Silyl-bis(trimethylsilyl)amin | 18134-68-4

• 分子结构分类: 有机化合物 - 有机金属化合物 - 有机类金属化合物
• 英文名称: Silyl-bis(trimethylsilyl)amin
• 英文别名: 1,1,1-Trimethyl-N-silyl-N-(trimethylsilyl)silanamine；[dimethyl-[silyl(trimethylsilyl)amino]silyl]methane
• CAS: 18134-68-4
• 化学式: C₆H₂₁NSi₃
• 分子量: 191.496
• InChiKey: ZNVOODNMOGCXRL-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.24
• 重原子数：
  10
• 可旋转键数：
  2
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  3.2
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  [dicarbonyl(η5-cyclopentadienyl)iron]trimethylsilane 、 Silyl-bis(trimethylsilyl)amin 以 甲苯 为溶剂， 以22%的产率得到(η5-C5H5)3Fe3(μ2-bis(trimethylsilyl)aminosilane(-2H))(μ3-COSiH2N(SiMe3)2)(μ3-η2-C2O2-SiHN(SiMe3)2)
  参考文献：
  名称：

  Photochemical Reaction of CpFe(CO)₂SiMe₃ (Cp = η⁵-C₅H₅) with a Trihydrosilane Containing a Bulky Amino Substituent, Bis(trimethylsilyl)aminosilane

  摘要：

  A photochemical reaction between CpFe(CO)(2)SiMe3 and (Me3Si)(2)NSiH3 in hexane gave the silylyne-bridged triiron complex Cp3Fe3(CO)(4)SiN(SiMe3)(2) (2) and a diiron complex bridged by a four-membered cyclic silylene, Cp2Fe2(CO)(2)(mu-CO)(mu-SiN(SiMe3)(2)SiMe2CH2) (3). In contrast, the silylene- and alkyne-bridged triiron complex Cp3Fe3{mu(2)-SiHN(SiMe3)(2)}{mu(3)-COSiH2N(SiMe3)(2)}{mu(3)-eta(2)-C2O2-SiHN(SiMe3)(2)} (4) was formed as the main product by a similar reaction in toluene.

  DOI：

  10.1021/om070185j
• 作为产物：
  描述：

  lithium hexamethyldisilazane 在 2,3-dibromotetrasilane 作用下， 以 正庚烷 、 正戊烷 为溶剂， 以85%的产率得到Silyl-bis(trimethylsilyl)amin
  参考文献：
  名称：

  Aminoderivate hydrierter Oligosilane: Darstellung, Charakterisierung und Eigenschaften

  摘要：

  Amino derivatives of linear and branched tri- und tetrasilanes R2N-H2Si(SiH2)SiH2-NR2 H3SiSiHNR2SiHNR2SiH3, R2N-H2SiSiH2SiH2SiH2-NR2 und (R2N-H2Si)2SiHSiH(SiH2-NR2)2 with R = Et, SiMe3 are formed by the reaction of the corresponding bromooligosilanes with suitable amines or alkali metal amides. Product distribution and yields are strongly influenced by the nucleophilicity of the amino reagent and by the structure of the SiSi-backbone. The structures proposed for the aminopolysilanes thus prepared are proved by Si-29-, H-1-NMR- and MS-investigations.

  DOI：

  10.1007/bf01277621

文献信息

• Wannagat,U. et al., Chemische Berichte, 1964, vol. 97, p. 2029 - 2036
  作者：Wannagat,U. et al.

  DOI：——

  日期：——
• Stueger H., Lassacher P., Monatsh. Chem, 125 (1994) N 6-7, S 615-622
  作者：Stueger H., Lassacher P.

  DOI：——

  日期：——
• Aminoderivate hydrierter Oligosilane: Darstellung, Charakterisierung und Eigenschaften
  作者：H. St�ger、P. Lassacher

  DOI：10.1007/bf01277621

  日期：1994.6

  Amino derivatives of linear and branched tri- und tetrasilanes R2N-H2Si(SiH2)SiH2-NR2 H3SiSiHNR2SiHNR2SiH3, R2N-H2SiSiH2SiH2SiH2-NR2 und (R2N-H2Si)2SiHSiH(SiH2-NR2)2 with R = Et, SiMe3 are formed by the reaction of the corresponding bromooligosilanes with suitable amines or alkali metal amides. Product distribution and yields are strongly influenced by the nucleophilicity of the amino reagent and by the structure of the SiSi-backbone. The structures proposed for the aminopolysilanes thus prepared are proved by Si-29-, H-1-NMR- and MS-investigations.
• Photochemical Reaction of CpFe(CO)₂SiMe₃ (Cp = η⁵-C₅H₅) with a Trihydrosilane Containing a Bulky Amino Substituent, Bis(trimethylsilyl)aminosilane
  作者：Masakazu Hirotsu、Takuo Nishida、Hiromitsu Sasaki、Takako Muraoka、Takashi Yoshimura、Keiji Ueno

  DOI：10.1021/om070185j

  日期：2007.5.1

  A photochemical reaction between CpFe(CO)(2)SiMe3 and (Me3Si)(2)NSiH3 in hexane gave the silylyne-bridged triiron complex Cp3Fe3(CO)(4)SiN(SiMe3)(2) (2) and a diiron complex bridged by a four-membered cyclic silylene, Cp2Fe2(CO)(2)(mu-CO)(mu-SiN(SiMe3)(2)SiMe2CH2) (3). In contrast, the silylene- and alkyne-bridged triiron complex Cp3Fe3mu(2)-SiHN(SiMe3)(2)}mu(3)-COSiH2N(SiMe3)(2)}mu(3)-eta(2)-C2O2-SiHN(SiMe3)(2)} (4) was formed as the main product by a similar reaction in toluene.