Phenyl-benzyl-malonsaeure | 55705-20-9

• 分子结构分类: 有机化合物 - 苯丙烷和聚酮 - 二苯乙烯类
• 英文名称: Phenyl-benzyl-malonsaeure
• 英文别名: benzyl-phenyl-malonic acid；α.β-Diphenyl-isobernsteinsaeure；Benzyl-phenyl-malonsaeure；Dibenzyl-α.α-dicarbonsaeure；α.β-Diphenyl-aethan-α.α-dicarbonsaeure；2-Benzyl-2-phenylpropanedioic acid
• CAS: 55705-20-9
• 化学式: C₁₆H₁₄O₄
• 分子量: 270.285
• InChiKey: ZUHPIMDQNAGSOV-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3
• 重原子数：
  20
• 可旋转键数：
  5
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.12
• 拓扑面积：
  74.6
• 氢给体数：
  2
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  Phenyl-benzyl-malonsaeure 生成 2,3-二苯基丙酸
  参考文献：
  名称：

  Wislicenus; Goldstein, Chemische Berichte, 1895, vol. 28, p. 818

  摘要：

  DOI：
• 作为产物：
  描述：

  苯基丙二酸二乙酯 在 乙醇 、 水 、 sodium ethanolate 、 sodium 作用下， 生成 Phenyl-benzyl-malonsaeure
  参考文献：
  名称：

  Wislicenus,W.; Goldstein, Chemische Berichte, 1895, vol. 28, p. 816

  摘要：

  DOI：

文献信息

• Thermoplastic polyester resin composition
  申请人：POLYPLASTICS CO. LTD.

  公开号：EP0251711A2

  公开（公告）日：1988-01-07

  A thermoplastic polyester resin composition, having excellent heat stability and good stability in long-term high-temperature use comprises 100 parts by weight of a thermoplastic polyester blended with a synergistic mixture of firstly,     0.001 ∼ 5 parts by weight of one or more phosphonite compounds expressed by the following formula (I): (in which R¹, R², R³ and R⁴ represent alkyl, substituted alkyl, aryl, or substituted aryl groups having 1 ∼ 25 carbon atoms which may be identical with or different from one another, and R⁵ represents an alkylene, substituted alkylene, arylene, or substituted arylene group having 4 ∼ 33 carbon atoms), and secondly,    0.001 ∼ 5 parts by weight of one or more hindered phenolic compounds. The polyester resin may be blended with other thermoplastic resins and glass fillers; and it may also comprise organo-halogen compounds and organophosphorous compounds as flame retardants and metallic oxides or hydroxides as flame retarding auxiliaries.

  一种热塑性聚酯树脂组合物，具有优异的热稳定性和在长期高温使用中的良好稳定性，该组合物由 100 份（重量）热塑性聚酯与以下物质的增效混合物混合而成：首先，由 0.001 ∼ 5 份（重量）由下式（I）表示的一种或多种膦酸盐化合物组成、 0.001 ∼ 5 份（按重量计）由下式（I）表示的一种或多种膦酸盐化合物： (其中 R¹、R²、R³ 和 R⁴ 代表具有 1 ∼ 25 个碳原子的烷基、取代的烷基、芳基或取代的芳基，它们可以彼此相同或不同，而 R⁵ 代表具有 4 ∼ 33 个碳原子的亚烷基、取代的亚烷基、芳基或取代的芳基)，其次、 0.001 ∼ 5 重量份的一种或多种受阻酚类化合物。 聚酯树脂可与其他热塑性树脂和玻璃填料混合，还可包括作为阻燃剂的有机卤化合物和有机磷化合物，以及作为阻燃助剂的金属氧化物或氢氧化物。
• Thermoplastics polyester resin composition
  申请人：POLYPLASTICS CO. LTD.

  公开号：EP0251712A2

  公开（公告）日：1988-01-07

  A thermoplastic polyester resin composition having excellent heat stability and retaining good properties in long-term use at elevated temperatures comprises 100 parts by weight of a thermoplastic polyester and, in mixture therewith, 0.001 ∼ 5 parts by weight of one or more different phosphoric compounds represented by the general formula (I): (in which Ar and Arʹ represent aryl or substituted aryl groups having 6 ∼ 35 carbon atoms, which may be identical with or different from each other.) The compounds of formula (I) have been found to act synergistically with 0.001 ∼ 5 parts by weight of hindered phenolic compounds. The polyester resin may be blended with other thermoplastic resins. The composition may be filled with glass fillers and organo-halogen compounds and organophosphorous compounds may be present as flame retardants optionally with metal oxide or hydroxide flame retarding auxiliaries.

