(3-phenyl-3,4-dihydro-2H-benzo[e][1,3]oxazin-6-yl)methyl methacrylate | 1228391-10-3

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 苯并恶嗪类
• 英文名称: (3-phenyl-3,4-dihydro-2H-benzo[e][1,3]oxazin-6-yl)methyl methacrylate
• 英文别名: (3-Phenyl-2,4-dihydro-1,3-benzoxazin-6-yl)methyl 2-methylprop-2-enoate；(3-phenyl-2,4-dihydro-1,3-benzoxazin-6-yl)methyl 2-methylprop-2-enoate
• CAS: 1228391-10-3
• 化学式: C₁₉H₁₉NO₃
• 分子量: 309.365
• InChiKey: MPMLAVGHVIMSCZ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4
• 重原子数：
  23
• 可旋转键数：
  5
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.21
• 拓扑面积：
  38.8
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为产物：
  描述：

  (3-phenyl-3,4-dihydro-2H-benzo[e][1,3]oxazin-6-yl)methanol 、 甲基丙烯酰氯 在 三乙胺 作用下， 以 二氯甲烷 为溶剂， 反应 2.0h， 以90%的产率得到(3-phenyl-3,4-dihydro-2H-benzo[e][1,3]oxazin-6-yl)methyl methacrylate
  参考文献：
  名称：

  Methacryloyl-Functional Benzoxazine: Photopolymerization and Thermally Activated Polymerization

  摘要：

  A novel class of photopolymerizable benzoxazines has been developed. This class has been coined as methacryloyl-functional benzoxazines. It has been synthesized by the reaction of the new benzoxazine monomers: (3-phenyl-3,4-dihydro-2H-benzo[e][1,3]oxazin-6-yl)methanol and methacryloyl chloride. The structure of the monomer has been confirmed by Fourier transform infrared spectroscopy (FTIR) and H-1 and C-13 nuclear magnetic resonance spectroscopy (NMR). Its photopolymerization has been successfully carried out with and without photoinitiator, while the thermally activated polymerization is compromised by low temperature degradation.

  DOI：

  10.1021/ma102351a

文献信息

• Methacryloyl-Functional Benzoxazine: Photopolymerization and Thermally Activated Polymerization
  作者：Lin Jin、Tarek Agag、Yusuf Yagci、Hatsuo Ishida

  DOI：10.1021/ma102351a

  日期：2011.2.22

  A novel class of photopolymerizable benzoxazines has been developed. This class has been coined as methacryloyl-functional benzoxazines. It has been synthesized by the reaction of the new benzoxazine monomers: (3-phenyl-3,4-dihydro-2H-benzo[e][1,3]oxazin-6-yl)methanol and methacryloyl chloride. The structure of the monomer has been confirmed by Fourier transform infrared spectroscopy (FTIR) and H-1 and C-13 nuclear magnetic resonance spectroscopy (NMR). Its photopolymerization has been successfully carried out with and without photoinitiator, while the thermally activated polymerization is compromised by low temperature degradation.