trans-Acenaphthen-1,2-diol | 97590-27-7

• 分子结构分类: 有机化合物 - 苯类化合物 - 萘
• 英文名称: trans-Acenaphthen-1,2-diol
• 英文别名: (+-)-trans-Acenaphthene-1,2-diol；(1R,2R)-1,2-dihydroacenaphthylene-1,2-diol
• CAS: 97590-27-7
• 化学式: C₁₂H₁₀O₂
• 分子量: 186.21
• InChiKey: ARGFAPRYULRPAN-VXGBXAGGSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.2
• 重原子数：
  14
• 可旋转键数：
  0
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.17
• 拓扑面积：
  40.5
• 氢给体数：
  2
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  trans-Acenaphthen-1,2-diol 、 乙酸酐 生成 trans-1,2-Diacetoxy-acenaphthen
  参考文献：
  名称：

  HATSUI TOSHIHIDE; TAKESHITA HITOSHI, BULL. CHEM. SOC. JAP., 1980, 53, NO 9, 2655-2658

  摘要：

  DOI：
• 作为产物：
  描述：

  苊烯 、 氧气 以2%的产率得到
  参考文献：
  名称：

  HATSUI TOSHIHIDE; TAKESHITA HITOSHI, BULL. CHEM. SOC. JAP., 1980, 53, NO 9, 2655-2658

  摘要：

  DOI：

文献信息

• WATER SOLUBLE COMPOSITIONS INCORPORATING ENZYMES, AND METHOD OF MAKING SAME
  申请人：Monosol, LLC

  公开号：EP3354716A1

  公开（公告）日：2018-08-01

  Disclosed herein are water soluble compositions, such as films, including a mixture of a first water-soluble resin, an enzyme, and an enzyme stabilizer which comprises a functional substrate for the enzyme, methods of making such compositions, and methods of using such compositions, e.g. to make packets containing functional ingredients. The enzymes can include proteases and mixtures of proteases with other enzymes, and the compositions provide good retention of enzyme function following film processing and storage.

  本文公开了水溶性组合物，例如薄膜，包括第一水溶性树脂、酶和酶稳定剂的混合物，其中酶稳定剂包括酶的功能底物，还公开了制造这种组合物的方法，以及使用这种组合物的方法，例如制造含有功能成分的包装。酶可以包括蛋白酶和蛋白酶与其他酶的混合物，这种组合物在薄膜加工和储存后能很好地保持酶的功能。
• Preparation of chiral trans-5-substituted-acenaphthene-1,2-diols by baker’s yeast-mediated reduction of 5-substituted-acenaphthylene-1,2-diones
  作者：Lixiao Wang、Xingyong Wang、Jingnan Cui、Weimin Ren、Nan Meng、Jingyun Wang、Xuhong Qian

  DOI：10.1016/j.tetasy.2010.04.048

  日期：2010.4

  A series of trans-5-substauted-acenaphthene-1,2-diols were obtained in 21-72% yield with 97-100% ee by baker's yeast-mediated reduction of the corresponding acenaphthylene-1,2-diones, in the presence of DMSO as a co-solvent and under vigorous agitation The absolute configuration of (-)-trans-5-methoxy-acenaphthene-1,2-diol trans-3b and (-)-trans-5-bromo-acenaphthene-12-diol trans-3c was assigned as (S,S) and (-)-trans-5-thiomorpholin-acenaphthene-1,2-diol trans-3d was established as (R,R) by exciton-coupled circular dichroism. (C) 2010 Elsevier Ltd All rights reserved
• PLATT, K. L.;OESCH, F., SYNTHESIS, BRD, 1982, N 6, 459-461
  作者：PLATT, K. L.、OESCH, F.

  DOI：——

  日期：——
• MERZ, A.;DIETL, F.;TONAHOGH, R.;WEBER, G.;SHELDRICK, G. M., TETRAHEDRON, 1984, 40, N 4, 665-671
  作者：MERZ, A.、DIETL, F.、TONAHOGH, R.、WEBER, G.、SHELDRICK, G. M.

  DOI：——

  日期：——
• ANIKIN, V. F.;LEVANDOVSKAYA, T. I., ZH. ORGAN. XIMII, 1984, 20, N 9, 1929-1933
  作者：ANIKIN, V. F.、LEVANDOVSKAYA, T. I.

  DOI：——

  日期：——