  一种热塑性聚酯树脂组合物，具有优异的热稳定性，在高温下长期使用仍能保持良好性能，该组合物由 100 份（重量）热塑性聚酯和 0.001 ∼ 5 份（重量）由通式(I)代表的一种或多种不同的磷化合物混合而成： (其中 Ar 和 Arʹ 代表具有 6 ∼ 35 个碳原子的芳基或取代芳基，它们可以彼此相同或不同）。已发现式（I）化合物与 0.001 ∼ 5 份（重量）的受阻酚类化合物协同作用。 聚酯树脂可与其他热塑性树脂混合。组合物中可填充玻璃填料，有机卤素化合物和有机磷化合物可作为阻燃剂，也可与金属氧化物或氢氧化物阻燃助剂一起使用。
• Hinge member
  申请人：POLYPLASTICS CO. LTD.

  公开号：EP0287245A2

  公开（公告）日：1988-10-19

  A hinge member can be obtained by molding a composite comprising (A) a thermoplastic polyester resin of 99 to 40 parts by weight and (B) a polymer obtained by homopolymerizing one kind or copolymerizing two or more kinds selected from the group consisting of vinyl cyanide compounds, acrylic esters, acrylic acid, methacrylic esters, methacrylic acid and aromatic vinyl compounds of 1 to 60 parts by weight.

  铰链部件可通过模塑复合材料获得，复合材料包括 (A) 一种热塑性聚酯树脂，其重量占 99 至 40%，以及 (B) 一种聚合物的均聚物或两种或两种以上聚合物的共聚物，这些聚合物选自乙烯基氰化物、丙烯酸酯、丙烯酸、甲基丙烯酸酯、甲基丙烯酸和芳香族乙烯基化合物组成的组，重量百分比为 1 至 60%。
• Thermoplastic resin composition
  申请人：POLYPLASTICS CO. LTD.

  公开号：EP0290230A2

  公开（公告）日：1988-11-09

  A thermoplastic resin composition is improved in durability to abrasion and comprises a thermoplastic polyester resin or polyacetal resin of 99.9 to 80.0 parts by weight and a silicon oil having a viscosity of 150,000 cSt or more of 0.1 to 20 parts by weight. Further improvements are obtained by additionally including up to 20 parts by weight of a lubricating oil having a viscosity of 3000 cSt or less.

  一种热塑性树脂组合物的耐磨性得到了改善，该组合物由 99.9 至 80.0 重量份的热塑性聚酯树脂或聚缩醛树脂和 0.1 至 20 重量份的粘度为 150,000 cSt 或更高的硅油组成。通过额外加入粘度为 3000 cSt 或更低的润滑油（按重量计，最多 20 份），可获得进一步的改进。
• POLYESTER FILM
  申请人：TORAY INDUSTRIES, INC.

  公开号：EP0331746A1

  公开（公告）日：1989-09-13

  A polyester film suited for optical recording media, which has a photo elasticity coefficient up to 1.2 x 10⁻³ mm²/kgf, a surface roughness, Rt, up to 100 nm, and an average distance between surface projections, Sm, of 20 µm or more. The film does not cause scattering or interference of light and produces no optical distortion even when heated or pressed, thus being useful as a support layer or a cover layer of optical recording media such as optical cards, optical discs, optical re­cording tapes, etc. ABSTRACT This invention relates to a polyester film suited for use in optical recording medium. The polyester film of the present invention has a modulus of photoelasticity of not more than 1.2 x 10⁻³ mm²/kgf, a maximum surface roughness Rt of not more than 100 nm and a mean interval Sm between adjacent surface projections of not less than 20 µm, so that the light scattering and interference are not caused, and optical strain is not generated even a thermal stress or an external force is exerted to the film. Thus, the polyester film of the present invention can be used as the supporting layer or the cover layer of optical recording media such as optical cards, optical disks and optical recording tapes.

  一种适用于光学记录介质的聚酯薄膜，其光弹性系数高达 1.2 x 10-³ mm²/kgf ，表面粗糙度 Rt 高达 100 nm，表面凸起之间的平均距离 Sm 为 20 µm 或更大。这种薄膜不会引起光的散射或干涉，即使在加热或挤压时也不会产生光学变形，因此可用作光学记录介质（如光卡、光盘、光学记录磁带等）的支撑层或覆盖层。 摘要 本发明涉及一种适用于光学记录介质的聚酯薄膜。本发明的聚酯薄膜具有不大于 1.2 x 10-³ mm²/kgf 的光弹性模量、不大于 100 nm 的最大表面粗糙度 Rt 和不小于 20 µm 的相邻表面凸起之间的平均间隔 Sm，因此不会造成光散射和干扰，即使对薄膜施加热应力或外力也不会产生光学应变。因此，本发明的聚酯薄膜可用作光学卡、光盘和光学记录磁带等光学记录介质的支撑层或覆盖层。