1,1,1,2,2,3,3,4,4,5,5,6,6,7,7,8,8-Heptadecafluoro-8-isocyanatooctane | 335-85-3

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: 1,1,1,2,2,3,3,4,4,5,5,6,6,7,7,8,8-Heptadecafluoro-8-isocyanatooctane
• CAS: 335-85-3
• 化学式: C₉F₁₇NO
• 分子量: 461.078
• InChiKey: BDWIDRPPSLOJNN-UHFFFAOYSA-N

物化性质

• 沸点：
  140 °C
• 密度：
  1.69±0.1 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  6.9
• 重原子数：
  28
• 可旋转键数：
  7
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.89
• 拓扑面积：
  29.4
• 氢给体数：
  0
• 氢受体数：
  19

反应信息

• 作为产物：
  描述：

  trimethyl(triazirin-1-yl)silane 、 十七氟壬酰氯 以 1,2,5-trimethyl-benzene 为溶剂， 生成 1,1,1,2,2,3,3,4,4,5,5,6,6,7,7,8,8-Heptadecafluoro-8-isocyanatooctane
  参考文献：
  名称：

  Interaction of carbonyl compounds with organomettalic azides IV. Perfluoroalkyl isocyanates

  摘要：

  DOI：

  10.1016/s0022-1139(00)83203-0

文献信息

• URETHANE AND UREA FLUOROSURFACTANTS
  申请人：MURPHY PETER MICHAEL

  公开号：US20120122999A1

  公开（公告）日：2012-05-17

  The present invention comprises a compound of a compound of Formula 1 wherein R f is a C 2 to C 12 perfluoroalkyl optionally interrupted by one to four moieties each independently selected from the group consisting of —CH 2 —, —O—, —S—, —S(O)—, and —S(O) 2 —; n is 1 to 6; m is 0 to 2, provided that m is less than or equal to n. X and Y are each independently O or NR, R is hydrogen or C 1 to C 6 alkyl; R 1 , and R 2 are each independently C 1 to C 6 alkyl, optionally containing one or more oxygen atoms and may form a ring selected from the group of piperidine, pyrrolidine, and morpholine; and R 3 is O − , (CH 2 ) p C(O)O − , (CH 2 ) p CH(OH)(CH 2 )SO 3 − , and (CH 2 ) q SO 3 − ; p is 1 to 4; and q is 2 to 4 which is useful as a surfactant.

  本发明涉及一种化合物，该化合物为式1的化合物，其中Rf是C2到C12的全氟烷基，可选地中断一个到四个基团，每个基团独立地选择自羟基、氧原子、硫原子、磺酰基和磺酰基二元组成的群体；n为1到6；m为0到2，但m小于或等于n；X和Y各自独立地为氧原子或氮原子；R为氢原子或C1到C6的烷基；R1和R2各自独立地为C1到C6的烷基，可选地含有一个或多个氧原子，并且可以形成从哌啶、吡咯烷和吗啉群体中选择的环；而R3为O-、(CH2)pC(O)O-、(CH2)pCH(OH)(CH2)SO3-和(CH2)qSO3-；p为1到4；q为2到4，该化合物可用作表面活性剂。
• Partially fluorinated compositions and surface active agents
  申请人：Acosta Erick Jose

  公开号：US20080113172A1

  公开（公告）日：2008-05-15

  Partially fluorinated amino acid derivatives are provided that are useful as organogelators and surface treatment materials to provide oil- and water-repellency properties to substrates. Also provided are composite materials comprising a porous support and a porous nanoweb. The porous nanoweb contains fibrous structures of about 10 nm to about 1000 nm effective average fiber diameter.

  提供部分氟化氨基酸衍生物，可用作有机凝胶剂和表面处理材料，以赋予基材油和水的抗性。还提供了复合材料，包括多孔支撑体和多孔纳米网。多孔纳米网包含有效平均纤维直径约为10纳米至1000纳米的纤维结构。
• Photolabile blocked surfactants and compositions containing the same
  申请人：MINNESOTA MINING AND MANUFACTURING COMPANY

  公开号：EP0046083A2

  公开（公告）日：1982-02-17

  Surfactants which are blocked against surfactant action (identified herein as "photolabile blocked surfactants") by a photolabile protective or masking group but which, on exposure to actinic radiation, become unblocked are provided. Coating compositions in which surfactant is formed on irradiation are provided by blending the photolabile blocked surfactant with polymeric film-forming materials. Compositions containing the photolabile blocked surfactants are useful when employed as protective coatings on various substrates or as the adhesive in a pressure sensitive adhesive tape. Although initially well adhering to a substrate, such compositions may be readily removed from the substrate following exposure of the same to suitable radiation which unblocks the surfactant to permit it to regain its surfactant activity.

  本发明提供的表面活性剂（此处称为 "光敏阻滞表面活性剂"）被光敏保护基团或掩蔽基团阻滞，但在暴露于光辐射时会解除阻滞。通过将光亲和性受阻表面活性剂与聚合物成膜材料混合，可提供在辐照时形成表面活性剂的涂层组合物。 含有光敏封端表面活性剂的组合物在用作各种基材的保护涂层或压敏胶带的粘合剂时非常有用。虽然最初能很好地粘附在基材上，但当基材暴露在适当的辐射下，表面活性剂就会解除阻塞，从而恢复其表面活性剂的活性，这样，这种组合物就可以很容易地从基材上去除。
• Gmelin Handbuch der Anorganischen Chemie, Gmelin Handbook: F: PerFHalOrg.9, 7.3, page 102 - 124
  作者：

  DOI：——

  日期：——
• Zur herstellung von Perfluoralkylisocyanaten und 1,1-Dihydroperfluoralkylisocyanaten
  作者：M. Sander

  DOI：10.1007/bf00901328

  日期：——