1'-(2-methacryloyloxyethyl)-3,3'-dimethyl-6-nitro-8-[10-(1,4,7-trioxa-10-azacyclododecyl)methyl]spiro[2H-1-benzopyran-2,2'-indoline] | 676340-15-1

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 苯并吡喃
• 英文名称: 1'-(2-methacryloyloxyethyl)-3,3'-dimethyl-6-nitro-8-[10-(1,4,7-trioxa-10-azacyclododecyl)methyl]spiro[2H-1-benzopyran-2,2'-indoline]
• 英文别名: 2-[3',3'-Dimethyl-6-nitro-8-(1,4,7-trioxa-10-azacyclododec-10-ylmethyl)spiro[chromene-2,2'-indole]-1'-yl]ethyl 2-methylprop-2-enoate；2-[3',3'-dimethyl-6-nitro-8-(1,4,7-trioxa-10-azacyclododec-10-ylmethyl)spiro[chromene-2,2'-indole]-1'-yl]ethyl 2-methylprop-2-enoate
• CAS: 676340-15-1
• 化学式: C₃₃H₄₁N₃O₈
• 分子量: 607.704
• InChiKey: CVCOZMOLFLAVHW-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.8
• 重原子数：
  44
• 可旋转键数：
  7
• 环数：
  5.0
• sp3杂化的碳原子比例：
  0.48
• 拓扑面积：
  116
• 氢给体数：
  0
• 氢受体数：
  10

反应信息

• 作为产物：
  描述：

  1'-(2-hydroxyethyl)-3,3'-dimethyl-6-nitro-8-[10-(1,4,7-trioxa-10-azacyclododecyl)methyl]spiro[2H-1-benzopyran-2,2'-indoline] 、 甲基丙烯酰氯 在 三乙胺 作用下， 以 四氢呋喃 为溶剂， 反应 3.0h， 以24%的产率得到1'-(2-methacryloyloxyethyl)-3,3'-dimethyl-6-nitro-8-[10-(1,4,7-trioxa-10-azacyclododecyl)methyl]spiro[2H-1-benzopyran-2,2'-indoline]
  参考文献：
  名称：

  Cation Complexation, Photochromism, and Photoresponsive Ion-Conducting Behavior of Crowned Spirobenzopyran Vinyl Polymers

  摘要：

  Vinyl polymers incorporating a crowned spirobenzopyran moiety at the side chain were synthesized, and their alkali metal-ion complexation, photochromism, and photoresponsive ion-conducting behaviors were studied in comparison with similar polymers incorporating crown ether and spirobenzopyran moieties independently. The metal-ion complexation by their crown ether moiety significantly affected the photochromism of their spirobenzopyran moiety. The crowned spirobenzopyran polymers are similar to their corresponding monomeric analogue in their metal-ion complexing property and photochromism, with some difference induced by polymer effect. Almost no significant aggregation of the photoinduced merocyanine moiety was found in the crowned spirobenzopyran polymer, unlike the polymers carrying spirobenzopyran and crown ether moiety independently. The crowned spirobenzopyran polymers were applied successfully as components of photoresponsive ion-conducting materials.

  DOI：

  10.1021/ma035644g

文献信息

• Cation Complexation, Photochromism, and Photoresponsive Ion-Conducting Behavior of Crowned Spirobenzopyran Vinyl Polymers
  作者：Keiichi Kimura、Hidefumi Sakamoto、Ryoko M. Uda

  DOI：10.1021/ma035644g

  日期：2004.3.1

  Vinyl polymers incorporating a crowned spirobenzopyran moiety at the side chain were synthesized, and their alkali metal-ion complexation, photochromism, and photoresponsive ion-conducting behaviors were studied in comparison with similar polymers incorporating crown ether and spirobenzopyran moieties independently. The metal-ion complexation by their crown ether moiety significantly affected the photochromism of their spirobenzopyran moiety. The crowned spirobenzopyran polymers are similar to their corresponding monomeric analogue in their metal-ion complexing property and photochromism, with some difference induced by polymer effect. Almost no significant aggregation of the photoinduced merocyanine moiety was found in the crowned spirobenzopyran polymer, unlike the polymers carrying spirobenzopyran and crown ether moiety independently. The crowned spirobenzopyran polymers were applied successfully as components of photoresponsive ion-conducting materials.