoester with an amine and subjecting the resulting salt of the fluorine-containing cyclopropane monoester and amine to recrystallization purification.

  本发明提供了一种工业上可应用的生产含氟环丙烷羧酸化合物的方法，该化合物可用作制药和农药产品的中间体。通过以下步骤获得含氟环丙烷单酯：使用含氟二醇化合物和氟磺酰氟形成含氟环状硫酸酯（作为环状硫酸酯化步骤）；将含氟环状硫酸酯与丙二酸二酯反应，从而形成含氟环丙烷二酯（作为环丙烷化步骤）；并水解含氟环丙烷二酯（作为水解步骤）。通过将含氟环丙烷单酯与胺混合并将所得的含氟环丙烷单酯和胺的盐进行重结晶纯化，可以获得高化学和光学纯度的含氟环丙烷羧酸化合物，例如含氟环丙烷单酯或其盐。
• Porous silica having substance carried thereon
  申请人：Kitahata Kouichi

  公开号：US20070003492A1

  公开（公告）日：2007-01-04

  The present invention relates to a substance-supporting porous silica, wherein a porous silica supports a substance selected from the group consisting of menthols, volatile substances, thermal substances, plant polyphenols and organic colorants.

  本发明涉及一种物质支持多孔硅胶，其中多孔硅胶支持从薄荷醇、挥发性物质、热性物质、植物多酚和有机染料等组成的物质。
• CURABLE COMPOSITION
  申请人：YASUDA Teruhiko

  公开号：US20090163662A1

  公开（公告）日：2009-06-25

  To provide a curable composition which has a high curing rate and can provide a cured product having good durability. A curable composition comprising an oxyalkylene polymer (A) having a reactive silicon group represented by the following formula (1), and a quaternary ammonium salt (B): —SiX 1 a R 1 3-a (1) wherein R 1 is a C 1-20 monovalent organic group which may have a substituent, X 1 is a hydroxyl group or a hydrolyzable group, and a is an integer of from 1 to 3; provided that when plural R 1 s are present, they may be the same or different from one another, and when plural X 1 s are present, they may be the same or different from one another.

  提供一种可治愈组合物，具有高固化速度，可提供具有良好耐久性的固化产品。一种可固化组合物，包括具有下式（1）所表示的反应性硅基团的氧烷基聚合物（A）和季铵盐（B）：—SiX1aR13-a(1)，其中R1是可以具有取代基的C1-20单价有机基团，X1是羟基或可水解基团，a是从1到3的整数；在存在多个R1时，它们可以相同或不同，当存在多个X1时，它们可以相同或不同。
• Process for the production of aromatic polycarbonate
  申请人：TEIJIN LIMITED

  公开号：EP0667366A2

  公开（公告）日：1995-08-16

  A process for the production of an aromatic polycarbonate, which comprises polycondensing an aromatic dihydroxy compound and a diaryl carbonate in the presence, as a polycondensation catalyst, of at least one alkali metal salt selected from the group consisting of alkali metal salts of ate-complexes of a metal element, which is silicon, germanium, stannum or plumbum, and alkali metal salts of oxoacids of said metal elements. The above aromatic polycarbonate is almost free from being colored, is also almost free from a decrease in polymerization degree when molded, and is further almost free from forming branches and insolubles.

  一种芳香族聚碳酸酯的生产工艺，包括在至少一种碱金属盐作为缩聚催化剂的存在下，将芳香族二羟基化合物和碳酸二芳基酯进行缩聚，该碱金属盐选自金属元素（硅、锗、锡或铂）的吃络合物的碱金属盐和上述金属元素的氧化物的碱金属盐组成的组。上述芳香族聚碳酸酯几乎不着色，成型时聚合度也几乎不会降低，而且几乎不会形成分支和不溶物。